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CAS: 446-52-6
分子式: C7H5FO
分子量: 124.12
沸点: 172-174℃
熔点: -44.5℃
中文名称: 
邻氟苯甲醛
2-氟苯甲醛
英文名称: 
2-fluoro-benzaldehyd
2-fluorobenzaldehyde
o-fluorobenzaldehyde
性质描述: 无色至淡黄色透明液体。熔点-44.5℃,沸点90 - 91℃(46mmHg),闪点55℃,相对密度1.178。
用途: 用作农药、医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
F809586MACKLIN2-氟苯甲醛98%28元/5g;   32元/25g;   56元/100g;   201元/500g;   947元/2.5kg;   咨询
储存:室温,易燃物区域
状态:无色到浅黄色液体
折射率:n20/D 1.521(lit.)
F742905MACKLIN2-氟苯甲醛Standard for GC, ≥99.8%(GC)128元/1g;   咨询
储存:室温, 易燃物区域
状态:液体
F0190TCI2-Fluorobenzaldehyde>98.0%(GC)290元/25ML;   850元/100ML;   1690元/250ML;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C7H5FO = 124.11
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN507155
PubChem物质ID87569973
SDBS (AIST Spectral DB)4316
MDL编号MFCD00003302

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

熔点-45 ℃
沸点175 ℃
闪点55 ℃
比重1.19
折射率1.52

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H226 : 易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。

相关法规

RTECS#CU6140000

运输信息

UN编号UN1989
类别3
包装类别 III
监管条件代码(*)
360587J&K2-Fluorobenzaldehyde97%64元/25G;   210元/100G;   655元/500G;   咨询

基本信息

分子式C7H5FO
分子量124.11
熔点-45
沸点172-174
闪点55
密度1.178
折光率(n20D)1.5205-1.5225
MDL编码MFCD00003302
Beilstein507155
EINECS 编号207-171-2

安全信息

图形或危害标志
提示语Warning
危险说明H226
H315
H319
H335
防范说明P261
P305+P351+P338
UN号码1989
危险分类3
包装等级III
WGK3
RTECSCU6140000
TSCA
A13800Alfa Aesar2-Fluorobenzaldehyde97%312元/5g;   1063元/25g;   3063元/100g;   13093元/500g;   咨询

应用
2?-(2-Fluorobenzylidene)-2-hydroxybenzohydrazide was synthesized by the reaction of 2-hydroxybenzoylhydrazine with 2-fluorobenzaldehyde in ethanol. Synthesis of n-aryl indolines from 2-fluorobenzaldehyde dimethylhydrazone derivatives which is an approach to preparation of c(aryl)-n(amine) bond atropisomeric amines. The o-dialkylaminobenzaldehydes were conveniently prepared by nucleophilic displacement of the activated fluorine in 2-fluorobenzaldehyde with the required dialkylamine in hot dimethylformamide. N?-(2-Fluorobenzylidene)-2-(quinolin-8-yloxy) acetohydrazide methanol solvate in the reaction of quinolin-8-yloxyacetic acid hydrazide and 2-fluorobenzaldehyde.

备注
Air Sensitive.Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, reducing agents, air, bases.

基本信息

MDL
MFCD00003302

EINECS
207-171-2

分子式
C7H5FO

分子量
124.11

熔点
-45°

沸点
172-174°

闪点
55°(131°F)

密度
1.180

折射率
1.5220

灵敏度
Air Sensitive. Store under Argon. Ambient temperatures.

形态
Liquid

溶解性
Insoluble in water.

Beilstein
507155

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H302-H315-H319-H335
Flammable liquid and vapour.Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-22-36/37/38
Flammable.Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
23-26-36/37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
CU6140000

TSCA

C11932Alfa Aesar2-Fluorobenzaldehyde97%858元/25ml;   2708元/100ml;   咨询

基本信息

Ref#
11932

MDL
3302

分子式
C7 H5 F O

分子量
124.11

闪点
55

密度
1.17

安全信息

危险等级
3

包装组
III

001671Fluorochem2-Fluorobenzaldehyde97%616元/100g;   1210元/250g;   咨询

基本信息

CAS Number446-52-6
MDL NumberMFCD00003302
Boiling Point90-91℃
Melting Point-44.5℃
Density1.178

安全信息

图形或危害标志
危险性说明 H226: Flammable liquid and vapour.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P210: Keep away from – No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P370 + P378: In case of fire: Use sand, CO2 or powdered extinguishing agent for extinction.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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