CAS 38465-86-0; 1,5-环辛二烯双(甲基联苯基磷化氢)铱六氟磷酸盐; 1,5-cyclooctadienebis(methyldiphenylphosphine)iridium hexafluorophosphate

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货号

品牌

产品名称

规格

包装、参考价格

C836494

MACKLIN

1,5-环辛二烯双(甲基联苯基磷化氢)铱六氟磷酸盐

97%

988元/50mg; 1452元/250mg; 3865元/1g;

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储存：室温,密封,干燥
状态：红色结晶粉末

018809

Alfa Aesar

1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate

0元/0.5g; 0元/2g;

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应用
1,5-Cyclooctadienebis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is used as a catalyst for isomerization of allylic ethers of glycerol and glucose to the corresponding 1-propenyl ethers. It is also used as a catalyst in hydrogenation reactions.

备注
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00064800

分子式
C₃₄H₃₈F₆IrP₃

分子量
845.79

熔点
224° dec.

灵敏度
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in acetone. Insoluble in water.

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
否

C37794

Alfa Aesar

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate

97%

2149元/250mg; 6003元/1g;

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基本信息

Ref#
37794

MDL
64800

分子式
C34 H38 Ir P2 . F6 P

分子量
845.81

安全信息

危险等级
6.1

包装组
III

337455

Sigma-Aldrich

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate

97%

448.49元/50 MG; 1476.46元/500 MG;

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产品说明

应用

(1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate is an air-stable cationic iridium complex, generally employed in allyl isomerization reactions. Upon bubbling hydrogen into the solution of [Ir(cod)(PPh₂Me)₂]PF₆, preferably in tetrahydrofuran, results in the formation of active catalyst [IrH₂(solv)₂(PPh₂Me)₂]PF₆ which can be used in the isomerization of 3-(silyloxy)-1-propenylboronates to (γ-(silyloxy)allyl)boronic esters; diallyl ethers to allyl (E)-vinyl ethers and 1-alkenylboronates to corresponding 3-alkoxyallylboronates.

包装

50, 500 mg in glass bottle

基本信息

经验(实验)分子式	C₃₄H₃₈F₆IrP₃
分子量	845.79
MDL编号	MFCD00064800
PubChem化学物质编号	24860482
NACRES	NA.22

产品性质

质量水平	100
测定	97%
reaction suitability	core: iridium reagent type: catalyst
mp	224 ℃ (dec.) (lit.)
SMILES string	[Ir+].F[P-](F)(F)(F)(F)F.C1CC=CCCC=C1.CP(c2ccccc2)c3ccccc3.CP(c4ccccc4)c5ccccc5
InChI	1S/2C13H13P.C8H12.F6P.Ir/c21-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2,3,4,5)6;/h22-11H,1H3;1-2,7-8H,3-6H2;;/q;;;-1;+1/b;;2-1-,8-7-;;
InChI key	LXKHQEQLBSJJCO-JXNOXZOESA-N

安全信息

象形图
警示用语：	Warning
危险声明	H302 + H312 + H332 - H315 - H319 - H335
预防措施声明	P261 - P280 - P301 + P312 - P302 + P352 + P312 - P304 + P340 + P312 - P305 + P351 + P338
危险分类	Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves