| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| R813729 | MACKLIN | (|R|)-(-)-α-甲氧基-α-(三氟甲基)苯乙酰氯 | 99% | 369元/50mg; 1102元/250mg; 4298元/1g; | 咨询 |
储存：-20°C, 干燥, 惰性气体 状态：无色到浅黄色到黄色液体 折射率：n20/D 1.469(lit.) |
| M1104 | TCI | (R)-(-)-α-Methoxy-α-(trifluoromethyl)phenylacetyl Chloride [for Determination of the optical purity of Alcohols and Amines] | >98.0%(GC)(T) | 995元/100MG; 4130元/1G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(GC)(T) | | 分子式/分子量 | C10H8ClF3O2 = 252.62 | | 外观与形状(20℃) | 液体 | | 储存温度 | 0-10℃ | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 湿气 (分解),加热 | | Reaxys-RN | 3591565 | | PubChem物质ID | 87573070 | | MDL编号 | MFCD00044400 |
技术规格 | Appearance | Colorless to Almost colorless clear liquid | | Purity(GC) | min. 98.0 % | | Optical purity(GC) | min. 99.0 ee% | | Functionality test | to pass test |
物性(参考值) | 沸点 | 99 ℃/12 mmHg | | 闪点 | 89 ℃ | | 比重 | 1.35 | | 比旋光度 [α]D | -149° (C=2,Toluene) | | 折射率 | 1.47 |
安全信息 | 图形或危害标志 |  | | 信号词 | 危险 | | 危险性说明 | H314 : 造成严重皮肤灼伤和眼损伤。
H227 : 可燃液体。
H290 : 可能腐蚀金属。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。
P390 : 吸收溢出物，防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。
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运输信息 | UN编号 | UN3265 | | 类别 | 8 | | 包装类别 | III | | 监管条件代码(*) | |
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| 902220 | J&K | (R)-(-)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride | 99%, 18wt.%二氯甲烷溶液 | 1212元/250MG; 2717元/1G; | 咨询 |
基本信息 | 分子式 | C10H8ClF3O2 | | 分子量 | 252.62 | | MDL编码 | MFCD00044400 | | Beilstein | 359156 | | 存储条件 | Freezer -20℃ |
安全信息 | 图形或危害标志 |    | | 提示语 | Danger | | 危险说明 | H290
H302
H314
H336
H351
H370
H372
H411 | | 防范说明 | P201
P202
P234
P260
P264
P270
P271
P273
P280
P303+P361+P353+P310+P363 | | UN号码 | 3265 | | 危险分类 | 8 | | 包装等级 | III | | WGK | 3 |
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| L14325 | Alfa Aesar | (R)-(-)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetyl chloride | 98+% | 596元/50mg; 2451元/250mg; 6949元/1g; | 咨询 |
应用
(R)-(-)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride is used as a chiral acylating reagent, which is used in the resolution of amino acid enantiomers like 2,5-dimethoxy-4-methylamphetamine. It is also suitable for the determination of the optical composition of compounds extracted from biological fluids. 备注
Moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. 基本信息 MDL
MFCD00044400 分子式
C10H8ClF3O2 分子量
252.62 沸点
213-214° 闪点
89°(192°F) 密度
1.353 折射率
1.4690 灵敏度
Store at -20°C. Moisture Sensitive. Store under Nitrogen. 形态
Liquid 溶解性
Sparingly miscible with water. Beilstein
3591565 Merck
14,6280 GHS危害和防范说明 GHS符号
Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage. Precautionary Statements
P210e-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. 安全信息 危险等级
8 包装组
II 危险类别
34
Causes burns. 安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste 欧盟危险品标志
 TSCA
否 |
| C26412 | Alfa Aesar | (R)-(-)-alpha-Methoxy-alpha-(trifluoromethyl)phenylacetyl chloride | 99% | 3105元/250mg; 8783元/1g; | 咨询 |
基本信息 Ref#
26412 MDL
44400 分子式
C10 H8 Cl F3 O2 分子量
252.62 闪点
90 密度
1.34 形态
Colorless liquid 安全信息 危险等级
8 包装组
II |
| 65363 | Supelco | (R)-(-)-α-Methoxy-α-(trifluoromethyl)phenylacetyl chloride | for chiral derivatization, LiChropur™, ≥99.0% | 1824.18元/100 MG; 7208.26元/500 MG; | 咨询 |
产品说明 一般描述 (R)-(-)-a-甲氧基-a-(三氟甲基)苯乙酰氯 (Mosher′s acid chloride)通常被用作手性衍生剂。本品通常以对映体纯形式提供。它能够与醇和胺形成非对映异构体。 应用 它是一种即用型试剂，用于测定衍生化后醇类和胺类的对映体纯度；doi:10.1038/nprot.2007.354
它被用于衍生化D-阿拉伯糖醇和L-阿拉伯糖醇样品，以便通过高效薄层色谱(HPTLC)分析研究非对映异构体的拆分。 包装 100, 500 mg in glass bottle
无底玻璃瓶。内含物装在插入的融合锥内。 其他说明 请注意，R(-)-MTPA-Cl衍生自S(-)-MTPA 推荐产品 探索最适于 HPLC 或 LC-MS 分析的 LiChropur 试剂 法律信息 ChiraSelect is a trademark of sigma-aldrich Co. LLC
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany 基本信息 | 线性分子式 | C6H5C(OCH3)(CF3)COCl | | 分子量 | 252.62 | | Beilstein | 3591563 | | MDL编号 | MFCD00044400 | | PubChem化学物质编号 | 329760054 |
产品性质 | 质量水平 | 100 | | 等级 | for chiral derivatization | | 产品线 | ChiraSelect™ | | 测定 | ≥99.0% (AT)
≥99.0% | | 旋光性 | [α]20/D −137±2°, c = 6.4% in carbon tetrachloride | | 光学纯度 | enantiomeric ratio: ≥99.5:0.5 (GC) | | 质量 | LiChropur™ | | technique(s) | HPLC: suitable | | 折射率 | n20/D 1.469
n20/D 1.47 (lit.) | | bp | 213-214 ℃ (lit.) | | 密度 | 1.35 g/mL at 25 ℃ (lit.) | | 运输 | wet ice | | 储存温度 | −20℃ | | SMILES string | CO[C@](C(Cl)=O)(c1ccccc1)C(F)(F)F | | InChI | 1S/C10H8ClF3O2/c1-16-9(8(11)15,10(12,13)14)7-5-3-2-4-6-7/h2-6H,1H3/t9-/m0/s1 | | InChI key | PAORVUMOXXAMPL-VIFPVBQESA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H314 | | 预防措施声明 | P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 | | 危险分类 | Skin Corr. 1B | | 储存分类代码 | 8A - Combustible, corrosive hazardous materials | | WGK | WGK 3 | | 闪点(F) | 192.2 °F - closed cup | | 闪点(C) | 89 ℃ - closed cup | | 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
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| 009428 | Fluorochem | (R)-(-)-a-Methoxy-a-trifluoromethylphenylacetyl chloride | 98% | 1276元/250mg; 2860元/1g; | 咨询 |
基本信息 | CAS Number | 39637-99-5 | | MDL Number | MFCD00044400 | | Boiling Point | 213-214℃ | | Density | 1.35 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H314: Causes severe skin burns and eye damage.
| | 防范说明 | P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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