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CAS: 346457-41-8
分子式: C78H64Cl5NO8P4Ru2
分子量: 1646.65
中文名称: 
(r)-[(rucl(segphos®)2(μ-cl)3[nh2me2]
(r)-[(rucl(segphos®))2(μ-cl)3][nh2me2]
dimethylammonium dichlorotri(μ-chloro)bis[(r)-(+)-5,5′-bis(diphenylphosphino)-4,4′-bi-1,3-benzodioxole]diruthenate(ii)
二甲基铵二氯三(μ-氯)二[(r)-(+)-5,5′-二(二苯基膦基)-4,4′-联-1,3-苯并二噁唑]二钌酸盐(ii)
推荐供应商
货号品牌产品名称规格包装、参考价格
N868021MACKLIN[NH2Me2][(RuCl((R)-segphos))2(μ-Cl)3]≥95%369元/200mg;   咨询
储存：室温
N1021TCI[NH2Me2][(RuCl((R)-segphos?))2(μ-Cl)3]360元/200MG;   1290元/1G;   咨询

基本信息

分子式/分子量C78H64Cl5NO8P4Ru2 = 1646.65
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气
Reaxys-RN19234466
PubChem物质ID253660972
MDL编号MFCD09753037

技术规格

AppearanceOrange to Brown powder to crystal
IRto pass test

物性(参考值)

水溶性不溶
44-0518StremDimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos?)}2(mu-Cl)3]795元/250mg;   2197元/1g;   6255元/5g;   咨询

Technical Notes:

1. Highly enantioselective, highly active catalyst for hydrogenation of functionalized ketones. The chlororuthenate salts show catalytic activity at relatively low temperature. See 15-0136.

2.Catalyst for enantioselective hydrogenation of enamines.

References:

1.Adv. Synth. Catal., 2001, 343, 264.

2.U.S. Pat. 8188307.

692204Sigma-Aldrich(R)-[(RuCl(SEGPHOS®))2(μ-Cl)3][NH2Me2]208.08元/50 MG;   咨询

产品说明

一般描述

(R)-[(RuCl(SEGPHOS®))2(μ-Cl)3][NH2Me2] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS®, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.

应用

Takasago Ligands and Complexes for Asymmetric Reactions

包装

50, 100 mg in amber glass bottle

法律信息

与 Takasago 合作销售，仅用于研究目的。日本注册号 3148136、3549390
SEGPHOS is a registered trademark of Takasago Intl. Corp.

基本信息

线性分子式(CH3)2NH2+[C76H56Cl5O8P4Ru2]-
分子量1646.64
MDL编号MFCD09753037
PubChem化学物质编号329761474
NACRESNA.22

产品性质

形式powder
质量水平100
储存温度2-8℃
SMILES stringCl.[Cl-].CNC.[Cl+]1[Ru-]2[Cl+][Ru-]1[Cl+]2.C3Oc4ccc(P(c5ccccc5)c6ccccc6)c(c4O3)-c7c8OCOc8ccc7P(c9ccccc9)c%10ccccc%10.C%11Oc%12ccc(P(c%13ccccc%13)c%14ccccc%14)c(c%12O%11)-c%15c%16OCOc%16ccc%15P(c%17ccccc%17)c%18ccccc%18
InChI1S/2C38H28O4P2.C2H7N.2ClH.3Cl.2Ru/c2*1-5-13-27(14-6-1)43(28-15-7-2-8-16-28)33-23-21-31-37(41-25-39-31)35(33)36-34(24-22-32-38(36)42-26-40-32)44(29-17-9-3-10-18-29)30-19-11-4-12-20-30;1-3-2;;;;;;;/h2*1-24H,25-26H2;3H,1-2H3;2*1H;;;;;/q;;;;;3*+1;2*-1/p-1
InChI keyRENFEASRVBXAEN-UHFFFAOYSA-M

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
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