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CAS: 14283-07-9
分子式: LiBF4
分子量: 93.75
熔点: 275-311℃
中文名称: 
四氟硼酸锂
氟硼酸锂,一水
英文名称: 
lithium tetrafluoroborate,anhydrous
lithium fluoborate
lithiumtetrafluoroborate
Borate(1-),tetrafluoro-,lithium
Borate(1-), tetrafluoro-, lithium
Lithium tetrafluoroborate
tetrafluoro-borate(1- lithium
Lithium fluoborate,monohydrate
推荐供应商
货号品牌产品名称规格包装、参考价格
L812415MACKLIN四氟硼酸锂99.9% metals basis176元/5g;   617元/25g;   1749元/100g;   4220元/500g;   咨询
储存:室温,易燃物区域,干燥
状态:白色至类白色粉末或晶体
L812414MACKLIN四氟硼酸锂98%30元/5g;   62元/25g;   237元/100g;   1033元/500g;   5130元/2.5kg;   咨询
储存:室温,易燃物区域,干燥
状态:白色至类白色粉末或晶体
L812599MACKLIN四氟硼酸锂99.99% metals basis208元/5g;   719元/25g;   1968元/100g;   4920元/500g;   咨询
储存:室温,易燃物区域,干燥
状态:白色至类白色粉末或晶体
L0133TCILithium Tetrafluoroborate>98.0%(T)665元/25G;   咨询

基本信息

纯度/分析方法>98.0%(T)
分子式/分子量LiBF4 = 93.74
外观与形状(20℃)固体
储存在惰性气体下存放于惰性气体之中
应避免的情况湿气 (吸湿)
Reaxys-RN11548282
PubChem物质ID87572088
Merck Index (14)5543
MDL编号MFCD00011087

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(Neutralization titration)min. 98.0 %

物性(参考值)

溶解性(可溶于)甲醇
溶解性(微溶于)乙醚

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H360 : 可能对生育能力或胎儿造成伤害。
H372 : 长期或反复接触会对器官造成损害。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P260 : 不要吸入粉尘/ 烟/ 气体/ 烟雾/ 蒸气/ 喷雾。
P270 : 使用本产品时不要进食、饮水或吸烟。
P202 : 在阅读并明了所有安全措施前切勿搬动。
P201 : 使用前取得专用说明。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P308 + P313 : 如接触到或有疑虑:求医/就诊。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P405 : 存放处须加锁。

运输信息

UN编号UN1759
类别8
包装类别 II
监管条件代码(*)
128379J&KLithium Tetrafluoroborate98%146元/10G;   356元/50G;   咨询

基本信息

分子式LiBF4
分子量93.75
熔点293-300
密度0.852
MDL编码MFCD00011087
EINECS 编号238-178-9

安全信息

图形或危害标志
提示语Danger
危险说明H302
H312
H314
H332
防范说明P280
P305+P351+P338
P310
UN号码3260
危险分类8
包装等级II
WGK3
93-0356StremLithium Tetrafluoroborate98%556元/10g;   2197元/50g;   咨询
011528Alfa AesarLithium Tetrafluoroborate98%692元/10g;   2120元/50g;   咨询

应用
Lithium tetrafluoroborate is extensively utilized as an electrolyte in primary and secondary cells. It is used in rechargeable Li ion batteries. The electrolytes are non aqueous solutions of lithium tetrafluoroborate in the organic media.

备注
Lithiumtetrafluoroborate is stable. It is incompatible with glass,acids and strong bases.

基本信息

MDL
MFCD00011087

EINECS
238-178-9

分子式
BF4Li

分子量
93.75

熔点
293-300° dec.

灵敏度
Very Hygroscopic. Store under Argon. Ambient temperatures.

形态
Powder

溶解性
Soluble in water and tetrahydrofuran. Slightly soluble is diethyl ether.

Merck
14,5543

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H332-H314-H318
Harmful if swallowed.Harmful if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.

Precautionary Statements
P260h-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
8

包装组
II

危险类别
20/22-34
Harmful by inhalation and if swallowed.Causes burns.

安全等级
9-20-26-36/37/39-45-60
Keep container in a well-ventilated place.When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA

C22377Alfa AesarLithium Tetrafluoroborate98%, pure, anhydrous1535元/10g;   5915元/50g;   咨询

基本信息

Ref#
22377

MDL
11087

分子式
B F4 Li

分子量
93.75

密度
0.852

形态
Powder

安全信息

危险等级
8

包装组
II

244767Sigma-AldrichLithium Tetrafluoroborate98%636.08元/10 G;   1561.95元/50 G;   咨询

产品说明

应用

四氟硼酸锂是一种用于 Diels-Alder 反应的温和路易斯酸。它可用作温和有效的环氧乙烷的催化剂。四氟硼酸锂(LiBF4)可作为电解质中的添加剂,改善锂离子电池的性能。

包装

10, 50 g in glass bottle

基本信息

线性分子式LiBF4
分子量93.75
EC 号238-178-9
MDL编号MFCD00011087
PubChem化学物质编号24854701
NACRESNA.23

产品性质

测定98%
形式powder
mp293-300 ℃ (dec.) (lit.)
SMILES string[Li+].F[B-](F)(F)F
InChI1S/BF4.Li/c2-1(3,4)5;/q-1;+1
InChI keyUFXJWFBILHTTET-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H319 - H341
预防措施声明P202 - P264 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
451622Sigma-AldrichLithium Tetrafluoroborateultra dry, powder, 99.99% trace metals basis1830.69元/5 G;   6091.85元/25 G;   咨询

产品说明

一般描述

四氟硼酸锂是一类电解质材料,可用于制造锂离子电池。锂离子电池由具有充放电循环的阳极、阴极和电解液组成。这些材料能形成更环保的可持续性电能储存电池。
我们致力于为您带来更加绿色的替代产品,这些产品遵守一项或多项绿色化学12项原则。该产品为增强型,提高了能源效率。点击此处,查看更多详情。

应用

最近用于研发锂电池的固体复合电解质。
LiBF4 主要用作电解液,具有良好的离子电导性。它有助于形成电解溶液或液体电解质,可用于制造锂离子电池和固态电化学显示器。

包装

5, 25 g in poly bottle

基本信息

线性分子式LiBF4
分子量93.75
EC 号238-178-9
MDL编号MFCD00011087
PubChem化学物质编号24868639
NACRESNA.23

产品性质

质量水平100
描述Grade: ultra dry
测定99.99% trace metals basis
形式powder
环保替代产品特性Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
杂质≤ 150.0  ppm Trace Metal Analysis
mp293-300 ℃ (dec.) (lit.)
application(s)battery manufacturing
环保替代产品分类Enabling
SMILES string[Li+].F[B-](F)(F)F
InChI1S/BF4.Li/c2-1(3,4)5;/q-1;+1
InChI keyUFXJWFBILHTTET-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H319 - H341
预防措施声明P202 - P264 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2
储存分类代码8B - Non-combustible, corrosive hazardous materials
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Faceshields, Gloves, type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
901695Sigma-AldrichLithium Tetrafluoroborate≥98%, acid <200 ppm, anhydrous2173.11元/10 G;   6659.55元/50 G;   咨询

产品说明

一般描述

Lithium tetrafluoroborate (LiBF4), a lithium salt, exhibits high conductivity, low electrical charge transfer, moisture resistance, and good cyclic properties. It is suitable for a low-temperature electrolytic system. Its performance is comparable to the widely used LiPF6 system.

应用

Lithium tetrafluoroborate (LiBF4) finds application as electrolyte material in lithium ion batteries (LIBs). However, the presence of trace amount of water in LiBF4 causes its hydrolysis which leads to HF generation and destruction of the battery electrodes. Our LiBF4 contains < 100 ppm of water and is well suited for applications in LIBs.

注意

  • These electrolyte solutions have extremely low water content; Please handle under inert and moisture free environment (glove box).
  • Keep away from heat, sparks and flame. Avoid moisture, strong acid, strong alkalis, and oxidizing agents. Avoid skin and eye contact from product. Highly toxic and corrosive gases (HF) are generated by reaction with moisture os use only under inert gas atmosphere.
  • Please handle under inert and moisture free environment.

Storage:
Keep containers away from heat, humidity, direct sunlight and ignition source. Keep containers tightly closed in a cool dry and well-ventilated place. Do not store with strong oxidizing agents.

法律信息

Product of Ube Industries Ltd.

基本信息

线性分子式LiBF4
分子量93.75
MDL编号MFCD00011087
NACRESNA.23

产品性质

等级anhydrous
测定≥98%
mp293-300 ℃ (dec.) (lit.)
application(s)battery manufacturing
SMILES string[Li+].F[B-](F)(F)F
InChI1S/BF4.Li/c2-1(3,4)5;/q-1;+1
InChI keyUFXJWFBILHTTET-UHFFFAOYSA-N

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H319 - H341
预防措施声明P202 - P264 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
8.14347Sigma-AldrichLithium Tetrafluoroboratefor synthesis445.9元/10 G;   咨询

产品说明

分析说明

Assay (acidimetric): ≥ 97.0 %
Identity (IR): passes test

基本信息

经验(实验)分子式BF4Li
分子量93.75
MDL编号MFCD00011087
EC索引号238-178-9

产品性质

质量水平200
测定≥97.0% (acidimetric)
效能1638 mg/kg LD50, oral (Rat)
>2000 mg/kg LD50, skin (Rat)
mp324 ℃ (decomposition)
储存温度2-30℃

安全信息

象形图GHS07GHS08
警示用语:Warning
危险声明H302 - H315 - H319 - H341
预防措施声明P202 - P264 - P301 + P312 - P302 + P352 - P305 + P351 + P338 - P308 + P313
危险分类Acute Tox. 4 Oral - Eye Irrit. 2 - Muta. 2 - Skin Irrit. 2
储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
002848FluorochemLithium Tetrafluoroborate96%220元/1g;   308元/5g;   594元/25g;   1408元/100g;   咨询

基本信息

CAS Number14283-07-9
MDL NumberMFCD00011087
Melting Point275℃

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H341: Suspected of causing genetic defects ..
防范说明 P201: Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P281: Use personal protective equipment as required.
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations..
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