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CAS: 23978-55-4
分子式: C12H26N2O4
分子量: 262.34
熔点: 111-115℃
中文名称: 
二氮杂18-冠醚-6
1,7,10,16-四恶-4,13-二氮环十八烷
英文名称: 
1,10-diaza-4,7,13,16-tetraoxacyclooctadecane
1,7,10,16-tetraoxa-4,13-diazacyclooctadecane
7,16-diaza-1,4,10,13-tetraoxcyclooctadecane
7,16-diaza-18-crown-6
cryptand 2.2
cryptand 22
diaza-18-crown-6
kryptofix 22
1,4,10,13-Tetraoxa-7,16-diazacyclooctadecane
1,10-Diaza-18-crown-6
4,13-Diaza-18-crown 6-Ether
展开更多英文名
推荐供应商
货号品牌产品名称规格包装、参考价格
T836347MACKLIN4,13-二氮杂-18-冠-6-醚96%75元/100mg;   135元/250mg;   535元/1g;   2399元/5g;   咨询
储存:室温,密封,干燥
状态:灰白色粉末
D2323TCI4,13-Diaza-18-crown 6-Ether>98.0%(T)1750元/1G;   6765元/5G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量C12H26N2O4 = 262.35
外观与形状(20℃)固体
包装和容器 1G-带有塑料内管的玻璃瓶 (查看图片)
Reaxys-RN609764
PubChem物质ID87568759
MDL编号MFCD00005112

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Nonaqueous Titration)min. 98.0 %
Melting point112.0 to 116.0 ℃

物性(参考值)

熔点115 ℃

安全信息

图形或危害标志
信号词警告
危险性说明H303 : 吞咽可能有害。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P312 : 如感觉不适,呼叫急救中心/医生。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
306601J&K1,10-Diaza-18-crown-695%479元/250MG;   1577元/1G;   咨询

基本信息

分子式C12H26N2O4
分子量262.35
熔点111-114
MDL编码MFCD00005112
Beilstein609764
EINECS 编号245-965-0

安全信息

图形或危害标志
提示语Warning
危险说明H315
H319
H335
防范说明P261
P305+P351+P338
WGK2
RTECSHM1650000
TSCA
H51063Alfa Aesar1,10-Diaza-18-crown-696%1542元/250mg;   4647元/1g;   18927元/5g;   咨询

应用
1,10-Diaza-18-crown-6 are starting materials to produce macrocyclic polyamine metal-complexing agents. It is used as a ligand in chemistry for the applications of diagnostic imaging technique to identify medical condition or disease and for the development of medication as a therapeutic agent and pharmaceutic aid. Also used as an ether.

备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.

基本信息

MDL
MFCD00005112

EINECS
245-965-0

分子式
C12H26N2O4

分子量
262.35

灵敏度
Air Sensitive. Ambient temperatures.

溶解性
Soluble in water.

Beilstein
609764

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
III

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
HM1650000

TSCA

295809Sigma-Aldrich1,4,10,13-Tetraoxa-7,16-diazacyclooctadecane≥96%2187.26元/1 G;   咨询

产品说明

应用

1,4,10,13-Tetraoxa-7,16-diazacyclooctadecane is a crown ether, which can be used:

  • In the spectroscopic studies of its complex-forming reaction with iodine.
  • To prepare the ligand 7,16-bis(5-t-butyl-2-hydroxybenzyl)-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane.
  • As a ligand in the study of zirconium facilitated hydrolysis of a dipeptide at neutral pH.

包装

1 g in glass bottle

基本信息

经验(实验)分子式C12H26N2O4
分子量262.35
Beilstein609764
EC 号245-965-0
MDL编号MFCD00005112
PubChem化学物质编号24857813
NACRESNA.22

产品性质

质量水平100
测定≥96%
mp111-114 ℃ (lit.)
SMILES stringC1COCCOCCNCCOCCOCCN1
InChI1S/C12H26N2O4/c1-5-15-9-10-17-7-3-14-4-8-18-12-11-16-6-2-13-1/h13-14H,1-12H2
InChI keyNLMDJJTUQPXZFG-UHFFFAOYSA-N

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备dust mask type N95 (US), Eyeshields, Gloves
8.10953Sigma-AldrichKryptofix® 22for synthesis475.41元/1 G;   1232.91元/5 G;   咨询

产品说明

应用

Kryptofix® 22 for synthesis. CAS 23978-55-4, molar mass 262.35 g/mol.

分析说明

Purity (GC): ≥ 99
Identity (IR-spectrum): passes test
Melting point: 112 - 115

法律信息

Kryptofix is a registered trademark of Merck KGaA, Darmstadt, Germany

基本信息

经验(实验)分子式C12H26N2O4
分子量262.35
MDL编号MFCD00005112
EC索引号245-965-0

产品性质

质量水平200
效能3400 mg/kg LD50, oral (Rat)
mp112-115 ℃
储存温度2-30℃
InChI1S/C12H26N2O4/c1-5-15-9-10-17-7-3-14-4-8-18-12-11-16-6-2-13-1/h13-14H,1-12H2/p+2
InChI keyNLMDJJTUQPXZFG-UHFFFAOYSA-P

安全信息

象形图GHS07
警示用语:Warning
危险声明H315 - H319 - H335
预防措施声明P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
危险分类Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码11 - Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
151822FluorochemKryptofix 2295%2002元/1g;   7502元/5g;   咨询

基本信息

CAS Number23978-55-4
MDL NumberMFCD00005112
Melting Point111-114℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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