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CAS: 54109-16-9
分子式: C9H6BrF3O
分子量: 267.05
熔点: 30°C
中文名称: 
2-溴-2'-(三氟甲基)苯乙酮
2-(三氟甲基)苯甲酰甲基溴
英文名称: 
2-bromo-2'-(trifluoromethyl)acetophenone
2-(trifluoromethyl)phenacyl bromide
推荐供应商
货号品牌产品名称规格包装、参考价格
B860038MACKLIN2-溴-2'-(三氟甲基)苯乙酮>98.0%(GC)65元/250mg;   204元/1g;   咨询
储存:2-8°C
B4797TCI2-Bromo-2'-(trifluoromethyl)acetophenone>98.0%(GC)470元/1G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C9H6BrF3O = 267.05
外观与形状(20℃)固体
储存温度0-10℃
Reaxys-RN4183222
PubChem物质ID253660608
MDL编号MFCD03094304

技术规格

AppearanceWhite to Almost white powder to lump
Purity(GC)min. 98.0 %
Melting point28.0 to 32.0 ℃

物性(参考值)

熔点30 ℃
闪点110 ℃

安全信息

图形或危害标志
信号词危险
危险性说明H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P234 : 只能在原容器中存放。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3261
类别8
包装类别 III
监管条件代码(*)
H32032Alfa Aesar2-Bromo-2'-(trifluoromethyl)acetophenone97%1655元/250mg;   2674元/1g;   11126元/5g;   咨询

应用
The sulfonyl urea thus obtained was used directly in the following condensation with 4-(trifluoromethyl)phenacyl bromide. Upon heating, benzenesulfinic acid ammonium salt might react with 2-(trifluoromethyl)phenacyl bromide to give β-keto sulfone. In Rap-Stoermer condensation reation.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

基本信息

MDL
MFCD03094304

分子式
C9H6BrF3O

分子量
267.04

熔点
24-32°

灵敏度
Ambient temperatures.

形态
Solid

溶解性
Slightly soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

036140Fluorochem2-(Trifluoromethyl)phenacyl Bromide97%1232元/1g;   4488元/5g;   7964元/10g;   咨询

基本信息

CAS Number54109-16-9
MDL NumberMFCD03094304

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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