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CAS: 33166-79-9
分子式: CH3C6H4COCH2CO2CH2CH3
分子量: 206.24
沸点: 273-274 ℃(lit.)
英文名称: 
Ethyl(3-methylbenzoyl)acetate
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储存:2-8°C
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基本信息

分子量
206.24

559180Sigma-AldrichEthyl (3-methylbenzoyl)acetate953.67元/1 G;   咨询

产品说明

应用

Reactant for:

  • Stereoselective ketonization-olefination of indoles by Co/Mn-mediated oxidative cross-coupling of indoles via dioxygen activation
  • Enantioselective Michael reaction
  • SEGPhos-ruthenium-catalyzed asymmetric hydrogenation

包装

1 g in glass bottle

基本信息

线性分子式CH3C6H4COCH2CO2CH2CH3
分子量206.24
MDL编号MFCD03424816
PubChem化学物质编号24879802
NACRESNA.22

产品性质

质量水平100
折射率n20/D 1.5290 (lit.)
bp273-274 ℃ (lit.)
密度1.083 g/mL at 25 ℃ (lit.)
SMILES stringCCOC(=O)CC(=O)c1cccc(C)c1
InChI1S/C12H14O3/c1-3-15-12(14)8-11(13)10-6-4-5-9(2)7-10/h4-7H,3,8H2,1-2H3
InChI keyLLFKVNDSLHMEQC-UHFFFAOYSA-N

安全信息

储存分类代码12 - Non Combustible Liquids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves
014851Fluorochem3-Oxo-3-m-tolyl-propionic acid ethyl ester97%352元/250mg;   924元/1g;   3696元/5g;   6468元/10g;   咨询

基本信息

CAS Number33166-79-9
MDL NumberMFCD03424816
Boiling Point293.1 ℃ at 760 mmHg

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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