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CAS: 5350-57-2
分子式: C13H12N2
分子量: 196.25
沸点: 225-230℃
熔点: 95-99℃
中文名称: 
苯甲酮腙
二苯甲酮腙
二苯酮腙
英文名称: 
diphenyl ketohydrazone
Benzophenone hydrazone
benzophenone, hydrazone
diphenyl ketone hydrazone
diphenylmethanone hydrazone
diphenyl-methanon hydrazone
Diphenyldiazomethane precursor
Methanone,diphenyl-,hydrazone
diphenyl methanone hydrazone
性质描述: 白色晶体。熔点98℃,沸点225-230℃(7.33kPa)。
生产方法: 将二苯甲酮的无水乙醇溶液与无水肼回流反应10h,冷却析出二苯甲酮腙,产率87%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
B802689MACKLIN二苯甲酮腙98%30元/25g;   38元/100g;   132元/500g;   628元/2.5kg;   2010元/10kg;   咨询
储存:2~8°C
状态:白色到黄色晶体,颗粒,粉末,块状
B1163TCIBenzophenone Hydrazone>98.0%(HPLC)190元/25G;   795元/500G;   咨询

基本信息

纯度/分析方法>98.0%(HPLC)
分子式/分子量C13H12N2 = 196.25
外观与形状(20℃)固体
Reaxys-RN1910177
PubChem物质ID87564103
SDBS (AIST Spectral DB)15081
MDL编号MFCD00007624

技术规格

AppearanceWhite to Orange to Green powder to crystal
Purity(HPLC)min. 98.0 area%
Purity(Nonaqueous Titration)min. 98.0 %
Melting point97.0 to 101.0 ℃

物性(参考值)

熔点99 ℃
沸点230 ℃/55 mmHg
417870J&KBenzophenone Hydrazone95%81元/25G;   107元/100G;   306元/500G;   咨询

基本信息

分子式C13H12N2
分子量196.25
熔点95-98
沸点225-230
MDL编码MFCD00007624
Beilstein1910177
EINECS 编号226-321-8
存储条件Store at 2-8℃

安全信息

防范说明P262
WGK3
RTECSPC4954487
TSCA
906225J&KBenzophenone Hydrazone98%60元/25G;   171元/100G;   682元/500G;   咨询

基本信息

分子式C13H12N2
分子量196.25
熔点95-98
沸点225-230
MDL编码MFCD00007624
Beilstein1910177
EINECS 编号226-321-8
存储条件Store at 2-8℃

安全信息

防范说明P262
WGK3
RTECSPC4954487
TSCA
A12266Alfa AesarBenzophenone Hydrazone98+%513元/50g;   1656元/250g;   3736元/1000g;   咨询

应用
An important compound in organic photochemistry and perfumery as well as in organic synthesis. Used in the antibiotics synthesis of 6-APA and 7-ACA of the carboxyl protecting groups and other organic compounds. Used as organic pigment and medical intermediate. It is used as a photoinitiator of UV-curing applications in inks, adhesive, coatings and optical fiber.

备注
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep refrigerated. (Store below 4 C/39 F.)

基本信息

MDL
MFCD00007624

EINECS
226-321-8

分子式
C13H12N2

分子量
196.25

熔点
96-100°

沸点
225-230°/55mm

闪点
146°(294°F)

密度
1.1

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in ether, benzene, chloroform and other organic solvents.

Beilstein
1910177

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H317-H401-H411
Toxic if swallowed.May cause an allergic skin reaction.Toxic to aquatic life.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P280g-P301+P310a-P321-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves.Wear protective gloves.Specific treatment (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
25-43-51/53
Toxic if swallowed.May cause sensitization by skin contact.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
24-37-45-61
Avoid contact with skin.Avoid contact with skin.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
PC4954487

TSCA

C10557Alfa AesarBenzophenone Hydrazone98+%488元/5g;   687元/100g;   2273元/500g;   咨询

基本信息

Ref#
10557

MDL
7624

分子式
C13 H12 N2

分子量
196.25

形态
Powder

B9602Sigma-AldrichBenzophenone Hydrazone96%429.09元/100 G;   899.67元/500 G;   咨询

基本信息

线性分子式(C6H5)2C=NNH2
分子量196.25
Beilstein1910177
EC 号226-321-8
MDL编号MFCD00007624
PubChem化学物质编号24892146

产品性质

质量水平100
测定96%
bp225-230 ℃/55 mmHg (lit.)
mp95-98 ℃ (lit.)
储存温度2-8℃
SMILES stringN\N=C(/c1ccccc1)c2ccccc2
InChI1S/C13H12N2/c14-15-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H,14H2
InChI keyQYCSNMDOZNUZIT-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P264 - P270 - P301 + P312 - P501
危险分类Acute Tox. 4 Oral
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)294.8 °F
闪点(C)146 ℃
个人防护装备Eyeshields, Gloves, type N95 (US)
991100FluorochemBenzophenone Hydrazone95%330元/100g;   704元/250g;   咨询

基本信息

CAS Number5350-57-2
MDL NumberMFCD00007624

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H317: May cause an allergic skin reaction.
H411: Toxic to aquatic life with long lasting effects.
防范说明 P261: Avoid breathing .
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P272: Contaminated work clothing should not be allowed out of the workplace.
P273: Avoid release to the environment.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P333 + P313: If skin irritation or rash occurs: Get medical advice/attention.
P363: Wash contaminated clothing before reuse.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container to local regulations..
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