| CAS: | 185449-86-9 | |
| 分子式: | C24H22NO2P | |
| 分子量: | 387.4 | |
| 中文名称: |
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| 英文名称: |
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| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |||
| S853910 | MACKLIN | (11bS)-N,N,2,6-Tetramethyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine | ≥98%,≥99% e.e. | 166元/100mg; 316元/250mg; | 咨询 | ||
储存：室温,干燥 状态：白色粉末 | |||||||
| 15-1255 | Strem | (S)-(+)-(2,6-Dimethyl-3,5-dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)dimethylamine | min. 98% | 2655元/100mg; 10635元/500mg; | 咨询 | ||
Technical Notes: 1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino acids, enamides, and unsaturated acids . 2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position. 3.L igand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction. 4.L igand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes . 5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition. References: 1.J. Am. Chem. Soc., 2000, 122, 1 1539. 2.Adv. Synth. ( atal., 2003, 345, 308. 3.Adv. Synth. Catal., 2002, 344, 1 003. 4.Chem. Comm, 1999, 741 . 5.Eur. J. Inorg. Chem., 2002, 2569. 6.J. Am. Chem. Soc., 2008, 130, 3734. 7.Ad. Synth. Catal, 2012, 354, 2433. 8.J. Org. Chem., 2013, 78, 2736. | |||||||
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