CAS 39085-59-1; 2,4,6-三异丙基苯磺酰基肼; 2,4,6-Triisopropylbenzenesulfonohydrazide

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货号

品牌

产品名称

规格

包装、参考价格

T824065

MACKLIN

2,4,6-三异丙基苯磺酰基肼

97%

30元/1g; 130元/5g; 628元/25g;

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储存：2-8 °C, 密封, 干燥, 避光
状态：白色粉末

T1591

TCI

2,4,6-Triisopropylbenzenesulfonyl Hydrazide

>95.0%(T)

350元/5G; 1490元/25G;

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基本信息

纯度/分析方法	>95.0%(T)
分子式/分子量	C₁₅H₂₆N₂O₂S = 298.45
外观与形状(20℃)	固体
储存温度	<0℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气,加热
Reaxys-RN	2145001
PubChem物质ID	87577348
MDL编号	MFCD00014750

技术规格

Appearance	White to Almost white powder to crystal
Purity(Potassium bromate Method)	min. 95.0 %

物性(参考值)

熔点	122 ℃(dec.)

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。 H228 : 易燃固体。
防范说明	P240 : 容器和装载设备接地/等势联接。 P210 : 远离热源/火花/明火/热表面。禁止吸烟。 P241 : 使用防爆的电气/通风/照明设备。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

运输信息

UN编号	UN1325
类别	4.1
包装类别	III
监管条件代码(*)

487192

J&K

2,4,6-Triisopropylbenzenesulfonyl Hydrazide

95%

282元/1G; 1126元/5G; 3990元/25G;

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基本信息

分子式	C₁₅H₂₆N₂O₂S
分子量	298.45
熔点	110-112
MDL编码	MFCD00014750
Beilstein	2145001
EINECS 编号	254-282-7
存储条件	Freezer -20℃

安全信息

防范说明	P262
WGK	3
TSCA	否

017976

Alfa Aesar

2,4,6-Triisopropylbenzenesulfonyl Hydrazide

895元/0.5g; 3308元/2g;

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应用
As a reagent for generation of diimide

基本信息

MDL
MFCD00014750

EINECS
254-282-7

分子式
C₁₅H₂₆N₂O₂S

分子量
298.58

熔点
110-112° dec.

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Crystalline

Beilstein
2145001

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

TSCA
否

192198

Sigma-Aldrich

2,4,6-Triisopropylbenzenesulfonyl Hydrazide

90%

1278.02元/1 G; 1650.22元/5 G;

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产品说明

应用

2,4,6-Triisopropylbenzenesulfonyl hydrazide (TPSH) is a best source of diazene. It can be used as a selective reducing agent for the reduction of alkenes and other double bonds via in situ formation of diazene (diimide) in the presence of base. TPSH reduction method is efficiently used in the synthesis of polymers and natural products as it tolerates sensitive groups such as esters, ketones, or organometal complexes. It also undergoes condensation reaction with ketones and aldehydes to produce corresponding hydrazones that can be converted into reactive intermediates such as diazoalkanes, carbenes, carbenium ions, and alkyllithiums.
It can be used as a reagent to synthesize:

Nitrogen-containing polycyclic compounds by intramolecular cyclopropanation of N-alkyl indoles/pyrroles.
Vinyl sulfones by sulfonylation reaction of vinyl bromides.
Nitrile derivatives from carbonyl compounds via formation of corresponding hydrazones.

包装

1, 5 g in glass bottle

基本信息

线性分子式	[(CH₃)₂CH]₃C₆H₂SO₂NHNH₂
分子量	298.44
Beilstein	2145001
EC 号	254-282-7
MDL编号	MFCD00014750
PubChem化学物质编号	24851533
NACRES	NA.22

产品性质

质量水平	100
测定	90%
形式	powder
mp	110-112 ℃ (dec.) (lit.)
储存温度	−20℃
SMILES string	CC(C)c1cc(C(C)C)c(c(c1)C(C)C)S(=O)(=O)NN
InChI	1S/C15H26N2O2S/c1-9(2)12-7-13(10(3)4)15(20(18,19)17-16)14(8-12)11(5)6/h7-11,17H,16H2,1-6H3
InChI key	UGRVYFQFDZRNMQ-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

223474

Fluorochem

2,4,6-Triisopropylbenzenesulfonohydrazide

95%

484元/1g; 1408元/5g; 2354元/10g; 4686元/25g;

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基本信息

CAS Number	39085-59-1
MDL Number	MFCD00014750
Melting Point	122℃

安全信息

图形或危害标志
危险性说明	H228: Flammable solid. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P370 + P378: In case of fire: Use for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .