CAS 359803-53-5; 2'-(Dimethylamino)-2-biphenylyl-palladium(II)chloride Dinorbornylphosphine complex

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CAS:

359803-53-5

分子式:

C28H37ClNPPd

分子量:

560.45

熔点:

160℃

英文名称:

2'-(Dimethylamino)-2-biphenylyl-palladium(II)chloride Dinorbornylphosphine complex

Chloro-[2'-(dimethylamino)-2-biphenylyl]-(dinorbornylphosphine)-palladium

2'-(dimethylamino)-2-biphenylyl-palladium(ii) chloride dinorbornylphosphine complex

推荐供应商

货号

品牌

产品名称

规格

包装、参考价格

D921369

MACKLIN

氯-[2'-(二甲氨基)-2-联苯基]-(二去甲冰片基膦)-钯

≥99.0% (C)

2135元/1g;

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储存：室温
状态：Powder,beige

46-0270

Strem

Chloro(di-2-norbornylphosphino)(2'-dimethylamino-1,1'-biphenyl-2-yl)palladium (II)

min. 97%

1335元/250mg; 4005元/1g; 16035元/5g;

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Tochnical Note:

1. A new, air and moisture-stable,

palladium catalyst useful in a broad scope of C-C and C-N coupling reactions. The highly-active catalyst can tolerate substrates containing a wide variety of functional groups such as alkyls, alkoxides, ketones, aldehydes, esters, amines, trifluoromethyl and nitro groups.

References: 1. SolviasA.-G.. EP1 132361. 2. Angew. Chem. Int. Ed.. 2002. 41, 3668

36037

Sigma-Aldrich

2′-(Dimethylamino)-2-biphenylyl-palladium(II) chloride Dinorbornylphosphine complex

≥99.0% (C)

2418.21元/1 G;

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产品说明

包装

1, 5 g in glass bottle
Bottomless glass bottle. Contents are inside inserted fused cone.

其他说明

用于 C-C 和 C-N 偶联反应(如 Suzuki 偶联、Heck 反应等)的对空气和水分稳定的高活性钯催化剂

法律信息

与 Solvias AG 联合销售

基本信息

经验(实验)分子式	C₂₈H₃₇ClNPPd
分子量	560.45
MDL编号	MFCD03427335
PubChem化学物质编号	57649461
NACRES	NA.22

产品性质

质量水平	100
测定	≥99.0% (C)
reaction suitability	core: palladium reaction type: Buchwald-Hartwig Cross Coupling Reaction reaction type: Heck Reaction reaction type: Hiyama Coupling reaction type: Negishi Coupling reaction type: Sonogashira Coupling reaction type: Stille Coupling reaction type: Suzuki-Miyaura Coupling reagent type: catalyst
mp	160-170 ℃ (dec.) (lit.)
SMILES string	C1C[C@@H]2C[C@H]1CC2PC3C[C@@H]4CC[C@H]3C4.CN(C)c5ccccc5-c6ccccc6[Pd]Cl
InChI	1S/C14H14N.C14H23P.ClH.Pd/c1-15(2)14-11-7-6-10-13(14)12-8-4-3-5-9-12;1-3-11-5-9(1)7-13(11)15-14-8-10-2-4-12(14)6-10;;/h3-8,10-11H,1-2H3;9-15H,1-8H2;1H;/q;;;+1/p-1/t;9-,10+,11+,12-,13?,14?;;
InChI key	YMZCYRNVJBOOCT-SBADXZPPSA-M

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
个人防护装备	Eyeshields, Gloves, type N95 (US)

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