CAS 33797-51-2; 二甲基亚甲基碘化铵; dimethylmethylammonium iodide

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产品名称

规格

包装、参考价格

N836455

MACKLIN

N,N-二甲基亚甲基碘化铵

97%

129元/1g; 460元/5g; 1248元/25g; 4020元/100g;

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储存：2~8 °C,密封,干燥
状态：白色到浅黄色灰色到棕色粉末到晶体

D1646

TCI

N,N-Dimethylmethyleneammonium Iodide

>97.0%(T)

520元/5G; 1550元/25G;

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基本信息

纯度/分析方法	>97.0%(T)
分子式/分子量	C₃H₈IN = 185.01
外观与形状(20℃)	固体
储存温度	0-10℃
储存在惰性气体下	存放于惰性气体之中
应避免的情况	光,湿气 (分解),加热
Reaxys-RN	3594966
PubChem物质ID	87568123
SDBS (AIST Spectral DB)	19772
Merck Index (14)	3251
MDL编号	MFCD00011810

技术规格

Appearance	White to Gray to Brown powder to crystal
Purity( Potassium iodate Method)	min. 97.0 %

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

A15146

Alfa Aesar

(N,N-Dimethyl)methyleneammonium iodide

97%

1195元/10g;

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应用
(N,N-Dimethyl)methyleneammonium iodide is a useful reagent for many synthetic applications like aminomethylation. It is also essential for the conversion of ketones to α, β-unsaturated enones. It is utilized to prepare derivatives of the type RCH₂N(CH₃)₂. It is extensively used in medicines like painkillers and sedatives- Tramadol hydrochloride intermediate viz. 2-dimethylamine methylcyclohexanone. It is also employed in reactive dyes, synthesized spices. It plays an essential role in Mannich reactions.

备注
Moisture and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place.

基本信息

MDL
MFCD00011810

EINECS
251-680-2

分子式
C₃H₈IN

分子量
185.01

熔点
ca 240° dec.

灵敏度
Keep Cold. Moisture Sensitive. Light Sensitive.

形态
Crystalline powder

溶解性
Soluble in dimethylformamide. Partially soluble in acetonitrile, tetrahydrofuran and dichloromethane.

Beilstein
3594966

Merck
14,3251

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否

C20101

Alfa Aesar

N,N-Dimethylmethyleneiminium Iodide

97%

1690元/10g; 9164元/50g;

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基本信息

Ref#
20101

MDL
11810

分子式
C3 H8 I N

分子量
185.01

214914

Sigma-Aldrich

N,N-Dimethylmethyleneiminium iodide

98%

1233.28元/10 G; 2674.13元/50 G;

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产品说明

一般描述

N,N -二甲基亚甲基碘是许多合成应用的有用试剂，尤其是氨基甲酰化和酮转化为 α,β-不饱和烯酮。

包装

10, 50 g in glass bottle

基本信息

线性分子式	CH₂=N⁺(CH₃)₂I^-
分子量	185.01
Beilstein	1731022
EC 号	251-680-2
MDL编号	MFCD00011810
PubChem化学物质编号	24852854
NACRES	NA.22

产品性质

质量水平	100
测定	98%
mp	219 ℃ (dec.) (lit.)
溶解性	water: soluble 50 mg/mL, clear to slightly hazy, colorless to yellow
SMILES string	[I-].C[N+](C)=C
InChI	1S/C3H8N.HI/c1-4(2)3;/h1H2,2-3H3;1H/q+1;/p-1
InChI key	VVDUZZGYBOWDSQ-UHFFFAOYSA-M

安全信息

象形图
警示用语：	Warning
危险声明	H315 - H319 - H335
预防措施声明	P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类	Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官	Respiratory system
储存分类代码	11 - Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves