| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| R838366 | MACKLIN | (R)-(+)-α-甲基苄基异氰酸酯 | 99% | 122元/1g; 340元/5g; 963元/25g; 3084元/100g; | 咨询 |
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| I0334 | TCI | (R)-(+)-α-Methylbenzyl Isocyanate | >98.0%(GC) | 510元/1G; 1490元/5G; | 咨询 |
基本信息 | 纯度/分析方法 | >98.0%(GC) | | 分子式/分子量 | C9H9NO = 147.18 | | 外观与形状(20℃) | 液体 | | 储存温度 | 0-10℃ | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 湿气 (分解),加热 | | Reaxys-RN | 3196930 | | PubChem物质ID | 87571689 | | SDBS (AIST Spectral DB) | 23529 | | MDL编号 | MFCD00063015 |
技术规格 | Appearance | Colorless to Almost colorless clear liquid | | Purity(GC) | min. 98.0 % | | Optical purity(GC) | min. 98.0 ee% |
物性(参考值) | 闪点 | 65 ℃ | | 比重 | 1.05 | | 比旋光度 [α]D | 10° (neat) | | 折射率 | 1.51 |
安全信息 | 图形或危害标志 |   | | 信号词 | 危险 | | 危险性说明 | H301 + H331 : 吞咽或吸入可致中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
H334 : 吸入可能导致过敏或哮喘病症状或呼吸困难。
H335 : 可能造成呼吸道刺激。
H227 : 可燃液体。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P284 : [在通风不足的情况下]戴呼吸防护装置。
P302 + P352 : 如皮肤沾染：用水充分清洗。
P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。
P342 + P311 : 如有呼吸系统病症：呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激：求医/就诊。
P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激：求医/就诊。
P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。
P304 + P340 + P311 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。呼叫急救中心/医生。
P403 + P233 : 存放在通风良好的地方。保持容器密闭。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。
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运输信息 | UN编号 | UN2206 | | 类别 | 6.1 | | 包装类别 | III | | 监管条件代码(*) | |
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| 245153 | J&K | (R)-(+)-1-Methylbenzyl isocyanate | 98% | 470元/1G; 1415元/5G; | 咨询 |
基本信息 | 分子式 | C9H9NO | | 分子量 | 147.17 | | 沸点 | 55-56 | | 闪点 | 65 | | 密度 | 1.045 | | 折光率(n20D) | 1.5130 | | 比旋光度([α]20D) | +10° to +11° (neat) | | MDL编码 | MFCD00063015 | | Beilstein | 3196930 | | EINECS 编号 | 251-485-2 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H315
H319
H330
H334
H335 | | 防范说明 | P260
P284
P305+P351+P338
P310 | | UN号码 | 2206 | | 危险分类 | 6.1 | | 包装等级 | III | | WGK | 3 | | TSCA | 否 |
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| L10305 | Alfa Aesar | (R)-(+)-1-Phenylethyl Isocyanate | 99% | 1077元/1g; 3578元/5g; | 咨询 |
应用
(R)-1-phenylethyl isocyanate is used in the derivatisation of alcohols, thiocarbamates and hydroxy fatty acids. (R)-1-phenylethyl isocyanate moderately inhibited both BP-DNA adducts. 备注
Moisture Sensitive.Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture. Store at 4?°C. 基本信息 MDL
MFCD00063015 EINECS
251-485-2 分子式
C9H9NO 分子量
147.18 沸点
55-56°/2.5mm 闪点
65°(149°F) 密度
1.045 折射率
1.5124 灵敏度
Keep Cold. Moisture Sensitive. 溶解性
Decomposes in water. Beilstein
3196930 GHS危害和防范说明 GHS符号
Hazard Statements
H227-H302-H331-H315-H319-H334-H335
Combustible liquid.Harmful if swallowed.Toxic if inhaled.Causes skin irritation.Causes serious eye irritation.May cause allergy or asthma symptoms or breathing difficulties if inhaled.May cause respiratory irritation. Precautionary Statements
P260-P280h-P305+P351+P338-P309-P310
Do not breathe dust/fume/gas/mist/vapours/spray.Wear protective gloves/clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician. 安全信息 危险等级
6.1 包装组
II 危险类别
20/22-36/37/38-42
Harmful by inhalation and if swallowed.Irritating to eyes, respiratory system and skin.May cause sensitization by inhalation. 安全等级
23-26-36/37-45
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). 欧盟危险品标志
 TSCA
否 |
| C20532 | Alfa Aesar | (R)-(+)-alpha-Methylbenzyl isocyanate | 98% | 4988元/5ml; | 咨询 |
基本信息 Ref#
20532 MDL
63015 分子式
C9 H9 N O 分子量
147.18 闪点
65 密度
1.05 安全信息 危险等级
6.1 包装组
II |
| 220574 | Sigma-Aldrich | (R)-(+)-α-Methylbenzyl isocyanate | 99% | 547.72元/1 G; 1304.49元/5 G; | 咨询 |
基本信息 | 线性分子式 | C6H5CH(CH3)NCO | | 分子量 | 147.17 | | Beilstein | 3196930 | | EC 号 | 251-485-2 | | MDL编号 | MFCD00063015 | | PubChem化学物质编号 | 24853180 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 测定 | 99% | | 形式 | liquid | | 旋光性 | [α]20/D +10°, neat | | 光学纯度 | ee: 96% (GLC) | | 折射率 | n20/D 1.513 (lit.) | | bp | 55-56 ℃/2.5 mmHg (lit.) | | 密度 | 1.045 g/mL at 20 ℃ (lit.) | | 储存温度 | 2-8℃ | | SMILES string | C[C@@H](N=C=O)c1ccccc1 | | InChI | 1S/C9H9NO/c1-8(10-7-11)9-5-3-2-4-6-9/h2-6,8H,1H3/t8-/m1/s1 | | InChI key | JJSCUXAFAJEQGB-MRVPVSSYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H315 - H317 - H319 - H330 - H334 - H335 | | 预防措施声明 | P260 - P264 - P280 - P302 + P352 - P304 + P340 + P310 - P305 + P351 + P338 | | 危险分类 | Acute Tox. 2 Inhalation - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials | | WGK | WGK 3 | | 闪点(F) | 149.0 °F - closed cup | | 闪点(C) | 65 ℃ - closed cup | | 个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
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| 77968 | Supelco | (R)-(+)-α-Methylbenzyl isocyanate | for chiral derivatization, LiChropur™, ≥99.0% | 2298.59元/1 ML; 9083.93元/5 ML; | 咨询 |
产品说明 一般描述 (R)-(+)-α-甲基苄基异氰酸酯[(R)-(+)-MBIC]是一种衍生剂。 应用 (R)-(+)-MBIC 已用于 4-(甲基亚硝胺基)-1-(3-吡啶基)-1-丁醇的衍生反应，形成 4-(甲基亚硝胺基)-1-(α-甲基苄基氨基甲酰基)-1-(3-吡啶基)丁烷。它也已用于分离羟基酸，将其转化为-4-[(S)-α-甲基苄基氨基甲酰基] -4-(3-吡啶基)-丁酸甲酯，并用 LC-MS/MS 进行进一步分析。1 它与水合盐酸盐酮苯胺反应生成半缩醛的 3-(((1R)-1-苯基乙基)-(4S)-6-氯-4-羟基-4-(三氟甲基)-1,3,4-三氢喹唑啉-2-酮。 包装 1, 5 mL in glass bottle 其他说明 用于测定醇和胺对映体纯度的试剂 推荐产品 探索最适于 HPLC 或 LC-MS 分析的 LiChropur 试剂 法律信息 LiChropur is a trademark of Merck KGaA, Darmstadt, Germany 基本信息 | 线性分子式 | C6H5CH(CH3)NCO | | 分子量 | 147.17 | | Beilstein | 3196930 | | EC 号 | 251-485-2 | | MDL编号 | MFCD00063015 | | PubChem化学物质编号 | 329768059 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 等级 | for chiral derivatization | | 测定 | ≥99.0% (sum of enantiomers, GC)
≥99.0% | | 形式 | liquid | | 旋光性 | [α]20/D +10.5±0.5°, neat | | 光学纯度 | enantiomeric ratio: ≥99.5:0.5 (GC) | | 质量 | LiChropur™ | | technique(s) | HPLC: suitable | | 折射率 | n20/D 1.513 (lit.)
n20/D 1.513 | | bp | 55-56 ℃/2.5 mmHg (lit.) | | 密度 | 1.045 g/mL at 20 ℃ (lit.)
1.046 g/mL at 20 ℃ | | 储存温度 | 2-8℃ | | SMILES string | C[C@@H](N=C=O)c1ccccc1 | | InChI | 1S/C9H9NO/c1-8(10-7-11)9-5-3-2-4-6-9/h2-6,8H,1H3/t8-/m1/s1 | | InChI key | JJSCUXAFAJEQGB-MRVPVSSYSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H315 - H317 - H319 - H330 - H334 - H335 | | 预防措施声明 | P260 - P264 - P280 - P302 + P352 - P304 + P340 + P310 - P305 + P351 + P338 | | 危险分类 | Acute Tox. 2 Inhalation - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3 | | 靶器官 | Respiratory system | | 储存分类代码 | 6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials | | WGK | WGK 3 | | 闪点(F) | 149.0 °F - closed cup | | 闪点(C) | 65 ℃ - closed cup | | 个人防护装备 | Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter |
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| 013633 | Fluorochem | R-(+)-a-Methylbenzyl isocyanate | 98% | 1056元/1g; 2948元/5g; 9592元/25g; | 咨询 |
基本信息 | CAS Number | 33375-06-3 | | MDL Number | MFCD00063015 | | Boiling Point | 55-56℃ (lit.) | | Density | 1.045 |
安全信息 | 图形或危害标志 |  | | 危险性说明 | H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P361: Remove/Take off immediately all contaminated clothing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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