CAS 1439-36-7; 1-三苯基膦-2-丙酮; triphenylphosphoranylidene-2-propanon

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货号

品牌

产品名称

规格

包装、参考价格

T821419

MACKLIN

1-三苯基膦烯-2-丙酮

98%

28元/1g; 35元/5g; 44元/25g; 163元/100g; 632元/500g;

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储存：室温
状态：白色到灰白色粉末和/或块状.

A1439

TCI

(Acetylmethylene)triphenylphosphorane

>98.0%(GC)

770元/25G;

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基本信息

纯度/分析方法	>98.0%(GC)
分子式/分子量	C₂₁H₁₉OP = 318.36
外观与形状(20℃)	固体
储存在惰性气体下	存放于惰性气体之中
应避免的情况	空气
Reaxys-RN	750077
PubChem物质ID	87562893
SDBS (AIST Spectral DB)	29562
MDL编号	MFCD00008774

技术规格

Appearance	White to Almost white powder to crystal
Purity(GC)	min. 98.0 %

物性(参考值)

熔点

207 ℃

相关法规

RTECS#

UC3900000

453870

J&K

1-Triphenylphosphoranylidene-2-propanone

99%

668元/25G; 2113元/100G;

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基本信息

分子式	C₂₁H₁₉OP
分子量	318.35
熔点	203-205
MDL编码	MFCD00008774
Beilstein	750077
EINECS 编号	215-878-2

安全信息

防范说明	P260 P262
WGK	3
RTECS	UC3900000
TSCA	否

A11410

Alfa Aesar

(Acetylmethylene)triphenylphosphorane

99%

893元/10g; 3278元/50g; 15174元/250g;

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应用
(Acetylmethylene)triphenylphosphorane is used as a Wittig reagent in synthetic chemistry, especially for the synthesis of functionalized pyrrolidines and cyclobutanones. It plays as a vital role in asymmetric allylboration for enantioselective synthesis of (+)-awajanomycin.It is also employed as a reactant in the preparation of 1,2-dioxanes with antitrypanosomal activity. Further, it is used in the preparation of amphibian pyrrolizidine alkaloids through allylic aminations and silicon-containing acyclic dienone musk odorants. In addition to this, it is involved in Domino Suzuki/Heck coupling reactions to prepare fluorenylidenes.

备注
Air sensitive. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00008774

EINECS
215-878-2

分子式
C₂₁H₁₉OP

分子量
318.36

熔点
204-209°

灵敏度
Keep Cold. Air Sensitive.

形态
Crystalline powder

溶解性
Soluble in chloroform. Slightly soluble in methanol.

Beilstein
750077

安全信息

RTECS
UC3900000

TSCA
否

C16997

Alfa Aesar

1-Triphenylphosphoranylidene-2-propanone

99%

1634元/25g; 6239元/100g;

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基本信息

Ref#
16997

MDL
8774

分子式
C21 H19 O P

分子量
318.34

形态
White to cream cryst powder

158755

Sigma-Aldrich

1-(Triphenylphosphoranylidene)-2-propanone

99%

1406.97元/25 G; 5345.86元/100 G;

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产品说明

应用

作为以下反应的反应物：

对映体选择性合成茚满衍生物的级联反应
对映选择性共轭加成合成α-支链吲哚
合成具有抗锥虫活性的1,2-二恶烷
不对称烯丙基硼化，用于(+)-awajanomycin的对映选择性合成
Domino Suzuki / Heck偶联反应，用于制备芴基
通过烯丙基胺化合成两栖吡咯并立生物碱
合成含硅无环二烯酮麝香香精

最近用于合成官能化吡咯烷和环丁酮的 Wittig 试剂。

包装

25, 100 g in poly bottle

基本信息

线性分子式	CH₃COCH=P(C₆H₅)₃
分子量	318.35
Beilstein	750077
EC 号	215-878-2
MDL编号	MFCD00008774
PubChem化学物质编号	24849772
NACRES	NA.22

产品性质

质量水平	200
测定	99%
reaction suitability	reaction type: C-C Bond Formation
mp	203-205 ℃ (lit.)
SMILES string	CC(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
InChI	1S/C21H19OP/c1-18(22)17-23(19-11-5-2-6-12-19,20-13-7-3-8-14-20)21-15-9-4-10-16-21/h2-17H,1H3
InChI key	KAANTNXREIRLCT-UHFFFAOYSA-N

安全信息

储存分类代码	13 - Non Combustible Solids
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Gloves, type N95 (US)

903015

Amethyst

1-Triphenylphosphoranylidene-2-propanone

98%, 用于合成

68元/5G; 209元/25G; 788元/100G;

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基本信息

分子式	C₂₁H₁₉OP
分子量	318.35
熔点	203-205
MDL编码	MFCD00008774
Beilstein	750077
EINECS 编号	215-878-2

安全信息

防范说明	P260 P262
WGK	3
RTECS	UC3900000
TSCA	否

215714

Fluorochem

1-(Triphenylphosphoranylidene)propan-2-one

95%

220元/1g; 220元/5g; 352元/10g; 704元/25g; 2464元/100g;

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基本信息

CAS Number	1439-36-7
MDL Number	MFCD00008774

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation. H335: May cause respiratory irritation.
防范说明	P233: Keep container tightly closed. P260: Do not breathe . P261: Avoid breathing . P264: Wash hands thoroughly after handling. P271: Use only outdoors or in a well-ventilated area. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P362: Take off contaminated clothing and wash before reuse. P403: Store in a well-ventilated place. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to in accordance with local regulation .