| 货号 | 品牌 | 产品名称 | 规格 | 包装、参考价格 | |
| C804772 | MACKLIN | 反式-1,2-环己二胺 | 98% | 32元/2ml; 75元/10ml; 230元/50ml; 1015元/250ml; 4050元/1L; | 咨询 |
储存：2~8℃ 状态：无色到浅黄色液体 折射率：n20/D 1.489(lit.) |
| C1120 | TCI | trans-1,2-Cyclohexanediamine | >97.0%(GC)(T) | 425元/25ML; 1735元/250ML; | 咨询 |
基本信息 | 纯度/分析方法 | >97.0%(GC)(T) | | 分子式/分子量 | C6H14N2 = 114.19 | | 外观与形状(20℃) | 液体 | | 储存在惰性气体下 | 存放于惰性气体之中 | | 应避免的情况 | 光,空气,湿气 (吸湿) | | Reaxys-RN | 2801643 | | PubChem物质ID | 87566150 | | MDL编号 | MFCD00063747 |
技术规格 | Appearance | Colorless to Almost colorless clear liquid | | Purity(GC) | min. 97.0 % | | Purity(Nonaqueous Titration) | min. 97.0 % |
物性(参考值) | 熔点 | 19 ℃ | | 沸点 | 80 ℃/15 mmHg | | 闪点 | 68 ℃ | | 比重 | 0.95 | | 折射率 | 1.49 | | 水溶性 | 完全溶解 | | 溶解性(可溶于) | 醇,乙醚 |
安全信息 | 图形或危害标志 |  | | 信号词 | 危险 | | 危险性说明 | H314 : 造成严重皮肤灼伤和眼损伤。
H227 : 可燃液体。
| | 防范说明 | P501 : 将内装物/容器送到批准的废物处理厂处理。
P210 : 远离热源/火花/明火/热表面。禁止吸烟。
P264 : 作业后彻底清洗皮肤。
P280 : 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
P370 + P378 : 火灾时：使用干砂、干粉或抗醇泡沫灭火。
P303 + P361 + P353 : 如皮肤(或头发)沾染：立即脱掉所有沾污的衣物。用水清洗皮肤/淋浴。
P301 + P330 + P331 : 如误吞咽：漱口。不要诱导呕吐。
P363 : 沾染的衣服清洗后方可重新使用。
P304 + P340 + P310 : 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。立即呼叫急救中心/医生。
P305 + P351 + P338 + P310 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。立即呼叫急救中心/医生。
P403 + P235 : 存放在通风良好的地方。保持低温。
P405 : 存放处须加锁。
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运输信息 | UN编号 | UN2735 | | 类别 | 8 | | 包装类别 | III | | 监管条件代码(*) | |
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| 252503 | J&K | trans-1,2-Diaminocyclohexane | 98% | 246元/25G; 1607元/250G; | 咨询 |
基本信息 | 分子式 | C6H14N2 | | 分子量 | 114.19 | | 熔点 | 14-15 | | 沸点 | 79-81 | | 闪点 | 68 | | 密度 | 0.951 | | 折光率(n20D) | 1.4870 - 1.4900 | | MDL编码 | MFCD00063747 | | Beilstein | 3193807 |
安全信息 | 图形或危害标志 | | | 提示语 | Danger | | 危险说明 | H314 | | 防范说明 | P280
P305+P351+P338
P310 | | UN号码 | 2735 | | 危险分类 | 8 | | 包装等级 | II | | WGK | 3 | | TSCA | 是 |
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| L06626 | Alfa Aesar | (±)-trans-1,2-Diaminocyclohexane | 99% | 384元/10g; 1539元/50g; 5184元/250g; | 咨询 |
应用
(^+)-trans-1,2-Diaminocyclohexane is employed in the synthesis of macrocyclic [3+3] hexa Schiff base. It also plays an important role in the preparation of multidentate ligands, chiral auxiliaries and chiral stationary phases. Further, it is used to prepare [2+2] macrocyclization by reacting with aliphatic dialdehydes. In addition to this, it acts as a chiral ligand, which finds application in asymmetric catalysis. 备注
Incompatible with strong oxidizing agents and strong acids. 基本信息 MDL
MFCD00063747 分子式
C6H14N2 分子量
114.19 熔点
14-15° 沸点
89-90°/14mm 闪点
68°(154°F) 密度
0.951 折射率
1.4890 灵敏度
Keep Cold. Air Sensitive. May form a Precipitate. Store under Nitrogen. 形态
Liquid 溶解性
Miscible with water. Beilstein
3193807 GHS危害和防范说明 GHS符号
Hazard Statements
H227-H314-H318
Combustible liquid.Causes severe skin burns and eye damage.Causes serious eye damage. Precautionary Statements
P262-P280-P305+P351+P338-P309-P310
Do not get in eyes, on skin, or on clothing.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician. 安全信息 危险等级
8 包装组
II 危险类别
34
Causes burns. 安全等级
20-23-26-36/37/39-45-60
When using do not eat or drink.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste 欧盟危险品标志
 TSCA
是 |
| C24867 | Alfa Aesar | (n)-trans-1,2-Diaminocyclohexane | 98% | 528元/10ml; 1725元/50ml; 5591元/250ml; | 咨询 |
基本信息 Ref#
24867 MDL
63747 分子式
C6 H14 N2 分子量
114.19 闪点
68 密度
0.951 形态
Colorless to pale yellow liquid 安全信息 危险等级
8 包装组
II |
| 270016 | Sigma-Aldrich | (±)-trans-1,2-Diaminocyclohexane | 99% | 308.68元/10 ML; 944.76元/50 ML; 4555.09元/250 ML; | 咨询 |
产品说明 一般描述 (±)-反式-1,2-二氨基环己烷可与脂肪族二醛缩合形成[3+3]或[2+2]大环化产物。 应用 (±)-反式-1,2-二氨基环己烷可用于合成大环[3+3]六席夫碱。它也可用于多齿配体、手性助剂 和手性固定相的合成。 包装 10, 50, 250 mL in glass bottle 基本信息 | 线性分子式 | C6H10(NH2)2 | | 分子量 | 114.19 | | Beilstein | 3193807 | | MDL编号 | MFCD00063747 | | PubChem化学物质编号 | 24856187 | | NACRES | NA.22 |
产品性质 | 质量水平 | 200 | | 蒸汽压 | 0.4 mmHg ( 20 ℃) | | 测定 | 99% | | 形式 | liquid | | 折射率 | n20/D 1.489 (lit.) | | bp | 79-81 ℃/15 mmHg (lit.) | | mp | 14-15 ℃ (lit.) | | 密度 | 0.951 g/mL at 25 ℃ (lit.) | | SMILES string | N[C@@H]1CCCC[C@H]1N | | InChI | 1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m1/s1 | | InChI key | SSJXIUAHEKJCMH-PHDIDXHHSA-N |
安全信息 | 象形图 | | | 警示用语： | Danger | | 危险声明 | H314 | | 预防措施声明 | P280 - P301 + P330 + P331 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 | | 危险分类 | Skin Corr. 1B | | 储存分类代码 | 8A - Combustible, corrosive hazardous materials | | WGK | WGK 3 | | 闪点(F) | 156.2 °F - closed cup | | 闪点(C) | 69 ℃ - closed cup | | 个人防护装备 | Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter |
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| 012707 | Fluorochem | trans-1,2-Diaminocyclohexane (Racemic) | 98% | 242元/1g; 682元/25g; 2024元/100g; 2992元/250ml; | 咨询 |
基本信息 | CAS Number | 1121-22-8 | | MDL Number | MFCD00063747 | | Boiling Point | 79 - 81 ℃ | | Melting Point | 14 - 15 ℃ | | Density | 0.95 |
安全信息 | 图形或危害标志 | | | 危险性说明 | H314: Causes severe skin burns and eye damage.
| | 防范说明 | P260: Do not breathe .
P264: Wash hands thoroughly after handling.
P280: Wear .
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303 + P361 + P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P321: Specific treatment (see . on this label).
P363: Wash contaminated clothing before reuse.
P405: Store locked up.
P501: Dispose of contents/container to local regulations.
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