CAS 5518-52-5; tri-(2-furyl)phosphine - �뵺�羺�ٷ��ַ

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

T819653

MACKLIN

三(2-呋喃基)膦

98%

30元/250mg; 34元/1g; 130元/5g; 560元/25g; 2150元/100g;

咨询

储存：室温,干燥
状态：白色到灰白色粉末,晶体和/或块状

T1643

TCI

Tri(2-furyl)phosphine

>98.0%(GC)

650元/1G; 1815元/5G;

咨询

基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₁₂H₉O₃P = 232.17
外观与形状(20℃)	固体
Reaxys-RN	1577564
PubChem物质ID	87577384
SDBS (AIST Spectral DB)	9360
MDL编号	MFCD00151857

技术规格

Appearance	White to Yellow to Orange powder to crystal
Purity(GC)	min. 98.0 %
Melting point	61.0 to 65.0 ℃

物性(参考值)

熔点	63 ℃
沸点	136 ℃/4 mmHg

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

455180

J&K

Tri(2-furyl)phosphine

98%

131元/250MG; 329元/1G; 1011元/5G;

咨询

基本信息

分子式	C₁₂H₉O₃P
分子量	232.17
熔点	59-64
沸点	136
MDL编码	MFCD00151857
Beilstein	1577564

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

15-6372

Strem

Tri-2-furylphosphine

98+%

540元/500mg; 1320元/2g; 2753元/5g;

咨询

Technical Notes:

1.Useful ligand for c-c coupling reactions.

2.Ligand used for the alkynylation of thioesters .

3.Ligand used for enol ester formation.

4.Ligand for palladium-catalyzed 3-Component coupling.

5.Ligand for palladium-catalyzed c-c coupling reaction.

6.Ligand for trans-olefin formation.

7.Olefin formation from N-tosylhydrazones and benzyl halides.

8.C-H arylation/alkenylation of 1-substituted tetrazoles.

9.Tandem allylic amination/2,3-Stevens Rearrangement.

10.Ligand for palladium- catalyzed carbonylation of anilines.

11Palladium-Catalyzed Reaction of Propargylic Carbonates with Benzyne.

12.Synthesis of Substituted Tetrahydrocyclobutabbenzofurans.

13.Palladium-Catalyzed Three-Component Reaction of Allenes, Aryl lodides, and Diazo Compounds.

14.Synthesis of Benzocycloheptabindoles .

15.Palladium-Catalyzed Decarboxylative Allylation and Benzylation.

16.Pd-catalyzed domino carbonylative decarboxylative allylation.

L13329

Alfa Aesar

Tri(2-furyl)phosphine

97%

513元/250mg; 1401元/1g; 5634元/5g;

咨询

基本信息

MDL
MFCD00151857

EINECS
000-000-0

分子式
C₁₂H₉O₃P

分子量
232.18

熔点
59-64°

沸点
136°/4mm

灵敏度
Ambient temperatures.

形态
Crystalline or fused solid

Beilstein
1577564

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

C29480

Alfa Aesar

Tri-(2-furyl)phosphine

98%

1922元/1g; 7618元/5g;

咨询

基本信息

Ref#
29480

MDL
151857

分子式
C12 H9 O3 P

分子量
232.18

383767

Sigma-Aldrich

Tri(2-furyl)phosphine

99%

678.93元/1 G;

咨询

基本信息

经验(实验)分子式	C₁₂H₉O₃P
分子量	232.17
Beilstein	1577564
MDL编号	MFCD00151857
PubChem化学物质编号	24863985
NACRES	NA.22

产品性质

质量水平	100
测定	99%
reaction suitability	reagent type: ligand reaction type: Buchwald-Hartwig Cross Coupling Reaction reagent type: ligand reaction type: Cycloisomerizations reagent type: ligand reaction type: Heck Reaction reagent type: ligand reaction type: Negishi Coupling reagent type: ligand reaction type: Oxidations reagent type: ligand reaction type: Sonogashira Coupling reagent type: ligand reaction type: Stille Coupling reagent type: ligand reaction type: Suzuki-Miyaura Coupling
bp	136 ℃/4 mmHg (lit.)
mp	59-64 ℃ (lit.)
官能团	phosphine
SMILES string	c1coc(c1)P(c2ccco2)c3ccco3
InChI	1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
InChI key	DLQYXUGCCKQSRJ-UHFFFAOYSA-N

安全信息

储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

923460

Amethyst

Tri(2-furyl)phosphine

98%, 用于合成

101元/1G;

咨询

基本信息

分子式	C₁₂H₉O₃P
分子量	232.17
熔点	59-64
沸点	136
MDL编码	MFCD00151857
Beilstein	1577564

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

043531

Fluorochem

Tri(2-furyl)phosphine

97%

550元/1g; 1716元/5g;

咨询

基本信息

CAS Number	5518-52-5
MDL Number	MFCD00151857
Boiling Point	136℃
Melting Point	59-64℃

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .