CAS 5315-25-3; 2-溴-6-甲基吡啶; 2-bromo-6-methylpyridine

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货号

品牌

产品名称

规格

包装、参考价格

B801937

MACKLIN

2-溴-6-甲基吡啶

98%

29元/1g; 35元/5g; 93元/25g; 325元/100g;

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储存：室温
状态：无色到淡黄色液体
折射率：n20/D 1.562(lit.)

B2114

TCI

2-Bromo-6-methylpyridine

>98.0%(GC)(T)

250元/5G; 595元/25G;

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基本信息

纯度/分析方法	>98.0%(GC)(T)
分子式/分子量	C₆H₆BrN = 172.03
外观与形状(20℃)	液体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气
Reaxys-RN	107322
PubChem物质ID	87564985
MDL编号	MFCD00040743

技术规格

Appearance	Colorless to Light orange to Yellow clear liquid
Purity(GC)	min. 98.0 %
Purity(Nonaqueous Titration)	min. 98.0 %

物性(参考值)

沸点	102 ℃/20 mmHg
闪点	97 ℃
比重	1.51
折射率	1.56

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

144640

J&K

2-Bromo-6-methylpyridine

98%

69元/5G; 145元/25G;

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基本信息

分子式	C₆H₆BrN
分子量	172.02
沸点	102-103
闪点	97
密度	1.512
折光率(n20D)	1.5600 - 1.5640
MDL编码	MFCD00040743
Beilstein	107322
EINECS 编号	226-173-4

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3
TSCA	否

L20018

Alfa Aesar

2-Bromo-6-methylpyridine

98%

703元/5g; 3138元/25g;

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应用
6-Bromo-2-picoline is a halogenated pyridine derivative used is a building block in the preparation of nitrogen containing heterocyclic compounds. It may used in following synthesis 6,6?-dimethyl-2,2?-bipyridine, 6-methyl-2-pyridyl-2-pyridylmethanone, 2-methyl-6-(trimethylsilyl)-pyridine and N,N?’-bis-(6-methylpyrid-2-yl)-(1R,2R)-1,2- diaminocyclohexane (cydiampy).

备注
Store in cool, dry place in tightly closed container. With adequate ventilation. Store away from oxidizing agent.

基本信息

MDL
MFCD00040743

EINECS
226-173-4

分子式
C₆H₆BrN

分子量
172.03

沸点
102-103°/20mm

闪点
97°(206°F)

密度
1.512

折射率
1.5625

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Soluble in chloroform, ethyl aceate. Not miscible or difficult to mix with water.

Beilstein
107322

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H311-H332-H315-H319
Toxic if swallowed.Toxic in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P261-P280-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/21/22-36/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA
否

C39105

Alfa Aesar

6-Bromo-2-picoline

97%

629元/1g; 3177元/10g;

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基本信息

Ref#
39105

MDL
40743

分子式
C6 H6 Br N

分子量
172.02

闪点
97

密度
1512

429112

Sigma-Aldrich

2-Bromo-6-methylpyridine

98%

228.23元/1 G; 1335.71元/10 G;

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产品说明

一般描述

2-溴-6-甲基吡啶是溴吡啶衍生物。2-氯-6-甲基吡啶与溴三甲基硅烷加热时形成。已报道通过各种方法合成这种物质。

应用

2-溴-6-甲基吡啶可用于以下合成：

6,6′-二甲基-2,2′-联吡啶
6-甲基-2-吡啶基-2-吡啶基甲酮
2-甲基-6-(三甲基硅基)-吡啶
N , N '-双-(6-甲基吡啶-2-基)-(1 R ,2 R )-1,2-二氨基环己烷 (cydiampy)
2-甲基-6-吡啶
2-(6-甲基吡啶-2-基)丙-2-醇
双 [(2-溴-6-甲基吡啶)六氟硅酸盐] 一水合物

包装

1, 10 g in glass bottle

基本信息

经验(实验)分子式	C₆H₆BrN
分子量	172.02
EC 号	226-173-4
MDL编号	MFCD00040743
PubChem化学物质编号	24866838
NACRES	NA.22

产品性质

质量水平	100
测定	98%
折射率	n20/D 1.562 (lit.)
bp	102-103 ℃/20 mmHg (lit.)
密度	1.512 g/mL at 25 ℃ (lit.)
SMILES string	Cc1cccc(Br)n1
InChI	1S/C6H6BrN/c1-5-3-2-4-6(7)8-5/h2-4H,1H3
InChI key	SOHDPICLICFSOP-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	206.6 °F - closed cup
闪点(C)	97 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, type ABEK (EN14387) respirator filter

020192

Fluorochem

2-Bromo-6-methylpyridine

98%

220元/10g; 440元/25g; 990元/100g;

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基本信息

CAS Number	5315-25-3
MDL Number	MFCD00040743
Boiling Point	102-103℃
Density	1.512

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .