CAS 155806-35-2; (R)-(-)-1-[(S)-2-(diphenylphosphino)ferrocenyl] ethyldicyclohexylphosphine

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货号

品牌

产品名称

规格

包装、参考价格

R829433

MACKLIN

(R)-(-)-1[(S)-2-(二苯基膦)二茂铁]乙基二环己基膦

97%

26元/100mg; 45元/250mg; 131元/1g; 587元/5g; 2856元/25g;

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储存：室温
状态：橙色晶体或粉末

26-1210

Strem

(R)-(-)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine ethanol adduct

min. 97%

1260元/100mg; 4410元/500mg; 12120元/2g; 45450元/10g;

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Technical Notes:

1.Ligand for Palladium-catalyzed amination of aryl halides .

2.Ligand for Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene .

3.L igand for Rhodium-catalyzed asymmetric ring opening of oxabicyclic alkenes with orga noboronic acids .

4. L igand for Copper catalyzed asymmetric 1 ,4 -hyd rosilylations of a,ß-unsaturated esters .

5. L igand for Ruthenium-catalyzed asymmetric hyd rogenation of N-sulfonated-a-dehydroamino acids .

6.L igand for Rhodium-catalyzed a symmetric hydrogenation of enamines

7.Ligand for Palladium-catalyzed Kumada coupling of aryl and vinyl tosylates.

8.L igand for Palladium-catalyzed enantioselective synthesis of aryl sulfoxides .

9. L igand for Rhodium-catalyzed enantioselective insertion of a carbenoid carbon into a c-c bond.

10.L igand for Rh-catalyzed Asymmetric Hydrogenation of enamine substrates.

C37067

Alfa Aesar

(R)-(-)-1-[(S)-2-Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

97+%

2733元/100mg; 11812元/500mg;

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基本信息

Ref#
37067

MDL
800284

分子式
C36 H44 Fe P2 . C2 H6 O

分子量
640.61

88717

Sigma-Aldrich

(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

≥97%

519.54元/100 MG; 2467.84元/500 MG; 3251.21元/1 G; 16178.7元/5 G; 129845元/50 G; 216453元/100 G;

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产品说明

一般描述

( R )-1- [( S _P)-2-(二苯基膦)二茂铁基] 乙基二环己基膦 (( R ， S )-乙基二环己基膦) 是手性二茂铁基二膦配体。
与 Solvias AG 合作销售

应用

(R)-(S)-JOSIPHOS的铑配合物可以作为催化剂用于选择性不对称氢化：

Z-β-芳基-β-(烯胺基)膦酸酯。
o-烷氧基四取代的酰胺，以产生具有出色对映体过量的 β-氨基醇类似物。

它可用于制备环戊二烯叶立德配合物，[IrCl (PP)] ₂ 和 [IrCp (PP)]。(Cp = 环戊二烯基；PP = ( R )-1- [( S _P)-2-(二苯基膦)二茂铁基] 乙基二环己基膦)

包装

1, 5 g in glass bottle
100, 500 mg in glass bottle
无底玻璃瓶。内含物在插入的融合锥体内。

基本信息

经验(实验)分子式	C₃₆H₄₄FeP₂ · C₂H₅OH
分子量	640.60
MDL编号	MFCD00800284
PubChem化学物质编号	24888985

产品性质

描述	ethanol adduct
质量水平	100
测定	≥97%
光学纯度	ee: ≥99%
SMILES string	[Fe].[CH]1[CH][CH][CH][CH]1.C[C@H]([C]2[CH][CH][CH][C]2P(c3ccccc3)c4ccccc4)P(C5CCCCC5)C6CCCCC6
InChI	1S/C31H39P2.C5H5.Fe/c1-25(32(26-15-6-2-7-16-26)27-17-8-3-9-18-27)30-23-14-24-31(30)33(28-19-10-4-11-20-28)29-21-12-5-13-22-29;1-2-4-5-3-1;/h4-5,10-14,19-27H,2-3,6-9,15-18H2,1H3;1-5H;/t25-;;/m1../s1
InChI key	HGTBZFMPHBAUCQ-KHZPMNTOSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)