基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	警告
危险性说明	H302 : 吞咽有害。 H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P501 : 将内装物/容器送到批准的废物处理厂处理。 P270 : 使用本产品时不要进食、饮水或吸烟。 P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。 P301 + P312 + P330 : 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口。

应用
3-Aminocrotononitrile reacts with ferrocenyl-1,2-enones to form ferrocenyl pyridines. It undergoes diazotization coupling reaction with p-substituted anilines to give 2-arylhydrazone-3-ketimino-butyronitriles.3-Aminocrotononitrile, (E)+(Z), is used in reaction with aryldiazonium salts gave, instead of the expected triazene, 2-arylhydrazono-3-ketobutyronitrile by electrophilic attack at the ?-carbon and hydrolysis of the resulting imine. It is also used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. 3-Aminocrotononitrile was used as bisnucleophilic reagent which on cyclocondensation with hexafluoroacetone(ethoxycarbonylimine) forms bis(trifluoromethyl)pyrimidinones.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents.

基本信息

MDL
MFCD00008071

EINECS
214-266-2

分子式
C₄H₆N₂

分子量
82.11

熔点
ca 70-75°

沸点
120°/4mm

闪点
154°(309°F)

灵敏度
Keep Cold.

形态
Crystalline flakes or powder

溶解性
Very soluble in water, soluble in ethanol.

Beilstein
1719815

GHS危害和防范说明

GHS符号

Hazard Statements
H302-H319-H317
Harmful if swallowed.Causes serious eye irritation.May cause an allergic skin reaction.

Precautionary Statements
P261-P280-P305+P351+P338-P302+P352-P321-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF ON SKIN: Wash with plenty of soap and water.Specific treatment (see label).Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
6.1

包装组
III

危险类别
20/22-36/37
Harmful by inhalation and if swallowed.Irritating to eyes and respiratory system.

安全等级
26-36/37/39
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.

欧盟危险品标志

TSCA
是

基本信息

Ref#
15245

MDL
8071

分子式
C4 H6 N2

分子量
82.1

形态
Pale yellow chips

安全信息

危险等级
6.1

包装组
III

基本信息

产品性质