CAS 13007-90-4; 双(三苯基膦)二羰基镍; Bis(triphenylphosphine)nickel(0)dicarbonyl

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货号

品牌

产品名称

规格

包装、参考价格

B918594

MACKLIN

双(三苯基膦)二羰基镍

98%

30元/250mg; 72元/1g; 360元/5g;

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储存：2-8°C,密闭,干燥
状态：白色到黄色粉末或晶体

28-0100

Strem

Bis(triphenylphosphine)nickel dicarbonyl

98%

585元/5g; 2265元/25g; 6780元/100g;

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039242

Alfa Aesar

Bis(triphenylphosphine)dicarbonylnickel

98%

425元/2.5g; 1830元/10g; 7879元/50g;

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基本信息

MDL
MFCD00009591

EINECS
235-851-9

分子式
[(C₆H₅)₃P]₂Ni(CO)₂

分子量
639.29

熔点
210-215° dec.

形态
Crystalline

Merck
14,1304

GHS危害和防范说明

GHS符号

Hazard Statements
H317-H350
May cause an allergic skin reaction.May cause cancer.

Precautionary Statements
P201-P261-P280-P308+P313-P405-P501a
Obtain special instructions before use.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF exposed or concerned: Get medical advice/attention.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
43-45
May cause sensitization by skin contact.May cause cancer.

安全等级
4-9-20-27-36/37/39-45-60
Keep away from living quarters.Keep container in a well-ventilated place.When using do not eat or drink.Take off immediately all contaminated clothing.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste

TSCA
否

213934

Sigma-Aldrich

Bis(triphenylphosphine)dicarbonylnickel

1188.05元/10 G;

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产品说明

应用

用于催化：

环三聚反应
环寡聚反应

包装

10 g in glass bottle

基本信息

线性分子式	[(C₆H₅)₃P]₂Ni(CO)₂
分子量	639.28
EC 号	235-851-9
MDL编号	MFCD00009591
PubChem化学物质编号	24852811
NACRES	NA.22

产品性质

质量水平	100
reaction suitability	core: nickel reagent type: catalyst
mp	206-209 ℃ (lit.)
储存温度	2-8℃
SMILES string	[Ni].[C-]#[O+].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6
InChI	1S/2C18H15P.2CO.Ni/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;21-2;/h2*1-15H;;;
InChI key	SLFKPACCQUVAPG-UHFFFAOYSA-N

安全信息

象形图
警示用语：	Danger
危险声明	H317 - H350
预防措施声明	P201 - P280 - P302 + P352 - P308 + P313
危险分类	Carc. 1B - Skin Sens. 1
储存分类代码	6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK	WGK 3
闪点(F)	Not applicable
闪点(C)	Not applicable
个人防护装备	Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges