Technical Notes:

1.N-Heterocyclic carbene and phosphine ruthe nium indenylidene precatalysts: A comparative

study in olefin metathesis.

2.Ruthenium(IV) alkylidenes as pre catalysts for direct arylations of alkenes with aryl chlorides and an application to sequential catalysis.

3.Synthesis of high molecular weight comb block copolymers and their assembly into ordered morphologies in Synthesis of the solid state.

4.Autonomic healing of epoxy vinyl esters via ring opening metathesis polymerization.

5.Amide synthesis from alcohols and amines catalyzed by ruthenium N-heterocyclic carbene complexes. 6.Stereoselective synthesis of E,Z- configured 1 ,3 -dienes by ring-closing metathesis.

7.Application to the total synthesis of lactimidomycin.

8.Long- Spaced aliphatic polyesters

9.A highly efficient olefin metathesis process for the synthesis of terminal alkenes from fatty acid esters.

10.Enaminones via ruthenium catalyzed coupling of thioamides and a diazocarbonyI compounds.

产品说明

应用

第一个被广泛用于有机合成的复分解催化剂。适用于在各种反应条件下的末端烯烃的无环二烯复分解聚合(ADMET)、应变环烯烃的开环复分解聚合(ROMP)、开环复分解(ROM)、烯烃交叉复分解(CM)和开环复分解(RCM)。

包装

1, 5, 50 g in glass bottle

其他说明

Aldrich用于烯烃复分解反应的Grubbs催化剂^® 技术

法律信息

Umicore 产品

有关更多信息，请访问http://www.pmc.umicore.com。
Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

基本信息

产品性质

安全信息

象形图
警示用语：	Warning
危险声明	H228
预防措施声明	P210
危险分类	Flam. Sol. 2
储存分类代码	4.1B - Flammable solid hazardous materials
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

基本信息

安全信息

图形或危害标志
危险性说明	H228: Flammable solid. H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P210: Keep away from – No smoking. P233: Keep container tightly closed. P240: Ground/bond container and receiving equipment. P241: Use explosion-proof ./ equipment. P260: Do not breathe . P261: Avoid breathing P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: . P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see . on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.