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CAS: 507-16-4
分子式: Br2OS
分子量: 207.87
沸点: 48 °C 20 mm Hg(lit.)
熔点: −52 °C(lit.)
英文名称: 
thionyl bromide
sulfur bromide oxide
推荐供应商
货号品牌产品名称规格包装、参考价格
T831982MACKLIN二溴亚砜97%148元/5g;   588元/25g;   咨询
储存:2~8°C,避光
状态:黄色或红色液体
折射率:n20/D 1.675(lit.)
L15648Alfa AesarThionyl bromide97%554元/25g;   1550元/100g;   咨询

应用
Thionyl bromide is used as a brominating agent in organic synthesis. It is used in the bromination of alfa-beta-unsaturated carbonyl compounds. It is also used to prepare alkyl bromides from alcohols.

备注
Moisture and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, hydrobromide, acetone and alcohol.It hydrolyzes readily to release hydrogen bromide.

基本信息

MDL
MFCD00011448

EINECS
208-064-3

分子式
Br2OS

分子量
207.88

熔点
-52°

沸点
47-49°/20mm

密度
2.683

折射率
1.6750

灵敏度
Keep Cold. Moisture Sensitive. Light Sensitive.

形态
Liquid

溶解性
Miscible with benzene, toluene and ether.

Merck
14,9347

GHS危害和防范说明

GHS符号

Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
I

危险类别
14-35
Reacts violently with water.Causes severe burns.

安全等级
8-20-23-26-30-36/37/39-45-60
Keep container dry.When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Never add water to this product.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

251259Sigma-AldrichThionyl bromide97%379.01元/25 G;   1053.58元/100 G;   咨询

产品说明

包装

25, 100 g in glass bottle

应用

在氟相中直接溴化伯醇。

基本信息

线性分子式SOBr2
分子量207.87
EC 号208-064-3
MDL编号MFCD00011448
PubChem化学物质编号24855121
NACRESNA.22

产品性质

质量水平200
蒸汽压10 mmHg ( 31 ℃)
测定97%
形式liquid
折射率n20/D 1.675 (lit.)
bp48 ℃/20 mmHg (lit.)
mp−52 ℃ (lit.)
密度2.683 g/mL at 25 ℃ (lit.)
储存温度2-8℃
SMILES stringBrS(Br)=O
InChI1S/Br2OS/c1-4(2)3
InChI keyHFRXJVQOXRXOPP-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H312 + H332 - H314
预防措施声明P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Dermal - Skin Corr. 1B
补充剂危害EUH014
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9
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