应用
Diphenyl selenide is used for anti-selective Michael addition of thiols and their analogs to nitro-olefins.

备注
Moisture sensitive. Incompatible with strong oxidizing agents. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place.

基本信息

MDL
MFCD00014067

EINECS
214-474-2

分子式
(C₆H₅)₂Se

分子量
233.17

熔点
3°

沸点
165-167°/12mm

密度
1.351

灵敏度
Ambient temperatures.

形态
Liquid

溶解性
Immiscible with water.

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H331-H373-H400-H410
Toxic if swallowed.Toxic if inhaled.May cause damage to organs through prolonged or repeated exposure.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P260-P301+P310a-P304+P340-P311a-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray.Do not breathe dust/fume/gas/mist/vapours/spray.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
23/25-33-50/53
Toxic by inhalation and if swallowed.Danger of cumulative effects.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
20/21-28-45-60-61
When using do not eat, drink or smoke.After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous wasteAvoid release to the environment. Refer to special instructions/safety data sheets.

欧盟危险品标志

TSCA
是

产品说明

一般描述

Diphenyl selenide is an organoselenium compound. Its standard enthalpies of combustion, formation and the mean bond-dissociation energy have been calculated. Its potential as a neutral carrier to develop silver-selective membrane electrode has been investigated. Diphenyl selenide undergoes oxidation to form selenoxides on treating with N-bromosuccinimide followed by alkaline hydrolysis.

应用

用于硫醇类化合物及其类似物经非选择性 Michael 加成到硝基烯烃类化合物的反应。

包装

10 g in glass bottle

基本信息

产品性质

安全信息

象形图
警示用语：	Danger
危险声明	H301 + H331 - H373 - H410
预防措施声明	P273 - P301 + P310 + P330 - P304 + P340 + P311 - P314
危险分类	Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
储存分类代码	6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
WGK	WGK 3
闪点(F)	230.0 °F - closed cup
闪点(C)	> 110 ℃ - closed cup
个人防护装备	Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

基本信息

安全信息

图形或危害标志
危险性说明	H301: Toxic if swallowed. H311: Toxic in contact with skin. H331: Toxic if inhaled. H373: May cause damage to organs .. H410: Very toxic to aquatic life with long lasting effects.
防范说明	P260: Do not breathe . P264: Wash hands thoroughly after handling. P270: Do not eat, drink or smoke when using this product. P271: Use only outdoors or in a well-ventilated area. P273: Avoid release to the environment. P280: Wear . P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P311: Call a POISON CENTER or doctor/physician. P312: Call a POISON CENTER or doctor/physician if you feel unwell. P314: Get medical advice/attention if you feel unwell. P321: Specific treatment (see . on this label). P322: Specific measures (see . on this label). P330: Rinse mouth. P361: Remove/Take off immediately all contaminated clothing. P363: Wash contaminated clothing before reuse. P391: Collect spillage. P403 + P233: Store in a well-ventilated place. Keep container tightly closed. P405: Store locked up. P501: Dispose of contents/container to local regulations.