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CAS: 29892-37-3
分子式: C2H6AuClS
分子量: 294.55
熔点: 160°C(dec.)(lit.)
英文名称: 
chloro(dimethylsulfide)gold(i)
(Dimethylsulfide)gold(I)chloride
性质描述: 晶体-粉末
推荐供应商
货号品牌产品名称规格包装、参考价格
C824123MACKLIN氯化(二甲硫醚)金(I)98%445元/250mg;   1688元/1g;   咨询
储存:2~8℃,干燥,密封
状态:白色到灰白色到米黄色到灰色到浅紫色粉末
物化性质:晶体-粉末
C2719TCIChloro(dimethylsulfide)gold(I)>97.0%(T)935元/200MG;   2775元/1G;   咨询

基本信息

纯度/分析方法>97.0%(T)
分子式/分子量C2H6AuClS = 294.55
外观与形状(20℃)固体
储存温度0-10℃
储存在惰性气体下存放于惰性气体之中
应避免的情况光,空气,加热
包装和容器 1G-带有塑料内管的玻璃瓶 (查看图片),  200MG-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN16499725
PubChem物质ID253660095
MDL编号MFCD00192090

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(Argentometric Titration)min. 97.0 %

物性(参考值)

熔点160 ℃(dec.)

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
79-0345StremChloro(dimethylsulfide)gold(I)min. 97%810元/250mg;   2430元/1g;   9720元/5g;   咨询

Technical Notes:

1.Gold(I) precursor to more advanced gold catalysts

2.Gold catalyst for the conversion of propargyl sulfoxides to a-thioenones

References:

1.Organometallics, 2007, 26, 1 069

2.J. Am. Chem. Soc., 2007, 129, 41 60

420727Sigma-AldrichChloro(dimethylsulfide)gold(I)686.86元/250 MG;   2463.49元/1 G;   咨询

产品说明

应用

Chloro(dimethylsulfide)gold(I) can be used to synthesize a gold(I)-catalyst that can effectively catalyze intermolecular [2+2] cycloaddition of terminal alkynes with substituted alkenes to form substituted cyclobutenes under mild reaction conditions.
It can also be used to synthesize:

  • chloro(trimesitylphosphine)gold(I)
  • gold(I) N-heterocyclic carbene (NHC) complexes
  • bis(carbene)gold(I) complex of ferrocenyl complexes
  • gold(I) acetylide complexes

包装

1 g in glass bottle
250 mg in glass bottle

基本信息

线性分子式(CH3)2SAuCl
分子量294.55
MDL编号MFCD00192090
PubChem化学物质编号24866348
NACRESNA.22

产品性质

质量水平100
reaction suitabilitycore: gold
reagent type: catalyst
SMILES stringCl[Au].CSC
InChI1S/C2H6S.Au.ClH/c1-3-2;;/h1-2H3;;1H/q;+1;/p-1
InChI keyYQALRAGCVWJXGB-UHFFFAOYSA-M

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
241818FluorochemChloro(dimethylsulfide)gold(I)95%990元/250mg;   3256元/1g;   15290元/5g;   咨询

基本信息

CAS Number29892-37-3
MDL NumberMFCD00192090
Melting Point160℃

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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