| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| T819552 | MACKLIN | 三(三苯基膦)二氯化钌(II) | 98% | 189元/1g; 559元/5g; 1847元/25g; | 咨询 |
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| T837093 | MACKLIN | 三(三苯基膦)二氯化钌 | 99.95% metals basis, 钌 10.2% 最低 | 459元/1g; 1378元/5g; | 咨询 |
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| D1997 | TCI | Tris(triphenylphosphine)ruthenium(II) Dichloride | >90.0%(T) | 295元/1G; 1060元/5G; | 咨询 |
基本信息 | 纯度/分析方法 | >90.0%(T) | | 分子式/分子量 | C54H45Cl2P3Ru = 958.85 | | 外观与形状(20℃) | 固体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 空气 | | Reaxys-RN | 14715227 | | PubChem物质ID | 87568451 | | MDL编号 | MFCD00013077 |
技术规格 | Appearance | Dark green to Dark red to Black powder to crystal | | Purity(Argentometric Titration) | min. 90.0 % |
安全信息 | 图形或危害标志 |  | | 信号词 | 警告 | | 危险性说明 | H302 + H312 + H332 : 吞咽、皮肤接触或吸入有害。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P261 : 避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P271 : 只能在室外或通风良好之处使用。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服。
P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。
P302 + P352 + P312 : 如皮肤沾染：用水充分清洗。如感觉不适，呼叫急救中心/医生。
P304 + P340 + P312 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。如感觉不适，呼叫急救中心/医生。
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| 233435 | J&K | Dichlorotris(triphenylphosphine)ruthenium(II) | 98% | 180元/1G; 712元/5G; 2809元/25G; | 咨询 |
基本信息 | 分子式 | C54H45Cl2P3Ru | | 分子量 | 958.83 | | 熔点 | 159 | | MDL编码 | MFCD00013077 | | Beilstein | 4935939 | | EINECS 编号 | 239-569-7 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 |  | | 提示语 | Warning | | 危险说明 | H302
H312
H331 | | 防范说明 | P280 | | UN号码 | 2811 | | 危险分类 | 6.1 | | 包装等级 | III | | WGK | 3 | | TSCA | 否 |
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| 44-0500 | Strem | Dichlorotris(triphenylphosphine)ruthenium(II) | 99% | 792元/1g; 2738元/5g; 9607元/25g; | 咨询 |
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| L00373 | Alfa Aesar | Dichlorotris(triphenylphosphine)ruthenium(II) | 97% | 922元/1g; 3439元/5g; 13756元/25g; | 咨询 |
应用
Dichlorotris(triphenylphosphine)ruthenium(II) is used as a catalyst employed in a synthesis of furans from allenyl sulfides. C-H Activation Catalyst in a Ruthenium/Lewis Acid System. It is used in the Kharasch addition of chlorocarbons to alkenes. 备注
Air & Moisture Sensitive. Keep container tightly closed. Store in cool, dry conditions in well sealed containers. 基本信息 MDL
MFCD00013077 EINECS
239-569-7 分子式
RuCl2[P(C6H5)3]3 分子量
958.86 熔点
132-134° 灵敏度
Moisture Sensitive. Air Sensitive. Ambient temperatures. 形态
Crystalline powder 溶解性
Insoluble in water. 安全信息 危险等级
6.1 包装组
III TSCA
否 |
| 010504 | Alfa Aesar | Dichlorotris(triphenylphosphine)ruthenium(II) | Premion庐, 99.95% (metals basis), Ru 10.2% min | 1537元/1g; 8780元/5g; | 咨询 |
应用
Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System 备注
Store under inert gas. It is Moisture sensitive. Keep container tightly closed in a dry and well-ventilated place. 基本信息 MDL
MFCD00013077 EINECS
239-569-7 分子式
RuCl2[P(C6H5)3]3 分子量
958.86 熔点
132-134° 灵敏度
Moisture Sensitive. Air Sensitive. Ambient temperatures. 形态
Crystalline powder 溶解性
Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene 安全信息 危险等级
6.1 包装组
III TSCA
否 |
| C20788 | Alfa Aesar | Tris(triphenylphosphine)ruthenium(II) chloride | 98% | 1276元/1g; 4643元/5g; 16986元/25g; | 咨询 |
基本信息 Ref#
20788 MDL
13077 分子式
C54 H45 Cl2 P3 Ru 分子量
958.85 形态
Crystalline powder 安全信息 危险等级
6.1 包装组
III |
| 223662 | Sigma-Aldrich | Tris(triphenylphosphine)ruthenium(II) Dichloride | 97% | 487.6元/1 G; 1299.04元/5 G; 4249.5元/25 G; | 咨询 |
产品说明 应用 Tris(triphenylphosphine)ruthenium(II) dichloride or [RuCl2(PPh3)3] can be used as a catalyst to synthesize: - Functionalized alcohols by C-C cross-coupling reaction between different alcohols via sp3 C-H bond activation of primary alcohols in the presence of Lewis acid.
- Furan derivatives from allenyl sulfides via 1,4 migration of the sulfanyl group.
- 1,3-diphenylpropan-1-one by alkylation of acetophenone with benzyl alcohol via C-C bond formation.
- Vinyl chloride monomer by hydrochlorination reaction of acetylene.
RuCl 2(PPh 3) 3 can also be used as a catalyst in the cyclization, isomerization, reduction, oxidation, and cross-coupling reactions of a variety of organic products. Hydrogenation of nitro groups, imines, and ketones, as well as selective oxidation of alcohols are also possible in the presence of this catalyst. 包装 1, 5, 25 g in glass bottle 基本信息 | 线性分子式 | [(C6H5)3P]3RuCl2 | | 分子量 | 958.83 | | Beilstein | 4935939 | | EC 号 | 239-569-7 | | MDL编号 | MFCD00013077 | | PubChem化学物质编号 | 24853394 | | NACRES | NA.22 |
产品性质 | 质量水平 | 100 | | 测定 | 97% | | reaction suitability | core: ruthenium
reagent type: catalyst
reaction type: C-H Activation | | SMILES string | Cl[Ru]Cl.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 | | InChI | 1S/3C18H15P.2ClH.Ru/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h3*1-15H;2*1H;/q;;;;;+2/p-2 | | InChI key | WIWBLJMBLGWSIN-UHFFFAOYSA-L |
安全信息 | 储存分类代码 | 13 - Non Combustible Solids | | WGK | WGK 3 | | 闪点(F) | Not applicable | | 闪点(C) | Not applicable | | 个人防护装备 | dust mask type N95 (US), Eyeshields, Gloves |
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| 934100 | Amethyst | Dichlorotris(triphenylphosphine)ruthenium(II) | 98%, 用于合成 | 111元/1G; 402元/5G; 1789元/25G; 6923元/100G; | 咨询 |
基本信息 | 分子式 | C54H45Cl2P3Ru | | 分子量 | 958.83 | | 熔点 | 159 | | MDL编码 | MFCD00013077 | | Beilstein | 4935939 | | EINECS 编号 | 239-569-7 | | 存储条件 | Store at 2-8℃ |
安全信息 | 图形或危害标志 | | | 提示语 | Warning | | 危险说明 | H302
H312
H331 | | 防范说明 | P280 | | UN号码 | 2811 | | 危险分类 | 6.1 | | 包装等级 | III | | WGK | 3 | | TSCA | 否 |
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| 048592 | Fluorochem | Dichlorotris(triphenylphosphine)ruthenium(II) | 97% | 484元/1g; 1540元/5g; 5720元/25g; | 咨询 |
基本信息 | CAS Number | 15529-49-4 | | MDL Number | MFCD00013077 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
| | 防范说明 | P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
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