CAS 389130-06-7; (11bs)-n,n-二甲基-8,9,10,11,12,13,14,15-八氢二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-胺; monophos ligand

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CAS:

389130-06-7

分子式:

C₂₂H₂₈NO₂P

分子量:

369.4

熔点:

86-94°C

中文名称:

(11bs)-n,n-二甲基-8,9,10,11,12,13,14,15-八氢二萘并[2,1-d:1′,2′-f][1,3,2]二噁磷杂庚英-4-胺

(11bs)-n,n-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine

英文名称:

monophos ligand

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

S853919

MACKLIN

(11bS)-8,9,10,11,12,13,14,15-八氢-N,N-二甲基-联萘并[2,1-d:1',2'-f][1,3,2]二氧膦杂-4-胺

98%,99%e.e.

270元/100mg; 572元/250mg; 1877元/1g;

咨询

储存：室温,干燥
状态：白色固体

15-3495

Strem

(S)-(+)-(8,9,10,11,12,13,14,15-Octahydro-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine

99%

1635元/100mg; 6045元/500mg;

咨询

685569

Sigma-Aldrich

(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine

1184.6元/100 MG;

咨询

产品说明

应用

(11bS)-N,N-dimethyl-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine is a monodentate phosphoramidite (MonoPhos) chiral ligand that can be used:

In the Cu-catalyzed synthesis of chiral 3-(arylbut-1-yn-1-yl)silane derivatives by reacting N-tosylhydrazones with silyl-substituted alkynes via asymmetric insertion.
In the Rh-catalyzed asymmetric hydrogenation of R-isopropylcinnamic acid derivative, a key intermediate of renin inhibitor aliskiren.
In the Rh-catalyzed conjugate addition of arylboronic acids to lactones, enones, and nitroalkenes.

DSM MonoPhos Family of Highly Efficient Privileged Ligands

包装

100 mg in clear glass bottle
500 mg in amber glass bottle

法律信息

经 DSM 授权销售，仅供研究之用。

基本信息

经验(实验)分子式	C₂₂H₂₆NO₂P
分子量	367.42
MDL编号	MFCD04117692
PubChem化学物质编号	329760980
NACRES	NA.22

产品性质

旋光性	[α]22/D 282.0°, c = 1 in chloroform
mp	86-94 ℃
SMILES string	CN(C)P1Oc2ccc3CCCCc3c2-c4c(O1)ccc5CCCCc45
InChI	1S/C22H26NO2P/c1-23(2)26-24-19-13-11-15-7-3-5-9-17(15)21(19)22-18-10-6-4-8-16(18)12-14-20(22)25-26/h11-14H,3-10H2,1-2H3
InChI key	OIZQADYWBXZQKE-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

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