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CAS: 516-12-1
分子式: C4H4INO2
分子量: 224.39
熔点: 197-204℃
中文名称: 
N-碘代琥珀酰亚胺
N-碘代丁二酰亚胺
N-碘琥珀酰亚胺
N-碘丁二酰亚胺
英文名称: 
Succinimide,N-iodo-
1-Iodo-2,5-pyrrolidinedione
N-iodo-Succinimide
N-Iodosuccinimide
n-iodo-succinimid
1-iodo-5-pyrrolidinedione
succiniodimide
性质描述: 白色针状结晶。熔点200-201℃,溶于丙酮、甲醇,略溶于二氧六环,几乎不溶于四氯化碳、乙醚。遇水分解。
生产方法: 在避光条件下,使丁二酰亚胺与氧化银反应,制取N-丁二亚胺银。将其和碘在干燥的二氧六环中反应,生成N-碘琥珀酰亚胺。
用途: 在有机合成中用于酮类、醛类的碘化。
推荐供应商
货号品牌产品名称规格包装、参考价格
N811786MACKLINN-碘代丁二酰亚胺97%27元/5g;   60元/25g;   220元/100g;   972元/500g;   4412元/2.5kg;   咨询
储存:2~8°C,干燥,密封
状态:白色到黄色到棕色粉末
I0074TCIN-Iodosuccinimide>99.0%(T)350元/5G;   1050元/25G;   2690元/100G;   咨询

基本信息

纯度/分析方法>99.0%(T)
分子式/分子量C4H4INO2 = 224.99
外观与形状(20℃)固体
储存温度<0℃
储存在惰性气体下存放于惰性气体之中
应避免的情况光,湿气 (分解),加热
包装和容器 5G-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN113917
PubChem物质ID87571478
SDBS (AIST Spectral DB)5300
Merck Index (14)5045
MDL编号MFCD00005512

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(Iodometric Titration)min. 98.0 %
Solubility in Acetonealmost transparency

物性(参考值)

熔点201 ℃
水溶性可溶,与水接触发生分解
溶解性(可溶于)甲醇,丙酮
溶解性(微溶于)二噁烷
溶解性(不溶于)乙醚

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。

相关法规

RTECS#WN2817000
275643J&KN-Iodosuccinimide99%463元/10G;   1404元/50G;   2548元/100G;   咨询

基本信息

分子式C4H4INO2
分子量224.98
熔点200-206
MDL编码MFCD00005512
Beilstein113917
EINECS 编号208-221-6
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSWN2817000
414842J&KN-Iodosuccinimide99%, 粉末379元/10g;   484元/50G;   1930元/250G;   咨询

基本信息

分子式C4H4INO2
分子量224.98
熔点200-206
MDL编码MFCD00005512
Beilstein113917
EINECS 编号208-221-6
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSWN2817000
A14320Alfa AesarN-Iodosuccinimide97%553元/5g;   1997元/25g;   4430元/100g;   咨询

应用
N-Iodosuccinimide is used in the preparation of vinyl sulfones from olefins and benzenesulfinic acid. It acts as a source for I+ and involved in Hunsdiecker reactions for the conversion of cinnamic acids, and propiolic acids to the corresponding alfa-halostyrenes and 1-halo-1-alkynes respectively. It is also used to hydrolyze thioglycosides to 1-hydroxyglycosides with triluoroacetic acid. It is involved in the preparation of iodobenzene from 1,6-diynes. Further, it acts as an iodinating agent in chemical synthesis.

备注
Moisture and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00005512

EINECS
208-221-6

分子式
C4H4INO2

分子量
224.99

熔点
ca 196° dec.

密度
2.245

灵敏度
Keep Cold. Moisture Sensitive. Light Sensitive.

形态
Powder

溶解性
Soluble in dioxane, tetrahydrfuran and acetonitrile. Insoluble in ether and carbon tetrachloride.

Beilstein
113917

Merck
14,5045

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

RTECS
WN2817000

TSCA

C29957Alfa AesarN-Iodosuccinimide98%2096元/10g;   7236元/50g;   12269元/100g;   48119元/500g;   咨询

基本信息

Ref#
29957

MDL
5512

分子式
C4 H4 I N O2

分子量
224.99

形态
White to pale brown powder

安全信息

危险等级
6.1

包装组
III

220051Sigma-AldrichN-Iodosuccinimide95%399.71元/5 G;   1172.7元/25 G;   3444.03元/100 G;   咨询

产品说明

包装

5, 25, 100 g in glass bottle

应用

从 1,6-二炔经过高效的两步工艺制备的高取代的碘苯。与 TFA 一起使用,将硫苷化学选择性地水解为 1-羟基糖苷。从烯烃和苯亚磺酸合成乙烯砜。

基本信息

经验(实验)分子式C4H4INO2
分子量224.98
Beilstein113917
EC 号208-221-6
MDL编号MFCD00005512
PubChem化学物质编号24853162
NACRESNA.22

产品性质

质量水平200
测定95%
形式powder
mp202-206 ℃ (lit.)
储存温度2-8℃
SMILES stringIN1C(=O)CCC1=O
InChI1S/C4H4INO2/c5-6-3(7)1-2-4(6)8/h1-2H2
InChI keyLQZMLBORDGWNPD-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08GHS09
警示用语:Warning
危险声明H315 - H317 - H319 - H341 - H410
预防措施声明P201 - P273 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
危险分类Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1B
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
907072AmethystN-Iodosuccinimide97%, 用于合成79元/25G;   278元/100G;   1026元/500G;   咨询

基本信息

分子式C4H4INO2
分子量224.98
熔点200-206
MDL编码MFCD00005512
Beilstein113917
EINECS 编号208-221-6
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSWN2817000
978140AmethystN-Iodosuccinimide99%, 用于合成73元/10G;   168元/50G;   303元/100G;   1134元/500G;   咨询

基本信息

分子式C4H4INO2
分子量224.98
熔点200-206
MDL编码MFCD00005512
Beilstein113917
EINECS 编号208-221-6
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H302
H315
H319
H335
防范说明P261
P305+P351+P338
WGK3
RTECSWN2817000
003418FluorochemN-Iodosuccinimide98%220元/5g;   264元/25g;   792元/100g;   2728元/500g;   咨询

基本信息

CAS Number516-12-1
MDL NumberMFCD00005512
Melting Point199-206℃
Density2.245

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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