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CAS: 4733-39-5
分子式: C26H20N2
分子量: 360.45
熔点: 279-283 °C(lit.)
中文名称: 
2,9-二甲基-4,7-二苯基-1,10-邻二氮杂菲
2,9-二甲基-4,7-联苯-1,10-邻二氮杂菲
2,9-二甲基-4,7-二苯基-1,10-菲绕啉
浴铜灵
2,9-二甲基-4,7-二苯基-1,10-菲啰啉
英文名称: 
10-Phenanthroline, 2,9-dimethyl-4,7-diphenyl-1
2,9-dimethyl-4,7-diphenyl-10-phenanthroline
bathocuproine
2,9-Dimethyl-4,7-diphenyl-1,10
1,10-Phenanthroline,2,9-dimethyl-4,7-diphenyl-
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline
Bathocuproin
推荐供应商
货号品牌产品名称规格包装、参考价格
B802392MACKLIN浴铜灵98%99元/1g;   385元/5g;   1699元/25g;   5548元/100g;   19260元/500g;   咨询
储存:室温
B798747MACKLIN浴铜灵升华提纯, 99.8% metals basis299元/100mg;   392元/250mg;   1030元/1g;   咨询
储存:室温, 惰性气体
状态:黄色粉末或晶体
B2694TCIBathocuproine (purified by sublimation)>99.0%(T)(HPLC)1550元/1G;   咨询

基本信息

纯度/分析方法>99.0%(T)(HPLC)
分子式/分子量C26H20N2 = 360.46
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
包装和容器 1G-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN306714
PubChem物质ID87558362
SDBS (AIST Spectral DB)11056
MDL编号MFCD00004972

技术规格

AppearanceLight yellow to Yellow to Green powder to crystal
Purity(HPLC)min. 99.0 area%
Purity(Nonaqueous Titration)min. 99.0 %

物性(参考值)

熔点283 ℃
水溶性实际上不溶
溶解性(可溶于)甲醇,苯,乙醇,丙酮

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H413 : 可能对水生生物造成长期持续有害影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
D0711TCIBathocuproine>95.0%(T)(HPLC)740元/1G;   2530元/5G;   咨询

基本信息

纯度/分析方法>95.0%(T)(HPLC)
分子式/分子量C26H20N2 = 360.46
外观与形状(20℃)固体
Reaxys-RN306714
PubChem物质ID87567349
SDBS (AIST Spectral DB)11056
MDL编号MFCD00004972

技术规格

AppearanceWhite to Light yellow to Green powder to crystaline
Purity(Nonaqueous Titration)min. 95.0 %

物性(参考值)

熔点283 ℃
水溶性实际上不溶
溶解性(可溶于)丙酮,乙醇,甲醇,苯

安全信息

图形或危害标志
信号词警告
危险性说明H302 : 吞咽有害。
H413 : 可能对水生生物造成长期持续有害影响。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P270 : 使用本产品时不要进食、饮水或吸烟。
P264 : 作业后彻底清洗皮肤。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
231472J&KBathocuproine99%630元/1G;   2299元/5G;   咨询

基本信息

分子式C26H20N2
分子量360.46
熔点279-283
MDL编码MFCD00004972
Beilstein306714
EINECS 编号225-240-5

安全信息

图形或危害标志
提示语Warning
危险说明H302
H413
防范说明P280
P305+P351+P338
WGK3
TSCA
986236J&K2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline99.5%, 用于钙钛矿太阳能电池9323元/10G;   咨询
B22841Alfa AesarBathocuproin98%1127元/1g;   3775元/5g;   咨询

应用
It is used as a reagent for the determination of copper. It acts as an exciton blocking barrier which prohibits excitons diffusion process towards the Al electrode otherwise being quenched. It is the most commonly used buffer layer between acceptor and cathode layer.

备注
Store in cool, dry conditions in a sealed container. Store away from oxidizing agents.

基本信息

MDL
MFCD00004972

EINECS
225-240-5

分子式
C26H20N2

分子量
360.46

熔点
279-285°

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in methanol (36mg/100ml), ethanol, 2-propanol, bezene, and acetone. Partly miscible in water.

Beilstein
306714

GHS危害和防范说明

GHS符号

Hazard Statements
H302
Harmful if swallowed.

Precautionary Statements
P264-P270-P301+P312a-P330-P501a
Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Do not eat, drink or smoke when using this product.Rinse mouth.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22
Harmful if swallowed.

安全等级
36-60
Wear suitable protective clothing.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

140910Sigma-AldrichBathocuproine96%790.18元/500 MG;   1282.52元/1 G;   咨询

基本信息

经验(实验)分子式C26H20N2
分子量360.45
Beilstein306714
EC 号225-240-5
MDL编号MFCD00004972
PubChem化学物质编号24848482
NACRESNA.23

产品性质

测定96%
形式powder
mp279-283 ℃ (lit.)
λmax~280 nm in methanol
轨道能量HOMO 7 eV 
LUMO 3.5 eV 
OLED设备性能ITO/CuPc/NPD/TCTA/mCP:FIrpic (6%)/BCP/LiF/Al
  • Color: blue
  • Max. EQE: 4.2 %

ITO/NPD/CBP:Ir(ppy)3/BCP/Alq3/Mg:Al
  • Color: green
  • Max. Luminance: 100000 Cd/m2
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V

ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: red
  • Max. Luminance: 24529 Cd/m2
  • Max. EQE: 17 %
  • Turn-On Voltage: 2.7 V

ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: green
  • Max. Luminance: 207839 Cd/m2
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V
SMILES stringCc1cc(-c2ccccc2)c3ccc4c(cc(C)nc4c3n1)-c5ccccc5
InChI1S/C26H20N2/c1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17/h3-16H,1-2H3
InChI keySTTGYIUESPWXOW-UHFFFAOYSA-N

安全信息

危险声明H413
预防措施声明P273
危险分类Aquatic Chronic 4
储存分类代码11 - Combustible Solids
WGKWGK 3
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
699152Sigma-AldrichBathocuproinesublimed grade, 99.99% trace metals basis2399.52元/500 MG;   16341.5元/5 G;   咨询

产品说明

一般描述

TGA/DSC Lot specific scans available upon request

包装

5 g in glass bottle
500 mg in glass insert

应用

可用作 OLED 电子传输层和空穴阻挡层的有机电子材料。

基本信息

经验(实验)分子式C26H20N2
分子量360.45
Beilstein306714
EC 号225-240-5
MDL编号MFCD00004972
PubChem化学物质编号329762113
NACRESNA.23

产品性质

等级sublimed grade
质量水平200
测定99.99% trace metals basis
mp279-283 ℃ (lit.)
285 ℃ (DSC)
λmax277 nm
荧光λem 386 nm in THF
轨道能量HOMO 7 eV 
LUMO 3.5 eV 
OLED设备性能ITO/CuPc/NPD/TCTA/mCP:Firpic (6%)/BCP/LiF/Al
  • Color: blue
  • Max. EQE: 4.2 %

ITO/NPD/CBP:Ir(ppy)3/BCP/Alq3/Mg:Al
  • Color: green
  • Max. Luminance: 100000 Cd/m2
  • Max. EQE: 8 %
  • Turn-On Voltage: 4.3 V

ITO/NPD/TCTA/BCPO:Ir(piq)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: red
  • Max. Luminance: 24529 Cd/m2
  • Max. EQE: 17 %
  • Turn-On Voltage: 2.7 V

ITO/NPD/TCTA/BCPO:Ir(ppy)3 (7-8%)/BCP/Alq3/LiF/Al
  • Color: green
  • Max. Luminance: 207839 Cd/m2
  • Max. EQE: 21.6 %
  • Turn-On Voltage: 2.1 V
SMILES stringCc1cc(-c2ccccc2)c3ccc4c(cc(C)nc4c3n1)-c5ccccc5
InChI1S/C26H20N2/c1-17-15-23(19-9-5-3-6-10-19)21-13-14-22-24(20-11-7-4-8-12-20)16-18(2)28-26(22)25(21)27-17/h3-16H,1-2H3
InChI keySTTGYIUESPWXOW-UHFFFAOYSA-N

安全信息

危险声明H413
预防措施声明P273
危险分类Aquatic Chronic 4
储存分类代码11 - Combustible Solids
WGKWGK 3
个人防护装备dust mask type N95 (US), Eyeshields, Faceshields, Gloves
235890Fluorochem2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline98%748元/1g;   2662元/5g;   4488元/10g;   8492元/25g;   咨询

基本信息

CAS Number4733-39-5
MDL NumberMFCD00004972
Melting Point279-283℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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