CAS 25895-60-7; (氰-C)三氢硼酸(1-)钠; Sodium cyanotrihydroborate

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货号

品牌

产品名称

规格

包装、参考价格

S817744

MACKLIN

氰基硼氢钠

5.0 M in 1 M NaOH

56元/2ml; 138元/10ml; 571元/50ml; 2799元/250ml;

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储存：室温,惰性气体氛围
状态：无色液体

S817743

MACKLIN

氰基硼氢钠

1.0 M in THF

390元/100ml; 1319元/500ml;

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储存：室温,惰性气体氛围
状态：无色液体

S817682

MACKLIN

氰基硼氢钠

95%

32元/5g; 95元/25g; 352元/100g; 1359元/500g; 6780元/2.5kg;

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储存：室温, 干燥, 惰性气体
状态：白色到浅黄色粉末

S0396

TCI

Sodium Cyanoborohydride [Reducing Agent]

>95.0%(T)

455元/5G; 1290元/25G; 7190元/250G;

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基本信息

纯度/分析方法	>95.0%(T)
分子式/分子量	CH₃BNNa = 62.84
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	湿气 (分解)
Reaxys-RN	4152656
PubChem物质ID	87575903
Merck Index (14)	8606
MDL编号	MFCD00003516

技术规格

Appearance	White to Almost white powder to crystal
Purity(Iodometric Titration)	min. 95.0 %

物性(参考值)

水溶性	完全溶解,与水接触发生分解
在水中的溶解度	2,120 g/l 29 ℃
溶解性(易溶于)	甲醇
溶解性(可溶于)	四氢呋喃,二甲基甲酰胺
溶解性(微溶于)	乙醇
溶解性(不溶于)	乙醚,苯

安全信息

图形或危害标志
信号词	危险
危险性说明	H300 + H310 + H330 : 吞咽、皮肤接触或吸入致命。 H314 : 造成严重皮肤灼伤和眼损伤。 H410 : 对水生生物毒性极大并具有长期持续影响。 H260 : 遇水放出可自燃的易燃气体。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P223 : 不得与水接触。 P273 : 避免释放到环境中。 P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。 P270 : 使用本产品时不要进食、饮水或吸烟。 P262 : 严防进入眼中、接触皮肤或衣服。 P231 + P232 : 在惰性气体中操作。防潮。 P271 : 只能在室外或通风良好之处使用。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P284 : [在通风不足的情况下]戴呼吸防护装置。 P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P335 + P334 : 掸掉皮肤上的细小颗粒。浸入冷水中/用湿绷带包扎。 P391 : 收集溢出物。 P361 + P364 : 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。 P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。 P301 + P310 + P330 : 如误吞咽：立即呼叫急救中心/医生。漱口。 P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。 P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。 P403 + P233 : 存放在通风良好的地方。保持容器密闭。 P402+P404 : 存放于干燥处。存放于密闭的容器中。 P405 : 存放处须加锁。

运输信息

UN编号	UN3134
类别	4.3 / 6.1
包装类别	II
监管条件代码(*)

11-2800

Strem

Sodium cyanoborohydride

95%

430元/5g; 1780元/25g;

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087839

Alfa Aesar

Sodium cyanoborohydride

95%

389元/5g; 1737元/25g; 6420元/100g;

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应用
Selective reducing agent for aldehydes, ketones, oximes, enamines. Reductive animation of ketones, aldehydes. Reductive alkylation of amines, hydrazines Sodium cyanoborohydride is used as a reagent involved in the reductive amination of aldehydes, ketones, oximes and enamines. It is also used in the reductive alkylation of amines and hydrazines. It acts as a catalyst in the preparation of phenolate-bridged dilanthanum(III) complex. In addition, it is used in the conversion of imines to amines. It plays an important role in the reductive deoxygenation of ketones.

备注
Moisture sensitive. Incompatible with strong acids, water and strong oxidizing agents.

基本信息

MDL
MFCD00003516

EINECS
247-317-2

分子式
NaBH₃CN

分子量
62.84

熔点
>300° dec.

密度
1.20

灵敏度
Moisture Sensitive. Ambient temperatures.

形态
Powder

溶解性
Soluble in water, THF, methanolSoluble in water, diglyme, tetrahydrofuran and methanol. Slightly soluble in dimethyl sulfoxide. Insoluble in diethyl ether.

Merck
14,8606

GHS危害和防范说明

GHS符号

Hazard Statements
H228-H261-H300-H310-H330-H314-H318-H400-H410
Flammable solid.In contact with water releases flammable gas.Fatal if swallowed.Fatal in contact with skin.Fatal if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P223-P301+P310a-P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire.Keep away from any possible contact with water, because of violent reaction and possible flash fire.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment is urgent (see label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
4.3

包装组
II

危险类别
11-15-26/27/28-32-34-50/53
Highly flammable.Contact with water liberates extremely flammable gases.Very toxic by inhalation, in contact with skin and if swallowed.Contact with acids liberates very toxic gas.Causes burns.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
26-28-36/37/39-45-60-61
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

TSCA
是

C16855

Alfa Aesar

Sodium cyanoborohydride

95%

956元/10g; 3338元/50g; 9871元/250g;

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基本信息

Ref#
16855

MDL
3516

分子式
C H3 B N Na

分子量
62.84

安全信息

危险等级
4.3

包装组
II

156159

Sigma-Aldrich

Sodium cyanoborohydride

reagent grade, 95%

991.09元/10 G; 1611.57元/25 G; 3020.37元/50 G; 12447元/250 G; 29361.6元/1 KG;

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产品说明

应用

用于醛、酮还原性胺化以及胺还原性烷化的试剂。
用于选择性还原反应的试剂。

特点和优势

用于合成新型酚氧桥联二镧(III) 络合物，该络合物具有金属蛋白模型以及基础化学和应用化学方面的应用前景。

基本信息

线性分子式	NaBH₃CN
分子量	62.84
Beilstein	4152656
EC 号	247-317-2
MDL编号	MFCD00003516
PubChem化学物质编号	24849595
NACRES	NA.22

产品性质

质量水平	200
等级	reagent grade
测定	95%
形式	powder
reaction suitability	reagent type: reductant
mp	>242 ℃ (dec.) (lit.)
SMILES string	[Na+].[BH3-]C#N
InChI	1S/CH3BN.Na/c2-1-3;/h2H3;/q-1;+1
InChI key	CVDUGUOQTVTBJH-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H228 - H260 - H300 + H310 + H330 - H314 - H410
预防措施声明	P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1B - Water-react. 1
补充剂危害	EUH032
储存分类代码	4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK	WGK 3
闪点(F)	158.0 °F
闪点(C)	70 ℃
个人防护装备	Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

918830

SAFC

Sodium cyanoborohydride

1802.35元/; 13002.9元/; 113801元/;

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基本信息

线性分子式	NaBH₃CN
分子量	62.84
Beilstein	4152656
MDL编号	MFCD00003516

产品性质

质量水平	300
生物来源	synthetic
mp	>242 ℃ (dec.) (lit.)
适用性	suitable for manufacturing use
SMILES string	[Na+].[BH3-]C#N
InChI	1S/CH3BN.Na/c2-1-3;/h2H3;/q-1;+1
InChI key	CVDUGUOQTVTBJH-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H228 - H260 - H300 + H310 + H330 - H314 - H410
预防措施声明	P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1B - Water-react. 1
补充剂危害	EUH032
储存分类代码	4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK	WGK 3
闪点(F)	158.0 °F
闪点(C)	70 ℃

296945

Sigma-Aldrich

Sodium cyanoborohydride solution

5.0 M in 1 M NaOH

1036.76元/50 ML; 4820.25元/500 ML;

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产品说明

一般描述

氰基硼氢化钠是一种选择性的温和还原剂，适用于多种官能团，如醛、酮、缩醛、环氧化物和亚胺。

应用

可作为如下反应的反应物：

将杂环醛直接转化为酯(氧化行为)
还原胺化反应
分子内还原环化反应
还原反应
作为双组元推进剂的自燃流体，制备基于二氰基硼酸盐的离子液体

包装

50, 500 mL in poly bottle

基本信息

线性分子式	NaBH₃CN
分子量	62.84
MDL编号	MFCD00003516
PubChem化学物质编号	24857889
NACRES	NA.22

产品性质

质量水平	200
reaction suitability	reagent type: reductant
浓度	5.0 M in 1 M NaOH
密度	1.083 g/mL at 25 ℃
SMILES string	[Na+].[H][B-]([H])([H])C#N
InChI	1S/CH3BN.Na/c2-1-3;/h2H3;/q-1;+1
InChI key	CVDUGUOQTVTBJH-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H260 - H290 - H300 + H310 + H330 - H314 - H410
预防措施声明	P231 + P232 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Water-react. 1
补充剂危害	EUH032
储存分类代码	4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable

8.18053

Sigma-Aldrich

Sodium cyanoborohydride

for synthesis

656.18元/5 G; 1263.29元/25 G;

咨询

基本信息

经验(实验)分子式	CH₃BNNa
分子量	62.84
MDL编号	MFCD00003516
EC索引号	247-317-2

产品性质

质量水平	200
形式	powder
reaction suitability	reagent type: reductant
mp	241-243 ℃
转变温度	flash point 70 ℃
密度	1.12 g/cm³ at 28 ℃
储存温度	2-30℃
InChI	1S/CN.B.Na.3H/c1-2;;;;;/q-1;+3;+1;3*-1
InChI key	IVGYREMSCQFSBM-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H228 - H260 - H300 + H310 + H330 - H314 - H410
预防措施声明	P210 - P231 + P232 - P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类	Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1B - Water-react. 1
补充剂危害	EUH032
储存分类代码	4.3 - Hazardous materials, which set free flammable gases upon contact with water
WGK	WGK 3
闪点(F)	158.0 °F
闪点(C)	70 ℃

044871

Fluorochem

Sodium cyanoborohydride

97%

550元/25g; 1716元/100g;

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基本信息

CAS Number	25895-60-7
MDL Number	MFCD00003516
Melting Point	241-243℃
Density	1.083

安全信息

图形或危害标志
危险性说明	EUH032: Contact with acids liberates very toxic gas. H228: Flammable solid. H300: Fatal if swallowed. H310: Fatal in contact with skin. H314: Causes severe skin burns and eye damage. H330: Fatal if inhaled. H410: Very toxic to aquatic life with long lasting effects.
防范说明	P210: Keep away from – No smoking. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P260: Do not breathe P262: Do not get in eyes, on skin, or on clothing. P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear . P284: Wear respiratory protection. P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P302 + P350: IF ON SKIN: Gently wash with plenty of soap and water. P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER or doctor/physician. P320: Specific treatment is urgent (see . on this label). P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P361: Remove/Take off immediately all contaminated clothing. P363: Wash contaminated clothing before reuse. P370 + P378: In case of fire: Use CO2, dry powder or foam for extinction. P391: Collect spillage. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.