[登录] [免费注册]
试剂仪器网
位置:首页 > 资料中心 > 化工字典 > 106-57-0
关键词:       仅模糊查询
CAS: 106-57-0
分子式: C4H6N2O2
分子量: 114.10
熔点: 300℃
中文名称: 
甘氨酸酐
2,5-哌嗪二酮
无水甘氨基酸轻声二氮已环二酮
英文名称: 
Diglycolydiamide
Glycyl glycine lacton
2,5-diketopiperazine
2,5-dioxopiperazine
2,5-piperazinedione
alpha,gamma-diacipiperazine
cyclo(glycylglycyl)
cyclodiglycine
cycloglycylglycine
diglycolyl diamide
diketopiperazine
glycylglycine lactam
glycine anhydride
piperazine-2,5-dione
2,5-dioxo-piperazine
Glycinanhydrid
2,5-Dioxopiperazin
2,5-Piperazindion
Glycerinanhydrid
Di-keto-piperazin
展开更多英文名
性质描述: 片状或针状结晶。熔点311-312℃(分解),260℃升华。溶于热水,具弱碱性。
生产方法: 由甘氨酸缩合而得。将甘氨酸与乙二胺按1:5混合后搅拌加热,174-176℃反应50min,然后置于冰室中过认,过滤出结晶,用甲醇洗涤,干燥得甘氨酰酐。也可以由甘氨酸在脱水的甘油中缩合而制备。
用途: 用作生化试剂。被碱、酸或热水水解可得甘氨酰甘氨酸。
推荐供应商
货号品牌产品名称规格包装、参考价格
G823794MACKLIN甘氨酸酐98%65元/5g;   215元/25g;   745元/100g;   2998元/500g;   咨询
储存:2~8℃
状态:NA
G0100TCIGlycine Anhydride>98.0%(N)395元/25G;   3020元/500G;   咨询

基本信息

纯度/分析方法>98.0%(N)
分子式/分子量C4H6N2O2 = 114.10
外观与形状(20℃)固体
Reaxys-RN112112
PubChem物质ID87570307
SDBS (AIST Spectral DB)3691
Merck Index (14)7466
MDL编号MFCD00006009

技术规格

AppearanceWhite to Almost white powder to crystal
Purity(with Total Nitrogen)min. 98.0 %
Solubility in hot Wateralmost transparency

相关法规

RTECS#TL6325250
A18822Alfa AesarGlycine Anhydride98%957元/25g;   2810元/100g;   咨询

应用
It can be used as an intermediate in the preparation of various pharmaceutical and biologically active compounds. Also used in the synthesis of dipeptide isosteres by cross-metathesis.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

基本信息

MDL
MFCD00006009

EINECS
203-411-5

分子式
C4H6N2O2

分子量
114.10

熔点
ca 300° dec.

灵敏度
Ambient temperatures.

形态
Powder

溶解性
Soluble in water (142mg/L).

Beilstein
112112

Merck
14,7466

安全信息

RTECS
TL6325250

TSCA

C12008Alfa AesarGlycine Anhydride98%457元/5g;   963元/25g;   3057元/100g;   29538元/1kg;   咨询

基本信息

Ref#
12008

MDL
6009

分子式
C4 H6 N2 O2

分子量
114.1

形态
White powder

G7251Sigma-AldrichGlycine Anhydridecyclic dipeptide910.08元/25 G;   1622.44元/100 G;   8541.6元/1 KG;   咨询

基本信息

经验(实验)分子式C4H6N2O2
分子量114.10
Beilstein112112
EC 号203-411-5
MDL编号MFCD00006009
eCl@ss32160406
PubChem化学物质编号24895298
NACRESNA.26

产品性质

质量水平200
测定≥99% (TLC)
形式powder
颜色 white
mp>300 ℃ (lit.)
SMILES stringO=C1CNC(=O)CN1
InChI1S/C4H6N2O2/c7-3-1-5-4(8)2-6-3/h1-2H2,(H,5,8)(H,6,7)
InChI keyBXRNXXXXHLBUKK-UHFFFAOYSA-N

安全信息

储存分类代码13 - Non Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
个人防护装备Eyeshields, Gloves, type N95 (US)
8.14160Sigma-Aldrich2,5-Piperazinedionefor synthesis854.34元/25 G;   咨询

产品说明

分析说明

Assay (ex N): ≥ 98.0 %
Identity (IR): passes test

基本信息

经验(实验)分子式C4H6N2O2
分子量114.10
MDL编号MFCD00006009
EC索引号203-411-5

产品性质

质量水平200
溶解性 142 g/L
储存温度2-30℃
InChI1S/C4H6N2O2/c7-3-1-5-4(8)2-6-3/h1-2H2,(H,5,8)(H,6,7)
InChI keyBXRNXXXXHLBUKK-UHFFFAOYSA-N

安全信息

储存分类代码11 - Combustible Solids
WGKWGK 3
闪点(F)Not applicable
闪点(C)Not applicable
358180Fluorochempiperazine-2,5-dione95%264元/5g;   440元/10g;   660元/25g;   1980元/100g;   咨询

基本信息

CAS Number106-57-0
MDL NumberMFCD00006009
Melting Point>300℃
Density1.3565

安全信息

图形或危害标志
危险性说明 H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
防范说明 P233: Keep container tightly closed.
P260: Do not breathe .
P261: Avoid breathing .
P264: Wash hands thoroughly after handling.
P271: Use only outdoors or in a well-ventilated area.
P280: Wear .
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing..
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P312: Call a POISON CENTER or doctor/physician if you feel unwell.
P321: Specific treatment (see relevant procedures. on this label).
P332 + P313: If skin irritation occurs: Get medical advice/ attention.
P337 + P313: If eye irritation persists: Get medical advice/attention.
P340: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P362: Take off contaminated clothing and wash before reuse.
P403: Store in a well-ventilated place.
P403 + P233: Store in a well-ventilated place. Keep container tightly closed.
P405: Store locked up.
P501: Dispose of contents/container to in accordance with local regulation .
CAS号首数字顺序排列: 1 2 3 4 5 6 7 8 9
Baidu
map