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CAS: 3518-65-8
分子式: CH2Cl2O2S
分子量: 149.00
沸点: 175°C
中文名称: 
氯甲烷硫酰氯
英文名称: 
Methanesulfonyl chloride,chloro-
chloro-methanesulfonyl chlorid
(chloromethyl)sulfonyl chloride
chlorid kyseliny chlormethansulfonove
chlormethansulfochlorid
chlormethansulfonylchlorid
chloromethanesulfonyl chloride
Chloromesyl chloride
Chloromethylsulfonyl Chloride
推荐供应商
货号品牌产品名称规格包装、参考价格
C836468MACKLIN氯甲基磺酰氯95%350元/1g;   1720元/5g;   8160元/25g;   咨询
储存:室温,密封,干燥
状态:无色到非常暗黄色和无色到非常深黄绿色到浅黄色到黄色到橙色液体
C708138MACKLIN氯甲基磺酰氯80%229元/1g;   740元/5g;   咨询
储存:室温,密封,干燥
C0924TCIChloromethylsulfonyl Chloride>80.0%(GC)810元/5G;   1990元/25G;   咨询

基本信息

纯度/分析方法>80.0%(GC)
分子式/分子量CH2Cl2O2S = 148.99
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (分解)
Reaxys-RN1811761
PubChem物质ID87565977
MDL编号MFCD00014727

技术规格

AppearanceLight yellow to Yellow to Orange clear liquid
Purity(GC)min. 80.0 %

物性(参考值)

沸点175 ℃
闪点73 ℃
比重1.67
折射率1.49

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H227 : 可燃液体。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

相关法规

RTECS#PB2800000

运输信息

UN编号UN3265
类别8
包装类别 II
监管条件代码(*)
041486Alfa AesarChloromethanesulfonyl Chloride98%738元/2g;   2944元/10g;   14315元/50g;   咨询

应用
It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dye stuff. It is synthesis of chloromethanesulfonates and chloromethanesulfonamides. It is also used for conversion of alcohols into the inverted acetates, azides and nitriles, and rearrangement of carbon-carbon and carbon-oxygen bonds under mild conditions, and in electrophilic and radical reactions.

备注
Moisture Sensitive. Stable under normal conditions. Store under nitrogen atmosphere and refrigerator.

基本信息

MDL
MFCD00014727

EINECS
222-526-1

分子式
CH2Cl2O2S

分子量
149.0

沸点
78-81°/20mm

密度
1.67

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Liquid

溶解性
It is soluble in dichloromethane, pyridine, and most organic solvents. It is insoluble in water.

Beilstein
1811761

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H314-H318
Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34
Harmful if swallowed.Causes burns.

安全等级
26-36/37/39-45-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

RTECS
PB2800000

TSCA

93479Sigma-AldrichChloromethanesulfonyl Chloridetechnical, ≥90% (AT)836.06元/5 G;   咨询

基本信息

线性分子式ClCH2SO2Cl
分子量149.00
Beilstein1811761
EC 号222-526-1
MDL编号MFCD00014727
PubChem化学物质编号57653562
NACRESNA.22

产品性质

质量水平100
等级technical
测定≥90% (AT)
形式liquid
密度1.64 g/mL at 20 ℃ (lit.)
储存温度−20℃
SMILES stringClCS(Cl)(=O)=O
InChI1S/CH2Cl2O2S/c2-1-6(3,4)5/h1H2
InChI keyKQDDQXNVESLJNO-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H302 - H314
预防措施声明P270 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
个人防护装备Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
120500FluorochemChloromethylsulphonyl chloride95%1188元/5g;   3630元/25g;   咨询

基本信息

CAS Number3518-65-8
MDL NumberMFCD00014727
Boiling Point175℃
Density1.67

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
防范说明 P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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