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CAS: 536-38-9
分子式: C8H6BrClO
分子量: 233.49
熔点: 95-99℃
中文名称: 
溴代-4-氯苯乙酮
2-溴-4-氯乙酰丙酮
α-溴-4-氯苯乙酮
α-氯代对氯苯乙酮
α-溴代对氯苯乙酮
α-溴代-4-氯苯乙酮
2-溴-4'-氯苯乙酮
4-氯苯甲酰甲基溴
alpha-溴代-4-氯苯乙酮
英文名称: 
ω-Bromo-4-chloroacetophenone
4-Chlorophenacyl bromide
2-bromo-4'-chloro-acetophenon
4'-chlorophenacyl bromide
bromomethyl p-chlorophenyl ketone
2-bromo-1-(4-chlorophenyl)-ethanon
4-Chloro-2'-bromoacetophenone
p-(bromoacetyl)chlorobenzene
p-chlorophenacyl bromide
2-bromo-4'-chloroacetophenone
α-Bromo-4-chloroacetophenone
Ethanone,2-bromo-1-(4-chlorophenyl)-
Acetophenone,2-bromo-4'-chloro-
-Bromo-4-chlorlacetophenone
2-Bromo-1-(4-chlorophenyl)ethanone
2-Bromo-4'-chloroace-tophenone
展开更多英文名
性质描述: 针状结晶。熔点96-96.5℃。
生产方法: 可由氯苯与溴乙酰氯在三氯化铝存在下反应而得。或由对氯苯乙酮溴化而得。
用途: 有机合成中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
C830759MACKLINalpha-溴代-4-氯苯乙酮98%31元/1g;   49元/5g;   140元/25g;   359元/100g;   1789元/500g;   8100元/2.5kg;   咨询
储存:室温,密封
状态:白色到浅黄色固体
B0568TCI4-Chlorophenacyl Bromide>98.0%(GC)(T)150元/25G;   370元/100G;   1850元/500G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C8H6BrClO = 233.49
外观与形状(20℃)固体
Reaxys-RN607603
PubChem物质ID87563586
SDBS (AIST Spectral DB)6084
Merck Index (14)2153
MDL编号MFCD00000625

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Argentometric Titration)min. 98.0 %
Melting point96.0 to 100.0 ℃

物性(参考值)

熔点99 ℃
溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

相关法规

RTECS#AM5978800

运输信息

UN编号UN3261
类别8
包装类别 III
监管条件代码(*)
A12607Alfa Aesar2-Bromo-4'-chloroacetophenone98%1129元/25g;   3113元/100g;   14006元/500g;   咨询

应用
2-Bromo-4'-chloroacetophenone is used as pharmaceutical intermediate.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents and bases.

基本信息

MDL
MFCD00000625

EINECS
208-631-5

分子式
C8H6BrClO

分子量
233.50

熔点
94-98°

灵敏度
Ambient temperatures.

形态
Crystalline powder

溶解性
Insoluble in water.

Beilstein
607603

Merck
14,2153

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

欧盟危险品标志

RTECS
AM5978800

TSCA

C14636Alfa Aesar2-Bromo-4'-chloroacetophenone98+%, ACROS OrganicsTM660元/25g;   2016元/100g;   咨询

基本信息

Ref#
14636

MDL
MFCD00000625

EINECS
208-631-5

分子式
C{8}H{6}BrClO

分子量
233.50

熔点
94-98°

形态
Crystals

Beilstein
607603

Merck
14,2153

安全信息

UN#
UN3261

危险等级
8

包装组
II

危险类别
34
Causes burns.

安全等级
26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).

RTECS
AM5978800

TSCA

101273Sigma-Aldrich2-Bromo-4′-chloroacetophenone98%422.11元/25 G;   1448.8元/100 G;   咨询

基本信息

线性分子式ClC6H4COCH2Br
分子量233.49
Beilstein607603
EC 号208-631-5
MDL编号MFCD00000625
PubChem化学物质编号24846535

产品性质

质量水平100
测定98%
mp93-96 ℃ (lit.)
SMILES stringClc1ccc(cc1)C(=O)CBr
InChI1S/C8H6BrClO/c9-5-8(11)6-1-3-7(10)4-2-6/h1-4H,5H2
InChI keyFLAYZKKEOIAALB-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302 - H315 - H319 - H335
预防措施声明P261 - P264 - P270 - P301 + P312 - P302 + P352 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
036379Fluorochem4-Chlorophenacyl Bromide97%220元/1g;   242元/5g;   484元/25g;   1760元/100g;   咨询

基本信息

CAS Number536-38-9
MDL NumberMFCD00000625
Melting Point94-98℃

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
H318: Causes serious eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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