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CAS: 14047-29-1
分子式: C7H7BO4
分子量: 165.94
沸点: 406.4±47.0 °C(Predicted)
熔点: 220 °C (dec.)(lit.)
中文名称: 
4-羧基苯硼酸
4-羧基苯基硼酸
英文名称: 
4-Carboxybenzeneboronic acid
p-carboxy-benzeneboronic aci
4-carboxyphenylboronic acid
4-borono-benzoic aci
p-borono-benzoic aci
p-boronobenzoic acid
p-carboxybenzeneboronic acid
p-carboxyphenylboronic acid
4-(Dihydroxyboryl)benzoic acid
4-Boronobenzoic acid
推荐供应商
货号品牌产品名称规格包装、参考价格
C742458MACKLIN4-羧基苯硼酸99%40元/1g;   57元/5g;   136元/25g;   378元/100g;   1625元/500g;   咨询
储存:2-8°C
状态:粉末或晶体
C804236MACKLIN4-羧基苯硼酸97%30元/1g;   38元/5g;   104元/25g;   345元/100g;   1433元/500g;   咨询
储存:2~8°C
状态:白色或浅黄色粉末
C1353TCI4-Carboxyphenylboronic Acid (contains varying amounts of Anhydride)155元/1G;   475元/5G;   咨询

基本信息

分子式/分子量C7H7BO4 = 165.94
外观与形状(20℃)固体
Reaxys-RN3031088
PubChem物质ID87566365
MDL编号MFCD00151801

技术规格

AppearanceWhite to Light yellow powder to crystal
Purity(Neutralization titration)97.0 to 112.0 %

物性(参考值)

溶解性(可溶于)甲醇

安全信息

图形或危害标志
信号词警告
危险性说明H315 : 造成皮肤刺激。
H319 : 造成严重眼刺激。
防范说明P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/戴防护眼罩/戴防护面具。
P302 + P352 : 如皮肤沾染:用水充分清洗。
P337 + P313 : 如仍觉眼刺激:求医/就诊。
P305 + P351 + P338 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。
P362+P364 : 脱掉沾污的衣服,清洗后方可重新使用。
P332 + P313 : 如发生皮肤刺激:求医/就诊。

相关法规

RTECS#CY8925000
131160J&K4-Carboxyphenylboronic acid98%108元/1G;   212元/5G;   446元/25G;   咨询

基本信息

分子式C7H7BO4
分子量165.94
熔点220
MDL编码MFCD00151801
Beilstein3031088

安全信息

WGK2
RTECSCY8925000
TSCA
05-0400Strem4-Carboxyphenylboronic acidmin. 97%430元/1g;   1780元/5g;   咨询
B20954Alfa Aesar4-Carboxybenzeneboronic acid97%754元/1g;   3119元/5g;   7530元/25g;   咨询

基本信息

MDL
MFCD00151801

EINECS
000-000-0

分子式
C7H7BO4

分子量
165.94

熔点
ca 220° dec.

形态
Powder

Beilstein
3031088

GHS危害和防范说明

GHS符号

Hazard Statements
H303-H315-H319-H335
May be harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

RTECS
CY8925000

TSCA

C34440Alfa Aesar4-Carboxyphenylboronic acid97%566元/1g;   1957元/5g;   7907元/25g;   咨询

基本信息

Ref#
34440

MDL
151801

分子式
C7 H7 B O4

分子量
165.94

形态
White to pale cream powder

456772Sigma-Aldrich4-Carboxyphenylboronic acid460.98元/1 G;   1893.81元/10 G;   咨询

产品说明

应用

作为反应物参与:

  • 与聚苯乙烯胶乳表面稳定链的缩合反应
  • Suzuki偶联反应
  • 酯化
  • 聚乙烯胺衍生化
  • 同位素标记汞的合成
  • 聚SiNW官能化用于检测多巴胺

作为试剂用于
  • Suzuki-Miyaura交叉偶联反应
  • NIR荧光染料诱导的pH敏感度对量子点荧光寿命的影响
  • 生物负载的钯纳米颗粒,作为水中Suzuki反应的无磷催化剂
  • 在室温下与芳基硼酸一起进行Chan-Lam型铜(Cu)催化的S-芳基化

作为试剂用于
  • 通过区域选择性Suzuki-Miyaura交叉偶联反应结合钯催化的分子内氨基羰基化和环化反应制备异喹啉酮
  • 制备安普那韦基P1取代双芳基衍生物,是超有效的HIV-1蛋白酶抑制剂
  • 以空气为氧化剂,通过可见光引发、钌(Ru)-配合物催化的芳基硼酸有氧氧化羟基化反应制备苯酚
  • 葡萄糖敏感性含硼嵌段共聚物
  • 制备三磺化杯芳烃上层磺酰胺基衍生物及其与三甲基赖氨酸表观遗传标记的配合物

包装

1, 10 g in glass bottle

基本信息

线性分子式HO2CC6H4B(OH)2
分子量165.94
Beilstein3031088
MDL编号MFCD00151801
PubChem化学物质编号24869234
EC索引号604-189-6

产品性质

质量水平200
mp220 ℃ (dec.) (lit.)
SMILES stringOB(O)c1ccc(cc1)C(O)=O
InChI1S/C7H7BO4/c9-7(10)5-1-3-6(4-2-5)8(11)12/h1-4,11-12H,(H,9,10)
InChI keySIAVMDKGVRXFAX-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 2
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
376400Amethyst4-Carboxyphenylboronic acid98%, 用于合成72元/5G;   170元/25G;   414元/100G;   咨询

基本信息

分子式C7H7BO4
分子量165.94
熔点220
MDL编码MFCD00151801
Beilstein3031088

安全信息

WGK2
RTECSCY8925000
TSCA
010786Fluorochem4-Carboxybenzeneboronic acid98%308元/5g;   506元/25g;   1408元/100g;   咨询

基本信息

CAS Number14047-29-1
MDL NumberMFCD00151801
Boiling Point406.4℃
Melting Point222-226℃
Density1.4

安全信息

图形或危害标志
危险性说明 H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: .
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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