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CAS: 120-94-5
分子式: C5H11N
分子量: 85.15
沸点: 80-81℃
熔点: -90-81℃
中文名称: 
N-甲基四氢吡咯
1-甲基吡咯烷
N-甲基吡咯烷
1-甲基吡啶烷
英文名称: 
1-methyl-pyrrolidine
Pyrrolidine,1-methyl-
N-Methylpirrolidine
1-methyl-Pyrrolidine
1-methylpyrrolidine
methylpyrrolidine (non-specific name)
n-methylpyrrolidine
n-methyltetrahydropyrrole
1-methyl-pyrrolidin
1-methyl
1-methyl pyrrolidine
CAS:120-94-51-Methylpyrrolidine(or 1-Methylpyrrolidin N-Methyltetrahydropyrrole
Methylpyrrolidine
N-Methyl pyrrolidine
展开更多英文名
性质描述: 无色透明易挥发液体。凝固点-90℃,沸点79.5~80.5℃,相对密度0.819,折光率1.4240,闪点-21℃。易溶于水,溶于醇、醚等有机溶剂。
用途: 医药中间体。
推荐供应商
货号品牌产品名称规格包装、参考价格
M795470MACKLIN1-甲基吡咯烷10mM in DMSO185元/1ml;   咨询
储存:-20°C
状态:无色至淡黄色液体
M813492MACKLIN1-甲基吡咯烷98%42元/25ml;   120元/100ml;   455元/500ml;   1770元/2.5L;   咨询
储存:室温,易燃物区域
状态:无色到淡黄色液体
折射率:n20/D 1.425
M0415TCI1-Methylpyrrolidine>98.0%(GC)(T)290元/25ML;   585元/100ML;   1615元/500ML;   咨询

基本信息

纯度/分析方法>98.0%(GC)(T)
分子式/分子量C5H11N = 85.15
外观与形状(20℃)液体
储存在惰性气体下存放于惰性气体之中
应避免的情况空气
Reaxys-RN102445
PubChem物质ID87572474
SDBS (AIST Spectral DB)10636
MDL编号MFCD00003173

技术规格

AppearanceColorless to Light yellow clear liquid
Purity(GC)min. 98.0 %
Purity(Nonaqueous Titration)min. 98.0 %

物性(参考值)

沸点76 ℃
闪点3 ℃
比重0.80
折射率1.42
水溶性完全混溶

安全信息

图形或危害标志
信号词危险
危险性说明H302 : 吞咽有害。
H314 : 造成严重皮肤灼伤和眼损伤。
H225 : 高度易燃液体和蒸气。
防范说明P501 : 将内装物/容器送到批准的废物处理厂处理。
P270 : 使用本产品时不要进食、饮水或吸烟。
P240 : 容器和装载设备接地/等势联接。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P233 : 保持容器密闭。
P243 : 采取防止静电放电的措施。
P241 : 使用防爆的电气/通风/照明设备。
P242 : 只能使用不产生火花的工具。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时:使用干砂、干粉或抗醇泡沫灭火。
P303 + P361 + P353 : 如皮肤(或头发)沾染:立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽:漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P301 + P312 + P330 : 如误吞咽:如感觉不适,呼叫急救中心/医生。漱口。
P304 + P340 + P310 : 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。

相关法规

RTECS#UY1420500

运输信息

UN编号UN2924
类别3 / 8
包装类别 II
监管条件代码(*)
289073J&KN-Methylpyrrolidine98%316元/100G;   1199元/500G;   咨询

基本信息

分子式C5H11N
分子量85.15
沸点80-81
闪点3
密度0.819
折光率(n20D)1.4237 - 1.4257
MDL编码MFCD00003173
Beilstein102445
EINECS 编号204-438-5
存储条件Store at 2-8℃

安全信息

图形或危害标志
提示语Danger
危险说明H225
H302
H314
防范说明P210
P280
P305+P351+P338
P310
UN号码2924
危险分类3
次要危险性8
包装等级II
WGK3
RTECSUY1420500
B23799Alfa Aesar1-Methylpyrrolidine98%534元/100g;   1952元/500g;   咨询

应用
1-Methylpyrrolidine is a methylated pyrollidine and is involved as an essential part of the structure of cefipime. It is also an active component of cigarette smoke.

备注
Air sensitive. Incompatible with strong oxidizing agents and strong acids.

基本信息

MDL
MFCD00003173

EINECS
204-438-5

分子式
C5H11N

分子量
85.15

熔点
-90°

沸点
80-81°

闪点
-18°(0°F)

密度
0.799

折射率
1.4247

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Miscible with water.

GHS危害和防范说明

GHS符号

Hazard Statements
H225-H302-H332-H314-H318-H401-H411
Highly flammable liquid and vapour.Harmful if swallowed.Harmful if inhaled.Causes severe skin burns and eye damage.Causes serious eye damage.Toxic to aquatic life.Toxic to aquatic life with long lasting effects.

Precautionary Statements
P210-P260h-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
II

危险类别
11-20/22-34-51/53
Highly flammable.Harmful by inhalation and if swallowed.Causes burns.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
16-26-36/37/39-45-61
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

RTECS
UY1420500

TSCA

8.16146Sigma-Aldrich1-Methylpyrrolidinefor synthesis415.99元/100 ML;   咨询

产品说明

分析说明

Assay (GC, area%): ≥ 98.0 % (a/a)
Identity (IR): passes test

基本信息

经验(实验)分子式C5H11N
分子量85.15
MDL编号MFCD00003173
EC索引号204-438-5

产品性质

质量水平200
蒸汽压100 hPa ( 20 ℃)
测定≥98.0% (GC)
自燃温度170 ℃ (DIN 51794)
效能280 mg/kg LD50, oral (Rat)
expl. lim.1.1-9.1 % (v/v)
pH值(酸碱度)11.3 (1 g/L in H2O)
bp81 ℃/1013 hPa
mp<-80 ℃
转变温度flash point -3 ℃
溶解性 213 g/L
密度0.799 g/cm3 at 20 ℃
储存温度2-30℃
InChI1S/C5H11N/c1-6-4-2-3-5-6/h2-5H2,1H3
InChI keyAVFZOVWCLRSYKC-UHFFFAOYSA-N

安全信息

象形图GHS02GHS05GHS06GHS09
警示用语:Danger
危险声明H225 - H301 - H314 - H332 - H411
预防措施声明P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
危险分类Acute Tox. 3 Oral - Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Flam. Liq. 2 - Skin Corr. 1A
储存分类代码3 - Flammable liquids
WGKWGK 2
闪点(F)-0.4 °F - closed cup
闪点(C)-18 ℃ - closed cup
046845Fluorochem1-Methylpyrrolidine>98.0%(GC)(T)220元/1g;   264元/25g;   484元/100ml;   1650元/500ml;   咨询

基本信息

CAS Number120-94-5
MDL NumberMFCD00003173
Density0.819

安全信息

图形或危害标志
危险性说明 H225: Highly flammable liquid and vapour.
H302: Harmful if swallowed.
H314: Causes severe skin burns and eye damage.
防范说明 P210: Keep away from – No smoking.
P235: Keep cool.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof ./ equipment.
P242: Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P280: Wear .
P301 + P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P330: Rinse mouth.
P363: Wash contaminated clothing before reuse.
P370 + P378: In case of fire: Use sand, CO2 or extinguishing powder for extinction.
P403 + P235: Store in a well-ventilated place. Keep cool.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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