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CAS: 3437-95-4
分子式: C4H3IS
分子量: 210.04
沸点: 181-185℃
熔点: -40-74℃
中文名称: 
2-碘噻吩
2-碘代噻吩
英文名称: 
2-Iodothyophene
2-iodo-thiophene
thiophene,2-iodo-
2-thienyl iodide
2-iodo-thiophen
2-iodothiophene
性质描述: 无色液体。熔点-40℃,沸点80-81℃(2.67kPa)。
生产方法: 将35g(0.42mol)噻吩和50毫升苯混合,在搅拌冷却下,分次交替地加入75g(0.35mol)黄色氧化汞和109g(0.43mol)碘。过滤,用乙醚洗涤滤渣。合并洗滤液,用硫代硫酸钠稀溶液洗涤,除去过量的碘,经无水氯化钙干燥后蒸除乙醚和苯,减压蒸馏,收集73℃(2.0kPa)馏分,得63-66g2-碘噻吩。收率72-75%。
用途: 用于有机合成。
推荐供应商
货号品牌产品名称规格包装、参考价格
I811793MACKLIN2-碘噻吩97%,含铜稳定剂27元/5g;   106元/25g;   397元/100g;   咨询
储存:2~8℃,避光
状态:无色到橙色液体
折射率:n20/D 1.651(lit.)
I0374TCI2-Iodothiophene>98.0%(GC)545元/25G;   2150元/100G;   咨询

基本信息

纯度/分析方法>98.0%(GC)
分子式/分子量C4H3IS = 210.03
外观与形状(20℃)液体
应避免的情况
Reaxys-RN104666
PubChem物质ID87571727
SDBS (AIST Spectral DB)5342
MDL编号MFCD00005424

技术规格

AppearanceYellow to Brown to Dark green clear liquid
Purity(GC)min. 98.0 %

物性(参考值)

熔点-40 ℃
沸点182 ℃
闪点71 ℃
比重2.06
折射率1.65

安全信息

信号词警告
危险性说明H227 : 可燃液体。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P403 + P235 : 存放在通风良好的地方。保持低温。
188716J&K2-Iodothiophene98%82元/5G;   298元/25G;   1084元/100G;   咨询

基本信息

分子式C4H3IS
分子量210.04
熔点-40
沸点73
闪点71
密度1.902
折光率(n20D)1.6510
MDL编码MFCD00005424
Beilstein104666
EINECS 编号222-342-1
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H302
H312
H332
防范说明P280
P301+P312
P302+P352
P304+P340
WGK3
TSCA
A12898Alfa Aesar2-Iodothiophene98%, stab. with copper916元/25g;   3443元/100g;   14073元/500g;   咨询

基本信息

MDL
MFCD00005424

EINECS
222-342-1

分子式
C4H3IS

分子量
210.04

熔点
-40°

沸点
182°

闪点
71°(159°F)

密度
2.064

折射率
1.6520

灵敏度
Light Sensitive. Ambient temperatures.

形态
Liquid

Beilstein
104666

GHS危害和防范说明

GHS符号

Hazard Statements
H227-H301-H311-H332-H315-H319
Combustible liquid.Toxic if swallowed.Toxic in contact with skin.Harmful if inhaled.Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P210e-P261-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Avoid breathing dust/fume/gas/mist/vapours/spray.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
20/21/22-36/38
Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.

安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.

欧盟危险品标志

TSCA

193344Amethyst2-Iodothiophene98%, 用于合成77元/5G;   195元/25G;   639元/100G;   1949元/500G;   咨询

基本信息

分子式C4H3IS
分子量210.04
熔点-40
沸点73
闪点71
密度1.902
折光率(n20D)1.6510 - 1.6530
MDL编码MFCD00005424
Beilstein104666
EINECS 编号222-342-1
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Warning
危险说明H302
H312
H332
防范说明P280
P301+P312
P302+P352
P304+P340
UN号码1993
危险分类3
包装等级III
WGK3
TSCA
001058Fluorochem2-Iodothiophene (Stabilized with copper)98%220元/1g;   330元/5g;   440元/25g;   1276元/100g;   咨询

基本信息

CAS Number3437-95-4
MDL NumberMFCD00005424
Boiling Point73℃/15mm
Melting Point-40℃
Density1.902

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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