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CAS: 1484-50-0
分子式: C14H11BrO
分子量: 275.14
熔点: 53-58℃
英文名称: 
Desyl bromide
2-bromo-1,2-diphenyl-ethanon
2-bromo-2-phenylacetophenone
推荐供应商
货号品牌产品名称规格包装、参考价格
D832761MACKLIN2-溴-2-苯基乙酰苯97%681元/5g;   2412元/25g;   咨询
储存:室温,干燥,密封
状态:米黄色-棕色结晶粉末
B4471TCI2-Bromo-2-phenylacetophenone>95.0%(GC)865元/5G;   3355元/25G;   咨询

基本信息

纯度/分析方法>95.0%(GC)
分子式/分子量C14H11BrO = 275.15
外观与形状(20℃)固体
Reaxys-RN780486
PubChem物质ID253661013
MDL编号MFCD00000136

技术规格

AppearanceWhite to Light yellow to Light orange powder to crystal
Purity(GC)min. 95.0 %
Melting point54.0 to 58.0 ℃

物性(参考值)

熔点56 ℃
溶解性(可溶于)甲苯

安全信息

图形或危害标志
信号词危险
危险性说明H314 : 造成严重皮肤灼伤和眼损伤。
H290 : 可能腐蚀金属。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘或烟雾。
P234 : 只能在原容器中存放。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P390 : 吸收溢出物,防止材料损坏。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P406 : 贮存于抗腐蚀/带抗腐蚀衬里的容器中。
P405 : 存放处须加锁。

运输信息

UN编号UN3261
类别8
包装类别 II
监管条件代码(*)
C40317Alfa Aesar2-Bromo-2-phenylacetophenone97%1813元/5g;   7123元/25g;   咨询

基本信息

Ref#
40317

MDL
136

分子式
C14 H11 Br O

分子量
275.13

形态
Cream to pale yellow powder

安全信息

危险等级
8

包装组
III

258156Sigma-AldrichDesyl Bromide97%704.14元/5 G;   咨询

产品说明

一般描述

Reaction of cesium N-carbobenzyloxyglycylphenylalanate with desyl bromide in DMF has been investigated.

应用

Desyl bromide has been used in:

  • synthesis of phosphate esters of benzoin and benzoinyl N-carbobenzyloxyglycylphenylalanate
  • novel chemiluminogenic reaction for the sensitive determination of Arg-containing peptides

包装

5 g in glass bottle

基本信息

线性分子式C6H5CH(Br)COC6H5
分子量275.14
EC 号216-057-1
MDL编号MFCD00000136
PubChem化学物质编号24855632
NACRESNA.22

产品性质

质量水平100
测定97%
形式powder
mp56-58 ℃ (lit.)
SMILES stringBrC(c1ccccc1)C(=O)c2ccccc2
InChI1S/C14H11BrO/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13H
InChI keyZFFBIQMNKOJDJE-UHFFFAOYSA-N

安全信息

象形图GHS05GHS07
警示用语:Danger
危险声明H314 - H335
预防措施声明P260 - P271 - P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
危险分类Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官Respiratory system
储存分类代码8A - Combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
212634Fluorochem2-Bromo-1,2-diphenylethanone95%418元/1g;   8910元/25g;   咨询

基本信息

CAS Number1484-50-0
MDL NumberMFCD00000136

安全信息

图形或危害标志
危险性说明 H314: Causes severe skin burns and eye damage.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P363: Wash contaminated clothing before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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