| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| T819087 | MACKLIN | 三正辛基膦 | 90% | 47元/5ml; 141元/25ml; 522元/100ml; 2396元/500ml; 7915元/2.5L; | 咨询 |
储存：室温, 惰性气体保存 状态：无色到黄色或橙色到淡棕色液体 折射率：n20/D 1.468(lit.) |
| T769218 | MACKLIN | 三正辛基膦 | 85% | 133元/25ml; 514元/100ml; 2221元/500ml; | 咨询 |
储存：室温, 惰性气体保存 状态：无色至黄色或橙色至浅棕色液体 折射率：n20/D 1.468(lit.) |
| T0503 | TCI | Tri-n-octylphosphine | >85.0%(GC) | 530元/25ML; 1295元/100ML; 4360元/500ML; | 咨询 |
基本信息 | 纯度/分析方法 | >85.0%(GC) | | 分子式/分子量 | C24H51P = 370.65 | | 外观与形状(20℃) | 液体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气 | | Reaxys-RN | 1776995 | | PubChem物质ID | 87576433 | | SDBS (AIST Spectral DB) | 7687 | | MDL编号 | MFCD00015298 |
技术规格 | Appearance | Colorless to Almost colorless clear liquid | | Purity(GC) | min. 85.0 % |
物性(参考值) | 沸点 | 234 ℃/1 mmHg | | 闪点 | 147 ℃ | | 比重 | 0.83 | | 折射率 | 1.47 | | 水溶性 | 不溶 |
安全信息 | 图形或危害标志 |   | | 信号词 | 危险 | | 危险性说明 | H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
H314 : 造成严重皮肤灼伤和眼损伤。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。
P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。
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相关法规 运输信息 | UN编号 | UN1760 | | 类别 | 8 | | 包装类别 | II | | 监管条件代码(*) | |
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| 963097 | J&K | Tri-n-octylphosphine | 90%, 工业级 | 472元/25ML; 1509元/100ML; | 咨询 |
基本信息 | 分子式 | C24H51P | | 分子量 | 370.64 | | 沸点 | 240 | | 闪点 | 147 | | 密度 | 0.831 | | 折光率(n20D) | 1.468 | | MDL编码 | MFCD00015298 | | Beilstein | 1776995 | | EINECS 编号 | 225-234-2 |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H314 | | 防范说明 | P280
P301+P330+P331
P303+P361+P353
P305+P351+P338 | | UN号码 | 1760 | | 危险分类 | 8 | | 包装等级 | II | | WGK | 2 | | RTECS | SZ3450000 |
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| 15-6655 | Strem | Tri-n-octylphosphine | min. 97% | 735元/25g; 1515元/100g; 5805元/500g; | 咨询 |
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| 15-6665 | Strem | Tri-n-octylphosphine | min. 90% | 1418元/100g; 5672元/500g; | 咨询 |
Technical Notes: 1.Ligand used in the manufacture of nanocrystals, specifically quantum dots.1 2.A General Phosphorus Source for the L ow-Temperature Conversion of Metals into Metal Phosphides.2 3.Raw material for chalcogenidesTOP=E(E= o,s, Se), used for II-VI semiconductor nanoparticles such as CdSe and CdTe, and IV-VI nanoparticles, such as PbSe. References: 1.Physika E.2017.90 175-182. 2.Chem. Mater. 2007. 19.17. 4234 4242 . 3.Mater. c hem.2010.20. 5797-5809. |
| L15744 | Alfa Aesar | Tri-n-octylphosphine | tech. 90% | 686元/25ml; 2156元/100ml; 7713元/500ml; | 咨询 |
应用
Tri-n-octylphosphine is used for coating zinc sulfide shells on cadmium-selenium quantum dot core by successive ionic layer adsorption and reaction method. It acts as a precursor to trioctylphosphine oxide. Further, it is used as a solvent for cadmium and selenium precursors. It also serves as a common reagent in the chemical synthesis of nanoparticles. It acts as a precursor to trioctylphosphine oxide. 备注
Air sensitive. Incompatible with strong oxidizing agents. 基本信息 MDL
MFCD00015298 EINECS
225-234-2 分子式
C24H51P 分子量
370.65 沸点
240°/10mm 闪点
147°(296°F) 密度
0.831 折射率
1.4680 灵敏度
Air Sensitive. Store under Nitrogen. Ambient temperatures. 形态
Liquid 溶解性
Immiscible with water. Beilstein
1776995 GHS危害和防范说明 GHS符号
Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage. Precautionary Statements
P280-P303+P361+P353-P305+P351+P338-P310a
Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 安全信息 危险等级
8 包装组
II 危险类别
34
Causes burns. 安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste 欧盟危险品标志
 RTECS
SZ3450000 TSCA
是 |
| C43646 | Alfa Aesar | Trioctylphosphine | 90%, technical grade, AcroSeal™ | 2351元/100ml; | 咨询 |
基本信息 Ref#
43646 MDL
15298 分子式
C24 H51 P 分子量
370.64 闪点
147 密度
0.831 形态
Liquid 安全信息 危险等级
8 包装组
II |
| 718165 | Sigma-Aldrich | Trioctylphosphine | 97% | 2887.6元/100 ML; 9367.85元/500 ML; 22305.5元/2 L; | 咨询 |
产品说明 应用 三辛基膦可用于金属纳米晶、块状粉体、箔、线、薄膜向金属磷化物的转化。它还可以作为由醋酸镉和硫中合成硫化镉纳米棒反应的溶剂和稳定剂。 包装 100, 500 mL in Sure/Seal™
2 L in Sure/Seal™ 基本信息 | 线性分子式 | [CH3(CH2)7]3P | | 分子量 | 370.64 | | Beilstein | 1776995 | | EC 号 | 225-234-2 | | MDL编号 | MFCD00015298 | | PubChem化学物质编号 | 329763556 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 97% | | 形式 | liquid | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand | | 折射率 | n20/D 1.468 (lit.) | | bp | 284-291 ℃/50 mmHg (lit.) | | 密度 | 0.831 g/mL at 25 ℃ (lit.) | | 官能团 | phosphine | | SMILES string | CCCCCCCCP(CCCCCCCC)CCCCCCCC | | InChI | 1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3 | | InChI key | RMZAYIKUYWXQPB-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H314 | | 预防措施声明 | P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338 | | 危险分类 | Eye Dam. 1 - Skin Corr. 1B | | 储存分类代码 | 8A - Combustible, corrosive hazardous materials | | WGK | WGK 2 | | 闪点(F) | 296.6 °F - closed cup | | 闪点(C) | 147 ℃ - closed cup |
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| 117854 | Sigma-Aldrich | Trioctylphosphine | technical grade, 90% | 2033.46元/4 X 25 ML; 2307.4元/100 ML; 5505.51元/500 ML; 19634.3元/2.5 L; | 咨询 |
产品说明 应用 三辛基膦能将金属纳米晶体，大体积粉末，箔片，线状，薄膜转化为金属磷化物。它还可用作硫和乙酸镉合成硫化镉纳米棒的溶剂和稳定剂。 包装 2.5 L in Sure/Seal™
4×25, 100, 500 mL in Sure/Seal™
建议将25 mL Sure/Seal™ 瓶作为一次性瓶使用。 反复穿刺可能会导致产品性能下降。 法律信息 Sure/Seal is a trademark of sigma-aldrich Co. LLC 基本信息 | 线性分子式 | [CH3(CH2)7]3P | | 分子量 | 370.64 | | Beilstein | 1776995 | | EC 号 | 225-234-2 | | MDL编号 | MFCD00015298 | | PubChem化学物质编号 | 24847349 | | NACRES | NA.22 |
产品性质 | 等级 | technical grade | | 测定 | 90% | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand | | 折射率 | n20/D 1.468 (lit.) | | bp | 284-291 ℃/50 mmHg (lit.) | | 密度 | 0.831 g/mL at 25 ℃ (lit.) | | 官能团 | phosphine | | SMILES string | CCCCCCCCP(CCCCCCCC)CCCCCCCC | | InChI | 1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3 | | InChI key | RMZAYIKUYWXQPB-UHFFFAOYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H314 | | 危险分类 | Skin Corr. 1B | | 储存分类代码 | 8A - Combustible, corrosive hazardous materials | | WGK | WGK 2 | | 闪点(F) | 296.6 °F - closed cup | | 闪点(C) | 147 ℃ - closed cup | | 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
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| 324041 | Fluorochem | Trioctylphosphine | 85% | 748元/25ml; 1826元/100ml; 6600元/500ml; | 咨询 |
基本信息 | CAS Number | 4731-53-7 | | MDL Number | MFCD00015298 | | Boiling Point | 234℃ | | Density | 0.83 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H302: Harmful if swallowed.
H312: Harmful in contact with skin.
H314: Causes severe skin burns and eye damage.
H332: Harmful if inhaled.
| | 防范说明 | P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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