CAS 5176-27-2; tert-butyl 1-pyrrolecarboxylate

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

N823221

MACKLIN

N-Boc-吡咯

97%

30元/5g; 108元/25g; 392元/100g; 1813元/500g;

咨询

储存：2~8℃
状态：无色到棕色液体

379794

J&K

N-Boc-pyrrole

99%

645元/25ML; 1961元/100ML;

咨询

基本信息

分子式	C₉H₁₃NO₂
分子量	167.21
沸点	91-92
闪点	75
密度	1
折光率(n20D)	1.4685
MDL编码	MFCD00209559

安全信息

图形或危害标志
提示语	Warning
危险说明	H227 H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3

425834

Sigma-Aldrich

N-Boc-pyrrole

98%

521.74元/25 ML; 1837.1元/100 ML;

咨询

产品说明

一般描述

N-Boc-吡咯是 N-保护的吡咯。它与对映体纯丙二烯-1,3-二羧酸酯进行 Diels-Alder 反应，形成内部加合物，在两个新生成的立体中心的保留构型。它还与苯基二乙酸甲酯进行环丙烷化，形成单环丙烷和二环丙烷。据报道，其 Ir 催化的 C-H 硼酸化，随后与 3-氯噻吩交叉偶联形成双杂环。

应用

通过用 n-BuLi 处理，随后与硼酸三甲酯反应， N-Boc-吡咯可用于合成 1-(叔丁氧基羰基)-1H-吡咯-2-基硼酸。
它可以用作以下合成中的原料：

托品衍生物
N-BOC-2-(4-甲氧基苯基)吡咯
N-boc-吡咯-2-基硼酸

包装

25, 100 mL in poly bottle

基本信息

经验(实验)分子式	C₉H₁₃NO₂
分子量	167.21
MDL编号	MFCD00209559
PubChem化学物质编号	24866669

产品性质

质量水平	100
测定	98%
折射率	n20/D 1.4685 (lit.)
bp	91-92 ℃/20 mmHg (lit.)
密度	1 g/mL at 25 ℃ (lit.)
SMILES string	CC(C)(C)OC(=O)n1cccc1
InChI	1S/C9H13NO2/c1-9(2,3)12-8(11)10-6-4-5-7-10/h4-7H,1-3H3
InChI key	IZPYBIJFRFWRPR-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	10 - Combustible liquids
WGK	WGK 3
闪点(F)	167.0 °F - closed cup
闪点(C)	75 ℃ - closed cup
个人防护装备	Eyeshields, Gloves, type ABEK (EN14387) respirator filter

986524

Amethyst

N-Boc-pyrrole

97%, 用于合成

112元/5G;

咨询

基本信息

分子式	C₉H₁₃NO₂
分子量	167.21
沸点	91-92
闪点	75
密度	1
折光率(n20D)	1.4685
MDL编码	MFCD00209559

安全信息

图形或危害标志
提示语	Warning
危险说明	H227 H315 H319 H335
防范说明	P261 P305+P351+P338
WGK	3

094160

Fluorochem

N-Boc-pyrrole

95%

374元/10g; 858元/25g; 2684元/100g;

咨询

基本信息

CAS Number	5176-27-2
MDL Number	MFCD00209559
Boiling Point	91-92℃
Density	1

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .