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CAS: 5453-80-5
分子式: C8H10O
分子量: 122.16
沸点: 67-70℃(1
中文名称: 
5-降冰片烯-2-甲醛
双环[2,2,1]庚-5-烯-2-甲醛
英文名称: 
Bicyclo[2,2,1]hept-5-ene-2-carboxaldehyde
5-Norbornene-2-carboxaldehyde,endo +exo
5-norbornene-2-carboxaldehyde
bicyclo[2.2.1]hept-5-ene-2-carboxaldehyde
5-norbornene-2-carboxaldehyde, mixture ofendo and exo
推荐供应商
货号品牌产品名称规格包装、参考价格
B802825MACKLIN5-降冰片烯-2-甲醛98%41元/1g;   79元/5g;   245元/25g;   858元/100g;   2643元/500g;   咨询
储存:室温,易燃物区域
状态:无色到浅黄色液体
折射率:n20/D 1.490(lit.)
N0504TCI5-Norbornene-2-carboxaldehyde>95.0%(GC)230元/5ML;   595元/25ML;   咨询

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C8H10O = 122.17
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN1363813
PubChem物质ID87573830
SDBS (AIST Spectral DB)13579
MDL编号MFCD00167568

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 95.0%(total of isomer)

物性(参考值)

沸点72 ℃/20 mmHg
闪点50 ℃
比重1.03
折射率1.49
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P403 + P235 : 存放在通风良好的地方。保持低温。

运输信息

UN编号UN1989
类别3
包装类别 III
监管条件代码(*)
419126J&K5-Norbornene-2-carboxaldehyde96%116元/5G;   460元/25G;   1515元/100G;   咨询

基本信息

分子式C8H10O
分子量122.17
沸点67-70
闪点51
密度1.03
折光率(n20D)1.4900
MDL编码MFCD00167568

安全信息

图形或危害标志
提示语Warning
危险说明H226
防范说明P260
UN号码1989
危险分类3
包装等级III
B24973Alfa Aesar5-Norbornene-2-carboxaldehydeendo + exo, 95%1233元/25g;   3840元/100g;   咨询

应用
5-Norbornene-2-carboxaldehyde was used in transition metal-catalyzed synthesis of norbornene-derived homopolymers having pendent t-Boc-protected quinizarin moieties for patterned fluorescence images. It acts as Diels-Alder adduct of acrolein and cyclopentadiene. It can be used as protected form of acrolein, from which the double bond may be liberated by cycloreversion, e.g. in a useful synthesis of 2-vinylimidazole.

备注
Store away from air and oxidizing agents. Airsensitive. Store under dry inert gas.

基本信息

MDL
MFCD00167568

EINECS
226-698-9

分子式
C8H10O

分子量
122.17

沸点
68-70°/12mm

闪点
50°(122°F)

密度
1.032

折射率
1.4910

灵敏度
Air Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Not miscible in water.

Beilstein
1363813

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H303
Flammable liquid and vapour.May be harmful if swallowed.

Precautionary Statements
P261
Avoid breathing dust/fume/gas/mist/vapours/spray.

安全信息

危险等级
3

包装组
III

危险类别
10
Flammable.

TSCA

C14910Alfa Aesar5-Norbornene-2-carboxaldehyde95%, mixture of endo and exo614元/5g;   1011元/25g;   2776元/100g;   咨询

基本信息

Ref#
14910

MDL
167568

分子式
C8 H10 O

分子量
122.17

闪点
50.6

密度
1018

安全信息

危险等级
3

包装组
III

109371Sigma-AldrichBicyclo[2.2.1]hept-5-ene-2-carboxaldehyde95%1277.58元/25 G;   咨询

产品说明

应用

5-降冰片烯-2-甲醛已被用于降冰片烯衍生均聚物的过渡金属催化合成,该均聚物具有受t-Boc保护的奎尼萨林侧基,用于图案化的荧光图像。

包装

25 g in glass bottle

基本信息

经验(实验)分子式C8H10O
分子量122.16
Beilstein1363813
EC 号226-698-9
MDL编号MFCD00167568
PubChem化学物质编号24846911
NACRESNA.22

产品性质

质量水平100
测定95%
折射率n20/D 1.490 (lit.)
bp67-70 ℃/12 mmHg (lit.)
密度1.03 g/mL at 20 ℃ (lit.)
SMILES stringO=CC1C[C@H]2C[C@@H]1C=C2
InChI1S/C8H10O/c9-5-8-4-6-1-2-7(8)3-6/h1-2,5-8H,3-4H2/t6-,7+,8?/m1/s1
InChI keyAJIBZRIAUXVGQJ-KVARREAHSA-N

安全信息

象形图GHS02
警示用语:Warning
危险声明H226
预防措施声明P210
危险分类Flam. Liq. 3
储存分类代码3 - Flammable liquids
WGKWGK 3
闪点(F)123.8 °F - closed cup
闪点(C)51 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
005462Fluorochem5-Norbornene-2-carboxaldehyde97%220元/1g;   264元/5g;   484元/25g;   1782元/100g;   咨询

基本信息

CAS Number5453-80-5
MDL NumberMFCD00167568
Boiling Point68-70℃
Density1.032

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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