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CAS: 1824-81-3
分子式: C6H8N2
分子量: 108.14
沸点: 208-209℃
熔点: 40-45℃
中文名称: 
6-甲基-2-氨基吡啶
2-氨基-6-噼哥啉
6-氨基-2-噼哥啉
2-氨基-6-甲基吡啶
2-氨基-6-甲基氮(杂)苯
英文名称: 
2-amino-6-methyl-pyridine
6-Methyl-pyridin-2-ylamine
2-Pyridinamine,6-methyl-
6-Amino-2-picoline
6-Methyl-2-pyridinamine,
6-methyl-2-Pyridinamine
2-amino-6-methyl-pyridin
2-amino-6-methylpyridine
6-methyl-2-pyridinamin
2-amino-6-picoline
2-Amino-6-picoline;2-Amino-6-methylpyridine
展开更多英文名
性质描述: 白色或微黄色结晶。熔点41℃,沸点208-209℃,相对密度1.0432(45/4℃)。极易溶于水,能溶于醇、醚、丙酮、苯等多数有机溶剂。有吸湿性。
生产方法: 由2-甲基吡啶胺化而得。将液氨通入反应罐内,加入硝酸高铁,搅拌下分次缓缓加入小块金属钠,加毕继续搅拌3h。自然排氨,至反应液呈稀浆状,得氨钠液。将无水二甲苯加入氨钠中,搅拌升温,蒸除残留氨气。温度升至120℃滴加2-甲基吡啶,加毕,保持124-129℃反应10h。在90-100℃缓缓加入适量水水解,水解完搅拌半小时,静置分取二甲苯层,蒸馏回收二甲苯,然后减压蒸馏收集90-120℃(1.33-2.67kPa)馏分,即2-氨基-6-甲基吡啶。收率72%。
用途: 医药中间体。用于生产萘啶酸,也用于有机合成,制造染料和照相显影剂。
推荐供应商
货号品牌产品名称规格包装、参考价格
A800530MACKLIN2-氨基-6-甲基吡啶98%61元/100g;   295元/500g;   咨询
储存:室温
状态:白色到黄色低熔点固体
A0403TCI2-Amino-6-methylpyridine>98.0%(GC)(T)100元/25G;   270元/100G;   990元/500G;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C6H8N2 = 108.14
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN107048
PubChem物质ID87562038
SDBS (AIST Spectral DB)3365
MDL编号MFCD00006331

技术规格

AppearanceWhite or Colorless to Light yellow powder to lump to clear liquid
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %
Melting point42.0 to 45.0 ℃

物性(参考值)

熔点43 ℃
沸点209 ℃
水溶性完全溶解

安全信息

图形或危害标志
信号词危险
危险性说明H310 : 皮肤接触致命。
H301 : 吞咽会中毒。
H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P262 : 严防进入眼中、接触皮肤或衣服。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P361 + P364 : 立即脱掉所有沾染的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。
P301 + P310 + P330 : 如误吞咽:立即呼叫急救中心/医生。漱口。
P302 + P352 + P310 : 如皮肤沾染:用水充分清洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

相关法规

RTECS#US1885000

运输信息

UN编号UN2811
类别6.1
包装类别 II
监管条件代码(*)
190496J&K2-Amino-6-methylpyridine98%602元/500G;   咨询

基本信息

分子式C6H8N2
分子量108.14
熔点40-44
沸点208-209
闪点103
MDL编码MFCD00006331
Beilstein107048
EINECS 编号217-360-1

安全信息

图形或危害标志
提示语Danger
危险说明H301
H310
H315
H319
H335
防范说明P261
P280
P301+P310
P302+P350
P305+P351+P338
P310
UN号码2811
危险分类6.1
包装等级III
WGK3
RTECSUS1885000
TSCA
A10444Alfa Aesar2-Amino-6-methylpyridine99%784元/100g;   3920元/500g;   咨询

基本信息

MDL
MFCD00006331

EINECS
217-360-1

分子式
C6H8N2

分子量
108.14

熔点
41-45°

沸点
208-209°

闪点
103°(217°F)

形态
Crystalline solid

Beilstein
107048

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H310-H315-H319-H335
Toxic if swallowed.Fatal in contact with skin.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P280h-P305+P351+P338-P307+P311
Wear protective gloves/clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed: Call a POISON CENTER or doctor/physician.

安全信息

危险等级
6.1

包装组
II

危险类别
24/25-36/37/38
Toxic in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.

安全等级
20-26-27-36/37-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take off immediately all contaminated clothing.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

RTECS
US1885000

TSCA

C10440Alfa Aesar2-Amino-6-picoline98%794元/100g;   664元/5g;   3204元/500g;   咨询

基本信息

Ref#
10440

MDL
6331

分子式
C6 H8 N2

分子量
108.14

闪点
103

形态
White to yellow/pale brown cryst. solid

安全信息

危险等级
6.1

包装组
II

A75706Sigma-Aldrich2-Amino-6-methylpyridine98%503.28元/100 G;   1345.51元/500 G;   咨询

基本信息

经验(实验)分子式C6H8N2
分子量108.14
Beilstein107048
EC 号217-360-1
MDL编号MFCD00006331
PubChem化学物质编号24891253
NACRESNA.22

产品性质

测定98%
bp208-209 ℃ (lit.)
mp40-44 ℃ (lit.)
SMILES stringCc1cccc(N)n1
InChI1S/C6H8N2/c1-5-3-2-4-6(7)8-5/h2-4H,1H3,(H2,7,8)
InChI keyQUXLCYFNVNNRBE-UHFFFAOYSA-N

安全信息

象形图GHS06
警示用语:Danger
危险声明H301 - H310 - H315 - H319 - H335
预防措施声明P262 - P280 - P301 + P310 + P330 - P302 + P352 + P310 - P305 + P351 + P338
危险分类Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官Respiratory system
储存分类代码6.1B - Non-combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGKWGK 3
闪点(F)217.4 °F - closed cup
闪点(C)103 ℃ - closed cup
个人防护装备Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
020196Fluorochem2-Amino-6-methylpyridine98%220元/25g;   418元/100g;   1826元/500g;   咨询

基本信息

CAS Number1824-81-3
MDL NumberMFCD00006331
Boiling Point208-209℃
Melting Point41.5-45.5℃
Density1.027

安全信息

图形或危害标志
危险性说明 H301: Toxic if swallowed.
H311: Toxic in contact with skin.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P322: Specific measures (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P361: Remove/Take off immediately all contaminated clothing.
P362: Take off contaminated clothing and wash before reuse.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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