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CAS: 34381-71-0
分子式: C6H13NO
分子量: 115.17
沸点: 66℃(12 t
英文名称: 
n-methyl-l-prolinol
用途: 膦配体的前体,可用于催化不对称格氏交叉偶联反应
推荐供应商
货号品牌产品名称规格包装、参考价格
S844155MACKLINN-甲基-L-脯氨醇97%27元/1g;   29元/5g;   116元/25g;   431元/100g;   咨询
储存:2-8°C
状态:无色到浅黄色液体
折射率:n20/D 1.469(lit.)
M2058TCI(S)-(1-Methylpyrrolidin-2-yl)methanol>98.0%(GC)(T)450元/5G;   1590元/25G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C6H13NO = 115.18
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN79851
MDL编号MFCD00011727

技术规格

AppearanceColorless to Light orange to Yellow clear liquid
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Specific rotation [a]20/D-54.0 to -46.0 deg(C=5, MeOH)

物性(参考值)

沸点82 ℃/22 mmHg
闪点63 ℃
比重0.97

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P403 + P235 : 存放在通风良好的地方。保持低温。
H62573Alfa AesarN-Methyl-L-prolinol96%987元/5g;   3947元/25g;   咨询

基本信息

MDL
MFCD00011727

EINECS
251-981-9

分子式
C6H13NO

分子量
115.17

沸点
67-69°/12mm

闪点
63°(145°F)

密度
0.968

折射率
1.4690

形态
Liquid

Beilstein
79851

GHS危害和防范说明

Hazard Statements
H227
Combustible liquid.

Precautionary Statements
P210e-P280a-P370+P378a-P403+P235-P501a
Wear protective gloves and eye/face protection.In case of fire: Use for extinction: CO2, powder or water spray.Store in a well-ventilated place. Keep cool.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

TSCA

302767Sigma-Aldrich(S)-(-)-1-Methyl-2-pyrrolidinemethanol96%549.81元/5 G;   1560.8元/25 G;   咨询

产品说明

应用

膦配体的前体,可用于催化不对称格氏交叉偶联反应。

包装

5, 25 g in glass bottle

基本信息

经验(实验)分子式C6H13NO
分子量115.17
Beilstein79851
EC 号251-981-9
MDL编号MFCD00011727
PubChem化学物质编号24858272
NACRESNA.22

产品性质

质量水平100
测定96%
旋光性[α]19/D −49.5°, c = 5 in methanol
reaction suitabilityreaction type: solution phase peptide synthesis
折射率n20/D 1.469 (lit.)
bp67-69 ℃/12 mmHg (lit.)
密度0.968 g/mL at 25 ℃ (lit.)
application(s)peptide synthesis
储存温度2-8℃
SMILES stringCN1CCC[C@H]1CO
InChI1S/C6H13NO/c1-7-4-2-3-6(7)5-8/h6,8H,2-5H2,1H3/t6-/m0/s1
InChI keyVCOJPHPOVDIRJK-LURJTMIESA-N

安全信息

储存分类代码10 - Combustible liquids
WGKWGK 3
闪点(F)145.4 °F - closed cup
闪点(C)63 ℃ - closed cup
个人防护装备Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
208659Fluorochem(S)-(-)-1-Methyl-2-pyrrolidinemethanol97%286元/1g;   462元/5g;   638元/10g;   1320元/25g;   咨询

基本信息

CAS Number34381-71-0
MDL NumberMFCD00011727
Density0.968

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9
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