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CAS: 41203-22-9
分子式: C14H32N4
分子量: 256.43
熔点: 41-43℃
中文名称: 
1,4,8,11-四甲基-1,4,8,11-四氮环十四烷
1-氟-四氟烯
英文名称: 
1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane
推荐供应商
货号品牌产品名称规格包装、参考价格
T819670MACKLIN1,4,8,11-四甲基-1,4,8,11-四氮杂环十四烷98%229元/200mg;   623元/1g;   2510元/5g;   咨询
储存:室温,干燥
状态:白色到几乎白色粉末到晶体
T1877TCI1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane>98.0%(GC)(T)490元/200MG;   1650元/1G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C14H32N4 = 256.44
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿),加热
Reaxys-RN1210788
PubChem物质ID253662392
MDL编号MFCD00005106

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(GC)min. 98.0 %
Purity(Neutralization titration)min. 98.0 %
Melting point38.0 to 42.0 ℃

物性(参考值)

熔点40 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#XA5255700
07-2112Strem1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane98%2115元/1g;   8445元/5g;   咨询
030854Alfa Aesar1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane7229元/1g;   咨询

应用
1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane is used as a macrocyclic chelating agent in coordination chemistry. It is also used as a ligand which bind strongly to a wide range of metal ions and as crown ethers.

备注
Moisture sensitive. Hygroscopic. Incompatible with strong oxidizing agents and strong acids.

基本信息

MDL
MFCD00005106

分子式
C14H32N4

分子量
256.43

熔点
34-36°

闪点
>110°(230°F)

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA

282804Sigma-Aldrich1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane98%2809.43元/1 G;   咨询

基本信息

经验(实验)分子式C14H32N4
分子量256.43
Beilstein1210788
MDL编号MFCD00005106
PubChem化学物质编号24857072

产品性质

质量水平100
测定98%
mp38-42 ℃ (lit.)
SMILES stringCN1CCCN(C)CCN(C)CCCN(C)CC1
InChI1S/C14H32N4/c1-15-7-5-8-17(3)13-14-18(4)10-6-9-16(2)12-11-15/h5-14H2,1-4H3
InChI keyHRFJEOWVAGSJNW-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)230.0 °F - closed cup
闪点(C)110 ℃ - closed cup
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
403695Fluorochem1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecane973564元/1g;   咨询

基本信息

CAS Number41203-22-9
MDL NumberMFCD00005106

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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