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CAS: 14898-67-0
分子式: Cl3Ru·xH2O
分子量: 207.43 (anhydrous basis)
熔点: 100 °C(dec.)
推荐供应商
货号品牌产品名称规格包装、参考价格
R817276MACKLIN三氯化钌,水合物36.0-40.0% Ru basis385元/1g;   1150元/5g;   4999元/25g;   咨询
储存:室温,干燥,密封
状态:黑色或红棕色或灰色粉末或晶体或块状
R854509MACKLIN三氯化钌 水合物≥37% Ru basis420元/1g;   1350元/5g;   5398元/25g;   咨询
储存:室温,干燥,密封
状态:黑色或红棕色或灰色粉末或晶体或块状
R837094MACKLIN三氯化钌 水合物99.99% metals basis487元/1g;   1560元/5g;   6439元/25g;   16350元/100g;   咨询
储存:室温,干燥,密封
状态:黑色或灰色粉末或晶体或块状
768522MACKLIN三氯化钌 水合物99.95% metals basis385元/1g;   1375元/5g;   5665元/25g;   咨询
储存:室温, 惰性气体保存
状态:黑色或灰色粉末或晶体或块状
R0074TCIRuthenium(III) Chloride Hydrate675元/1G;   1835元/5G;   咨询

基本信息

分子式/分子量RuCl3.xH2O = 207.42
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
包装和容器 1G-带有塑料内管的玻璃瓶 (查看图片),  5G-带有塑料内管的玻璃瓶 (查看图片)
PubChem物质ID87575631
MDL编号MFCD00149844

技术规格

AppearanceBlack powder to crystal
Content(Ruthenium)min. 40.0 %
Drying loss1.0 to 5.0 %

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H410 : 对水生生物毒性极大并具有长期持续影响。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P273 : 避免释放到环境中。
P260 : 不要吸入粉尘或烟雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P391 : 收集溢出物。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3260
类别8
包装类别 II
监管条件代码(*)
44-5885StremRuthenium(III) Chloride Hydrate40-43% Ru, 99.99+%-Ru PURATREM [free of Ru(II) and Ru(IV) by electrochemical analysis]795元/1g;   3195元/5g;   咨询
44-5880StremRuthenium(III) Chloride Hydrate(99.9%-Ru)690元/1g;   2505元/5g;   9255元/25g;   咨询
011043Alfa AesarRuthenium(III) Chloride Hydrate99.9% (PGM basis), Ru 38% min0元/2g;   0元/10g;   0元/50g;   咨询

应用
Oxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs?’ catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.

备注
Hygroscopic. Incompatible with zinc.

基本信息

MDL
MFCD00149844

EINECS
233-167-5

分子式
Cl3Ru?xH2O

分子量
207.43(anhy)

熔点
100°dec

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline Soluble

溶解性
Very soluble in water. Soluble in alcohol, acetone.

Merck
14,8302

GHS危害和防范说明

GHS符号

Hazard Statements
H290-H302-H314-H318-H412
May be corrosive to metals.Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.Harmful to aquatic life with long lasting effects.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34-53
Harmful if swallowed.Causes burns.May cause long-term adverse effects in the aquatic environment.

安全等级
20-26-36/37/39-45-60-61
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
VM2650000

TSCA

043364Alfa AesarRuthenium(III) Chloride HydratePremion庐, 99.99% (metals basis)2334元/2g;   9953元/10g;   咨询

应用
Ruthenium(III) chloride hydrate is used as a starting material in ruthenium chemistry. It acts as a precursor to many ruthenium compounds, which finds application as catalysts in asymmetric hydrogenation and alkene metathesis. It serves as a catalyst in the preparation of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine. Further, it is used in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst for the efficient dehydrogenation of arylmethyl alcohols to the corresponding aldehydes.

备注
Hygroscopic. Incompatible with oxidizing agents, bases, zinc and metals.

基本信息

MDL
MFCD00149844

EINECS
233-167-5

分子式
RuCl3•xH2O

分子量
207.43(anhy)

熔点
100°dec

灵敏度
Hygroscopic. Ambient temperatures.

形态
Crystalline

溶解性
Soluble in water.

Merck
14,8302

GHS危害和防范说明

GHS符号

Hazard Statements
H290-H302-H314-H318-H412
May be corrosive to metals.Harmful if swallowed.Causes severe skin burns and eye damage.Causes serious eye damage.Harmful to aquatic life with long lasting effects.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
22-34-53
Harmful if swallowed.Causes burns.May cause long-term adverse effects in the aquatic environment.

安全等级
20-26-36/37/39-45-60-61
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
VM2650000

TSCA

C19548Alfa AesarRuthenium(III) Chloride Hydrate35 - 40% Ru771元/1g;   2428元/5g;   16905元/25g;   56595元/100g;   咨询

基本信息

Ref#
19548

MDL
149844

分子式
Cl3 Ru . x H2 O

分子量
207.42

安全信息

危险等级
8

包装组
I

206229Sigma-AldrichRuthenium(III) Chloride HydrateReagentPlus®920.57元/1 G;   2647.78元/5 G;   9080.69元/25 G;   咨询

产品说明

一般描述

可溶型

应用

它被用于制备纳米颗粒钌-氢氧化铝氧化物催化剂,使芳甲基醇有效脱氢生成相应的醛。该产物可催化由伯芳香胺和三烯丙基胺合成2-乙基-3-甲基喹啉。使用 RhCl3 在二氧化钛纳米管上沉积制备的钌水合氧化物,可用作分子氧选择性氧化醇的催化体系。

包装

1, 5, 25 g in glass bottle

法律信息

ReagentPlus is a registered trademark of sigma-aldrich Co. LLC

基本信息

线性分子式RuCl3 · xH2O
分子量207.43 (anhydrous basis)
EC 号233-167-5
MDL编号MFCD00149844
PubChem化学物质编号24852386
NACRESNA.23

产品性质

质量水平200
产品线ReagentPlus®
形式powder and chunks
组成Degree of hydration, ≤1
Ruthenium content, 40.00-49.00%
reaction suitabilityreagent type: catalyst
core: ruthenium
杂质≤ 0.1% Insoluble matter (C=1%, 25% HCl)
SMILES stringO.Cl[Ru](Cl)Cl
InChI1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3
InChI keyBIXNGBXQRRXPLM-UHFFFAOYSA-K

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H411
预防措施声明P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
463779Sigma-AldrichRuthenium(III) Chloride Hydrate99.98% trace metals basis1254.64元/1 G;   4336.04元/5 G;   咨询

产品说明

包装

1, 5 g in glass bottle

应用

用于不饱和醛的选择性加氢反应。
与三仲丁氧基铝 (201073) 一起用于纳米粒子催化剂的制备,该催化剂可用于催化醇的无受体脱氢反应生成醛和酮。
催化由芳香伯胺和三烯丙基胺合成 2-乙基-3-甲基喹啉。

其他说明

可溶型

基本信息

线性分子式RuCl3 · xH2O
分子量207.43 (anhydrous basis)
EC 号233-167-5
MDL编号MFCD00149844
PubChem化学物质编号24870096
NACRESNA.23

产品性质

质量水平100
测定99.98% trace metals basis
形式powder and chunks
reaction suitabilityreagent type: catalyst
core: ruthenium
杂质≤ 250.0  ppm Trace Metal Analysis
SMILES stringO.Cl[Ru](Cl)Cl
InChI1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3
InChI keyBIXNGBXQRRXPLM-UHFFFAOYSA-K

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H411
预防措施声明P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
84050Sigma-AldrichRuthenium(III) Chloride Hydrate38.0-42.0% Ru basis956.67元/1 G;   2141.71元/5 G;   咨询

产品说明

包装

1, 5 g in glass bottle

其他说明

与氧化剂发生氧化反应的催化剂;综述

基本信息

线性分子式RuCl3 · xH2O
分子量207.43 (anhydrous basis)
EC 号233-167-5
MDL编号MFCD00149844
PubChem化学物质编号57652984

产品性质

质量水平100
测定38.0-42.0% Ru basis
reaction suitabilitycore: ruthenium
reagent type: catalyst
SMILES stringO.Cl[Ru](Cl)Cl
InChI1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3
InChI keyBIXNGBXQRRXPLM-UHFFFAOYSA-K

安全信息

象形图GHS05GHS07GHS09
警示用语:Danger
危险声明H302 - H314 - H411
预防措施声明P260 - P273 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
961642AmethystRuthenium(III) Chloride Hydrate99.9%, 用于合成211元/1G;   841元/5G;   3183元/25G;   咨询

基本信息

分子式RuCl3·xH2O
分子量207.43(anhydrous)
熔点>300
MDL编码MFCD00149844
EINECS 编号233-167-5

安全信息

图形或危害标志
提示语Danger
危险说明H314
防范说明P280
P305+P351+P338
P310
UN号码3260
危险分类8
包装等级II
WGK3
005538FluorochemRuthenium(III) Chloride Hydrate97%462元/1g;   2200元/5g;   9856元/25g;   咨询

基本信息

CAS Number14898-67-0
MDL NumberMFCD00149844
Melting Point>300℃
Density2.9

安全信息

图形或危害标志
危险性说明 EUH071: Corrosive to the respiratory tract.
H290: May be corrosive to metals.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H400: Very toxic to aquatic life.
H410: Very toxic to aquatic life with long lasting effects.
防范说明 P234: Keep only in original container.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P390: Absorb spillage to prevent material damage.
P391: Collect spillage.
P405: Store locked up.
P406: Store in corrosive resistant/. container with a resistant inner liner.
P501: Dispose of contents/container to local regulations.
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