基本信息

技术规格

物性(参考值)

安全信息

图形或危害标志
信号词	警告
危险性说明	H315 : 造成皮肤刺激。 H319 : 造成严重眼刺激。
防范说明	P264 : 作业后彻底清洗皮肤。 P280 : 戴防护手套/戴防护眼罩/戴防护面具。 P302 + P352 : 如皮肤沾染：用水充分清洗。 P337 + P313 : 如仍觉眼刺激：求医/就诊。 P305 + P351 + P338 : 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364 : 脱掉沾污的衣服，清洗后方可重新使用。 P332 + P313 : 如发生皮肤刺激：求医/就诊。

相关法规

基本信息

安全信息

图形或危害标志
提示语	Warning
危险说明	H315 H319
防范说明	P305+P351+P338
WGK	2
RTECS	MW4890000
TSCA	是

应用
3-Phenylpropionaldehyde is used as a flavoring agent. It is also used in the preparation of cinnamaldehyde, 2-chloro hydrocinnamaldehyde by alfa chlorination and mixture of homopropargyl alcohols. It serves as a precursor for the synthesis of mixture of syn- and anti-beta-hydroxyallylsilanes by hydroboration of allenylsilane. It is also involved in the catalytic asymmetric cyanosilylation to prepare (2S)-2-hydroxy-4-phenylbutanenitrile. Further, it undergoes Henry reaction to form nitroaldols by reacting with nitromethane.

备注
Incompatible with strong oxidizing agents and strong bases.

基本信息

MDL
MFCD00007021

EINECS
203-211-8

分子式
C₉H₁₀O

分子量
134.18

熔点
-42°

沸点
222-223°

闪点
95°(203°F)

密度
1.017

折射率
1.5230

灵敏度
Air Sensitive. Store under Nitrogen. Ambient temperatures.

形态
Liquid

溶解性
Miscible with chloroform, dichloromethane, ethyl acetate, alcohol and ether. Immiscible with water.

Beilstein
1071910

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
23-26-37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

RTECS
MW4890000

TSCA
是

基本信息

Ref#
24051

MDL
7021

分子式
C9 H10 O

分子量
134.18

闪点
95

密度
1.01

形态
Colorless liquid

产品说明

一般描述

氢化肉桂醛是C=C双键氢化的肉桂醛。它可以通过各种方法对肉桂醛的C=C双键进行选择性氢化而合成。 氢化肉桂醛和硝基甲烷经过Henry反应，形成硝基醇。 使用 ¹³C标记氢化肉桂醛的C1和C3位置并对它们进行质谱分析，可阐明其断裂模式。

应用

氢化肉桂醛可用于合成以下物质：

• 通过α-氯化反应，合成2-氯代氢化肉桂醛。
• 通过动力学拆分-丙烯酰化反应，合成均聚炔丙醇混合物。
• 通过硼氢化硅烷的硼氢化反应，合成顺式-和反式--β-羟基烯丙基硅烷。
• 通过催化不对称氰基甲硅烷基化反应，合成(2S)-2-羟基-4-苯基丁腈。
• 通过Pd(TFA)₂/4,5-二氮杂萘酮催化的脱氢反应，合成肉桂醛。

包装

100 mL in glass bottle

基本信息

产品性质

安全信息

产品说明

分析说明

Assay (GC, area%): ≥ 95.0 % (a/a)
Density (d 20 °C/ 4 °C): 1.010 - 1.018
Identity (IR): passes test

基本信息

产品性质

安全信息

基本信息

安全信息

图形或危害标志
危险性说明	H315: Causes skin irritation. H319: Causes serious eye irritation.
防范说明	P264: Wash hands thoroughly after handling. P280: Wear . P302 + P352: IF ON SKIN: Wash with plenty of soap and water. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321: Specific treatment (see relevant procedures. on this label). P332 + P313: If skin irritation occurs: Get medical advice/ attention. P337 + P313: If eye irritation persists: Get medical advice/attention. P362: Take off contaminated clothing and wash before reuse.