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CAS: 5111-65-9
分子式: C11H9BrO
分子量: 237.10
熔点: 108-111℃
中文名称: 
6-溴-2-甲氧基萘
2-溴-6-甲氧基萘
6-甲氧基-2-溴萘
6-溴-2-甲基萘
英文名称: 
2-Methoxy-6-bromonaphthalene
2-bromo-6-methoxynaphthalene
性质描述: 熔点108-111℃(100-103℃)。
生产方法: 用2-溴-6-萘酚以硫酸二甲酯甲基化制得。
用途: 萘丁美酮的中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
B1547TCI2-Bromo-6-methoxynaphthalene>98.0%(GC)450元/25G;   2390元/250G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C11H9BrO = 237.10
外观与形状(20℃)固体
Reaxys-RN2043874
PubChem物质ID87564452
SDBS (AIST Spectral DB)19259
MDL编号MFCD00004062

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Melting point107.0 to 111.0 ℃

物性(参考值)

熔点108 ℃
沸点164 ℃/3 mmHg
水溶性不溶

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
283990J&K2-Bromo-6-methoxynaphthalene98%93元/5G;   263元/25G;   咨询

基本信息

分子式C11H9BrO
分子量237.10
熔点106-109
MDL编码MFCD00004062
Beilstein2043874
EINECS 编号225-837-0

安全信息

图形或危害标志
提示语Warning
危险说明H302
防范说明P281
P305+P351+P338
WGK3
TSCA
A19450Alfa Aesar2-Bromo-6-methoxynaphthalene98%661元/10g;   3210元/50g;   咨询

应用
2-Bromo-6-methoxynaphthalene is used in the synthesis of nabumetone [4-(6-methoxy-2-naphthalenyl)-2-butanone] by Heck reaction.

备注
Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

基本信息

MDL
MFCD00004062

EINECS
225-837-0

分子式
C11H9BrO

分子量
237.10

熔点
105-110°

沸点
160-164°/3mm

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in DMSO. Insoluble in water.

Beilstein
2043874

安全信息

TSCA

C19056Alfa Aesar2-Bromo-6-methoxynaphthalene98%591元/5g;   2246元/25g;   咨询

基本信息

Ref#
19056

MDL
4062

分子式
C11 H9 Br O

分子量
237.1

200174Sigma-Aldrich2-Bromo-6-methoxynaphthalene97%356.03元/10 G;   1755.03元/50 G;   咨询

产品说明

应用

2-Bromo-6-methoxynaphthalene was used in the synthesis of nabumetone [4-(6-methoxy-2-naphthalenyl)-2-butanone] by Heck reaction.

包装

10, 50 g in poly bottle

基本信息

线性分子式BrC10H6OCH3
分子量237.09
Beilstein2043874
EC 号225-837-0
MDL编号MFCD00004062
PubChem化学物质编号24851960
NACRESNA.22

产品性质

质量水平100
测定97%
mp106-109 ℃ (lit.)
SMILES stringCOc1ccc2cc(Br)ccc2c1
InChI1S/C11H9BrO/c1-13-11-5-3-8-6-10(12)4-2-9(8)7-11/h2-7H,1H3
InChI keyAYFJBMBVXWNYLT-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
07503Supelco2-Bromo-6-methoxynaphthalenepharmaceutical impurity standard1548.37元/50MG;   咨询

基本信息

线性分子式BrC10H6OCH3
分子量237.09
Beilstein2043874
EC 号225-837-0
MDL编号MFCD00004062
PubChem化学物质编号329748458
NACRESNA.24

产品性质

质量水平100
测定≥98.0% (GC)
保质期limited shelf life, expiry date on the label
杂质≤0.5% water
mp106-109 ℃ (lit.)
application(s)pharmaceutical (small molecule)
格式neat
SMILES stringCOc1ccc2cc(Br)ccc2c1
InChI1S/C11H9BrO/c1-13-11-5-3-8-6-10(12)4-2-9(8)7-11/h2-7H,1H3
InChI keyAYFJBMBVXWNYLT-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P301 + P312 + P330
危险分类Acute Tox. 4 Oral
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
PHR2524SupelcoNaproxen Impurity NPharmaceutical Secondary Standard; Certified Reference Material6146.58元/100 MG;   咨询

产品说明

一般描述

Pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards

分析说明

These secondary standards offer multi-traceability to the USP, EP and BP primary standards, where they are available.

其他说明

This Certified Reference Material (CRM) is produced and certified in accordance with ISO 17034 and ISO/IEC 17025. All information regarding the use of this CRM can be found on the certificate of analysis.

附注

To see an example of a Certificate of Analysis for this material enter LRAC4558 in the Documents slot below. This is an example certificate only and may not be the lot that you receive.

基本信息

线性分子式BrC10H6OCH3
分子量237.09
Beilstein2043874
MDL编号MFCD00004062

产品性质

等级certified reference material
pharmaceutical secondary standard
形式solid
CofAcurrent certificate can be downloaded
包装pkg of 100 mg
mp106-109 ℃ (lit.)
储存温度2-8℃
SMILES stringCOc1ccc2cc(Br)ccc2c1
InChI1S/C11H9BrO/c1-13-11-5-3-8-6-10(12)4-2-9(8)7-11/h2-7H,1H3
InChI keyAYFJBMBVXWNYLT-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H302
预防措施声明P301 + P312 + P330
危险分类Acute Tox. 4 Oral
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
023276Fluorochem2-Bromo-6-methoxynaphthalene98%220元/1g;   220元/10g;   330元/25g;   990元/100g;   咨询

基本信息

CAS Number5111-65-9
MDL NumberMFCD00004062
Melting Point104-110℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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